Grafting poly(2-acryloyloxyethyl trimethyl ammonium chloride) branches onto the backbones of corn starch for toughening starch film
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Zhifeng Zhu
,
Zhongqiu Zhu
Abstract
This work was undertaken to examine the effect of poly(2-acryloyloxyethyl trimethyl ammonium chloride) (PATAC) branches grafted onto the backbones of starch on the toughening of starch film. A series of starch-g-PATAC samples having different levels of grafting ratio were prepared by the graft copolymerization of granular corn starch with ATAC in an aqueous system, using Fenton’s initiator through changing the weight ratio of the monomer to starch. The influences of grafted branches on the properties such as tensile strength, breaking elongation, work-to-break, bending endurance, moisture regain, swelling power, and solubility of starch film were evaluated by comparison with those of acid-treated starch (ATS). It was found that the branches were able to toughen starch film due to the significant increases in breaking elongation, work-to-break and bending endurance of the film. The branches were also able to increase its moisture regain, water swelling power, and solubility. In addition, the properties were dependent on the amount of the branches. Furthermore, the grafted starch was biodegradable when its grafting ratio did not exceed 7.5 wt%.
Acknowledgments
Contract grant sponsor: the Research Foundation Program of Scientific and Technological Innovation Team of College and University at the Provincial Level of Anhui Province (No. TD200710), China.
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©2015 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Original articles
- Visualization and simulation of filling process of simultaneous co-injection molding based on level set method
- Effect of compatibilizer on the properties of PBS/lignin composites prepared via a vane extruder
- Fabrication and characterization of thermally conductive composites based on poly(butylene terephthalate)/glass fiber-silicon carbide
- Preparation and characterization of poly(MMA-EGDMA-AMPS) microspheres by soap-free emulsion polymerization
- Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin
- Investigation of synthesis and processing of cellulose, cellulose acetate and poly(ethylene oxide) nanofibers incorporating anti-cancer/tumor drug cis-diammineplatinum (II) dichloride using electrospinning techniques
- Grafting poly(2-acryloyloxyethyl trimethyl ammonium chloride) branches onto the backbones of corn starch for toughening starch film
- Erosion characteristics of Teflon under different operating conditions
- Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials
Artikel in diesem Heft
- Frontmatter
- Original articles
- Visualization and simulation of filling process of simultaneous co-injection molding based on level set method
- Effect of compatibilizer on the properties of PBS/lignin composites prepared via a vane extruder
- Fabrication and characterization of thermally conductive composites based on poly(butylene terephthalate)/glass fiber-silicon carbide
- Preparation and characterization of poly(MMA-EGDMA-AMPS) microspheres by soap-free emulsion polymerization
- Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin
- Investigation of synthesis and processing of cellulose, cellulose acetate and poly(ethylene oxide) nanofibers incorporating anti-cancer/tumor drug cis-diammineplatinum (II) dichloride using electrospinning techniques
- Grafting poly(2-acryloyloxyethyl trimethyl ammonium chloride) branches onto the backbones of corn starch for toughening starch film
- Erosion characteristics of Teflon under different operating conditions
- Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials
