Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials
-
Mohammed Rafi Shaik
und
Naser M. Alandis
Abstract
Linseed polyetheramide (LPEtA) resin was synthesized by the condensation polymerization of N-N-bis (2-hydroxyethyl) linseed oil fatty amide (HELA) with pyrogallol. The residual hydroxyl groups of LPEtA resin were further modified with isophorone diisocyanate (IPDI) to obtain linseed poly(urethane-etheramide) (ULPEtA) via addition polymerization. ULPEtA was modified with iron oxide nanoparticles in different weight percent (0.1 wt%, 0.2 wt%, 0.3 wt% and 0.4 wt%) producing ULPEtA/Fe2O3 nanocomposite. Spectroscopic characterization of HELA, LPEtA and ULPEtA was carried out by using Fourier transform infrared (FT-IR), proton nuclear magnetic resonance (1H-NMR) and carbon nuclear magnetic resonance (13C-NMR) techniques. Physicochemical and physico-mechanical properties of LPEtA and ULPEtA were carried out by using standard methods. Thermal stability and anticorrosion performance were assessed by thermogravimetric analysis/differential scanning calorimetry (TGA/DSC) and potentiodynamic polarization. The corrosion behavior of ULPEtA/Fe2O3 nanocomposite coatings on mild steel was investigated in different corrosive environments (3.5 wt% HCl, 5.0 wt% NaCl, 3.5 wt% NaOH, and tap water) at room temperature. Surface morphology study was performed through scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). Coating properties such as gloss, scratch hardness, flexibility and impact resistance were evaluated using standard methods. The results of this study showed that ULPEtA/Fe2O3 nanocomposite coatings exhibit good physico-mechanical, anticorrosive properties and can be safely used up to 220°C.
Acknowledgments
This project was supported by King Saud University, Deanship of Scientific Research, College of Science-Research Center.
References
[1] Miranda TJ. In Surface Coatings, 3rd ed., Chapman & Hall: London, 1993, Vol. 1, p. 9.Suche in Google Scholar
[2] Schweitzer PA. Corrosion-Resistant Linings and Coatings, Marcel Dekker: New York, 2001, p. 301.10.1201/9781482270891Suche in Google Scholar
[3] Goldade VA, Pinchuk LS, Makarevich AV, Kestelman VN. Plastics for Corrosion Inhibition, Springer-Verlag: Berlin, 2005, Vol. 82, p. 175.10.1007/b138595Suche in Google Scholar
[4] Javni I, Petrovic ZS, Guo A, Fuller R. J. Appl. Polym. Sci. 2000, 77, 1723–1734.10.1002/1097-4628(20000822)77:8<1723::AID-APP9>3.0.CO;2-KSuche in Google Scholar
[5] Aigbodion AI, Pillai CKS, Bakare IO, Yahaya LE. Ind. J. Chem. Technol. 2001, 8, 378–384.Suche in Google Scholar
[6] Alam M, Akram D, Sharmin E, Zafar F, Ahmad S. Arabian J. Chem. 2014, 7, 469–479.10.1016/j.arabjc.2013.12.023Suche in Google Scholar
[7] Meshram PD, Puri RG, Patil AL, Gite VV. Prog. Org. Coat. 2013, 76, 1144–1150.10.1016/j.porgcoat.2013.03.014Suche in Google Scholar
[8] Can E, Kusefoglu S, Wool RP. J. Appl. Polym. Sci. 2002, 83, 972–980.10.1002/app.2277Suche in Google Scholar
[9] Alam M, Alandis NM. Ind. Crops Prod. 2014, 57, 17–28.10.1016/j.indcrop.2014.03.023Suche in Google Scholar
[10] Lu Y, Larock RC. ChemSusChem 2009, 2, 136–147.10.1002/cssc.200800241Suche in Google Scholar PubMed
[11] Alam M, Ashraf SM, Ray AR, Ahmad S. J. Polym Environ. 2010, 18, 208–215.10.1007/s10924-010-0177-0Suche in Google Scholar
[12] Alam M, Alandis NM. High Perform. Polym. 2012, 24, 538–545.10.1177/0954008312445227Suche in Google Scholar
[13] Alam M, Alandis NM. Prog. Org. Coat. 2012, 75, 527–536.10.1016/j.porgcoat.2012.06.001Suche in Google Scholar
[14] Alam M, Alandis NM. Anti-Corros. Methods Mater. 2014, 61, 232–240.10.1108/ACMM-01-2013-1234Suche in Google Scholar
[15] Guo A, Cho Y, Petrovic ZS. J. Polym. Sci. Part A: Polym. Chem. 2000, 38, 3900–3910.10.1002/1099-0518(20001101)38:21<3900::AID-POLA70>3.0.CO;2-ESuche in Google Scholar
[16] Petrović ZS. Polym. Rev. 2008, 48, 109–155.10.1080/15583720701834224Suche in Google Scholar
[17] Lligadas G, Ronda JC, Galia M, Cadiz V. Biomacromolecules 2010, 11, 2825–2835.10.1021/bm100839xSuche in Google Scholar PubMed
[18] Desroches M, Escouvois M, Auvergne R, Caillol S, Boutevin B. Polym. Rev. 2012, 52, 38–79.10.1080/15583724.2011.640443Suche in Google Scholar
[19] Pfister DP, Xia Y, Larock RC. ChemSusChem 2011, 4, 703–717.10.1002/cssc.201000378Suche in Google Scholar PubMed
[20] Siyanbola TO, Sasidhar K, Anjaneyulu B, Kumar KP, Rao BVSK, Narayan R, Olaofe O, Akintayo ET, Raju KVSN. J. Mater. Sci. 2013, 48, 8215–8227.10.1007/s10853-013-7633-xSuche in Google Scholar
[21] Lligadas G, Ronda JC, Galia M, Cadiz V. Biomacromolecules 2006, 7, 2420–2426.10.1021/bm060402kSuche in Google Scholar PubMed
[22] Zlatanic A, Petrovic ZS, Dusek K. Biomacromolecules 2002, 3, 1048–1056.10.1021/bm020046fSuche in Google Scholar PubMed
[23] Rahman O, Ahmad S. RSC Adv. 2014, 4, 14936–14947.10.1039/C3RA48068BSuche in Google Scholar
[24] Dhoke SK, Khanna AS. Corr. Sci. 2009, 51, 6–20.10.1016/j.corsci.2008.09.028Suche in Google Scholar
[25] Dhoke SK, Khanna AS. Mater. Chem. Phys. 2009, 117, 550–556.10.1016/j.matchemphys.2009.07.010Suche in Google Scholar
[26] Rahman O, Kashid M, Ahmad S. Prog. Org. Coat. 2015, 80, 77–86.10.1016/j.porgcoat.2014.11.023Suche in Google Scholar
[27] Alam M, Ray AR, Ashraf SM, Ahmad S. J. Am. Oil Chem. Soc. 2009, 6, 573–580.10.1007/s11746-009-1375-6Suche in Google Scholar
©2015 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Original articles
- Visualization and simulation of filling process of simultaneous co-injection molding based on level set method
- Effect of compatibilizer on the properties of PBS/lignin composites prepared via a vane extruder
- Fabrication and characterization of thermally conductive composites based on poly(butylene terephthalate)/glass fiber-silicon carbide
- Preparation and characterization of poly(MMA-EGDMA-AMPS) microspheres by soap-free emulsion polymerization
- Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin
- Investigation of synthesis and processing of cellulose, cellulose acetate and poly(ethylene oxide) nanofibers incorporating anti-cancer/tumor drug cis-diammineplatinum (II) dichloride using electrospinning techniques
- Grafting poly(2-acryloyloxyethyl trimethyl ammonium chloride) branches onto the backbones of corn starch for toughening starch film
- Erosion characteristics of Teflon under different operating conditions
- Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials
Artikel in diesem Heft
- Frontmatter
- Original articles
- Visualization and simulation of filling process of simultaneous co-injection molding based on level set method
- Effect of compatibilizer on the properties of PBS/lignin composites prepared via a vane extruder
- Fabrication and characterization of thermally conductive composites based on poly(butylene terephthalate)/glass fiber-silicon carbide
- Preparation and characterization of poly(MMA-EGDMA-AMPS) microspheres by soap-free emulsion polymerization
- Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin
- Investigation of synthesis and processing of cellulose, cellulose acetate and poly(ethylene oxide) nanofibers incorporating anti-cancer/tumor drug cis-diammineplatinum (II) dichloride using electrospinning techniques
- Grafting poly(2-acryloyloxyethyl trimethyl ammonium chloride) branches onto the backbones of corn starch for toughening starch film
- Erosion characteristics of Teflon under different operating conditions
- Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials
