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Effect of compatibilizer on the properties of PBS/lignin composites prepared via a vane extruder

  • Huan Yu Liu , Fu Quan Chen , Rui Biao Guo , GuiZhen Zhang and JinPing Qu EMAIL logo
Published/Copyright: April 1, 2015
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Abstract

Maleic anhydride (MAH) grafted polymers and silanes have been used as the compatibilizer in poly (butylene succinate)/lignin (PBS/lignin) composites. Compatibilized composites were fabricated by a novel vane extruder (VE). The effects of MAH grafted and coupling agent on the mechanical, thermal property, rheological property and water absorption of PBS/lignin were investigated. The results showed that the use of MAH grafted polymers and silanes resulted in significant improvements in flexural property, tensile modulus and tensile strength. Furthermore, MAH grafted polymers and silanes exhibited some improvement on the properties of vicat softening temperature as well as water absorption. The composites treated by MAH grafted polymers and silanes showed non-Newtonian behaviors from rheological tests. A better interfacial adhesion between lignin and matrix was observed from the scanning electron microscopy (SEM) of the compatibilized composites.


Corresponding author: JinPing Qu, The National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou 510640, Guangdong, China; and The Key Laboratory of Polymer Processing Engineering of Ministry of Education, South China University of Technology, Guangzhou 510640, Guangdong, China, e-mail:

Acknowledgments

The authors are thankful for the support of the Program for the Fundamental Research Funds for the Central Universities (2014ZB0021), 973 Program (2012CB025902), China Postdoctoral Science Foundation Funded Project (2014M560664). Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 51403068).

References

[1] Xie Y, Hill CA, Xiao Z, Militz H, Mai C. Compos. Part A: Appl. Sci. Manufac. 2010, 41, 806–819.10.1016/j.compositesa.2010.03.005Search in Google Scholar

[2] Sahoo S, Seydibeyoğlu MÖ, Mohanty AK, Misra M. Biomass Bioenergy 2011, 35, 4230–4237.10.1016/j.biombioe.2011.07.009Search in Google Scholar

[3] Li J, Luo X, Lin X. Mater. Des. 2013, 46, 902–909.10.1016/j.matdes.2012.11.054Search in Google Scholar

[4] Kadla JF, Kubo S. Compos. Part A 2004, 35, 395–400.10.1016/j.compositesa.2003.09.019Search in Google Scholar

[5] Huang J, Lu X, Zhang N, Yang L, Yan M, Liu H. Polym. Compos. 2014, 35, 53–59.10.1002/pc.22633Search in Google Scholar

[6] Shih YF, Lee WC, Jeng RJ, Huang, CM. J. Appl. Polym. Sci. 2006, 99, 188–99.10.1016/j.annemergmed.2006.07.903Search in Google Scholar

[7] Lee SM, Cho D, Park WH, Lee SG, Han SO, Drzal LT. Compos. Sci. Technol. 2005, 65, 647–657.10.1016/j.compscitech.2004.09.023Search in Google Scholar

[8] Chen F, Guo R, Feng Y, Qu J. Acta. Polym. Sin. 2014, 4, 482–490.Search in Google Scholar

[9] Feng Y, Shen H, Qu J, Liu B, He H, Han L. Polym. Eng. Sci. 2011, 51, 474–481.10.1002/pen.21852Search in Google Scholar

[10] Sahoo S, Misra M, Mohanty AK. J. Appl. Polym. Sci. 2013, 127, 4110–4121.10.1002/app.37667Search in Google Scholar

[11] Liu L, Yu J, Cheng L, Qu W. Compos. Part A: Appl. Sci. Manufac. 2009, 40, 669–674.10.1016/j.compositesa.2009.03.002Search in Google Scholar

[12] Qu JP. Patent 10026054 CN, 2008.Search in Google Scholar

[13] Chen F, Liu H, Zhao Y, Feng Y, Guo R, Wu Z. Polym. Compos. 2014, 35, 208.10.1002/pc.22652Search in Google Scholar

[14] Qu J, Chen H, Liu S, Liu S, Tan B, Liu L, Yin X. J. Appl. Polym. Sci. 2013, 128, 3576–3585.10.1002/app.38573Search in Google Scholar

[15] Qu J, Liu L, Tan B, Liu S, Liu H, Feng Y. Polym. Compos. 2012, 33, 185–191.10.1016/j.ijleo.2019.03.109Search in Google Scholar

[16] Qu J, Yang Z, Yin X, He H, Feng Y. Polym.-Plast. Technol. 2009, 48, 1269.10.1080/03602550903204121Search in Google Scholar

[17] Qu J, Zhang G, Chen H, Yin X, He H. Polym. Eng. Sci. 2012, 52, 2147–2156.10.1002/pen.23176Search in Google Scholar

[18] Qu J, Zhao X, Li J, Cai S. J. Appl. Polym. Sci. 2013, 127, 3923–3932.10.1002/app.36806Search in Google Scholar

[19] Jia S, Qu J, Zhai S, Huang Z, Wu C, Chen R, Feng Y. Polym. Compos. 2014, 35, 884–891.10.1002/pc.22732Search in Google Scholar

[20] Qu J, Zhai S, Liu H, Chen H, Jia S, Huang Z, Zhao Y, Liu L. J. Appl. Polym. Sci. 2013, 130, 842–850.10.1002/app.39231Search in Google Scholar

[21] Herrera-Franco P, Valadez-González A. Compos. Part B-Eng. 2005, 36, 597–608.10.1016/j.compositesb.2005.04.001Search in Google Scholar

[22] Valadez-Gonzalez A, Cervantes-Uc J, Olayo R, Herrera-Franco P. Compos. Part B 1999, 30, 309–320.10.1016/S1359-8368(98)00054-7Search in Google Scholar

[23] Rojo E, Oliet M, Alonso M, Saz-Orozco B, Rodriguez F. Polym. Eng. Sci. 2014, 54, 2228–2238.10.1002/pen.23772Search in Google Scholar

[24] Liu L, Yu J, Cheng L, Yang X. Polym. Degrad. Stabil. 2009, 94, 90–94.10.1016/j.polymdegradstab.2008.10.013Search in Google Scholar

[25] Gao H. The composites of wood flour/Maleic Anhydride Grafted Polyolefin Blends. PhD Thesis, Northeast Forestry University, China, 2011.Search in Google Scholar

[26] Li M. Study on the preparation and properties of poly(latic acid)/poly(butylene succinate)/jute fiber composites. PhD Thesis, JiLin University, China, 2012.Search in Google Scholar

[27] Gassan J, Bledzki AK. Compos. Part A: Appl. Sci. Manufac. 1997, 28, 1001–1005.10.1016/S1359-835X(97)00042-0Search in Google Scholar

[28] Najafi SK, Kiaefar A, Hamidina E, Tajvidi M. J. Reinf. Plast. Compos. 2007, 26, 341–348.10.1177/0731684407072519Search in Google Scholar

[29] Feng Y, Li Y, Xu B, Zhang D, Qu J, He H. Compos. Part B-Eng. 2013, 44, 193–199.10.1016/j.compositesb.2012.05.051Search in Google Scholar

Received: 2015-1-18
Accepted: 2015-3-3
Published Online: 2015-4-1
Published in Print: 2015-11-1

©2015 by De Gruyter

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