Startseite Preparation and characterization of oxidized starch-graft-poly(styrene-butyl acrylate) latex via emulsion polymerization
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Preparation and characterization of oxidized starch-graft-poly(styrene-butyl acrylate) latex via emulsion polymerization

  • Shijie Cheng EMAIL logo , Jun Xu und Yumin Wu
Veröffentlicht/Copyright: 20. Mai 2014
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Journal of Polymer Engineering
Aus der Zeitschrift Journal of Polymer Engineering Band 34 Heft 7

Abstract

Oxidized starch-graft-poly(styrene-butyl acrylate) [OS-g-P(St-BA)] latex was synthesized by the graft copolymerization of OS with St and n-butyl acrylate (BA) via emulsion polymerization. The graft copolymers were characterized by Fourier transform infrared (FT-IR), transmission electronic microscopy (TEM), dynamic light scattering, thermogravimetry (TG), and differential scanning calorimetry (DSC). The effects of the amount of OS, monomers, and initiator on graft copolymerization were investigated. Under the optimal conditions, the percentage of graft (PG), grafting efficiency (GE), and ζ potential could reach 256.5%, 41.7%, and -30.1 mV, respectively. The results indicated that the OS grafted onto particles greatly enhanced the colloidal stability of latex. The thermal stability properties of OS-g-P(St-BA) were also improved by the addition of OS. The OS-g-P(St-BA) latex may be used to partly replace the conventional synthetic latex for paper coating.

Keywords: colloidal stability; graft; latex; oxidized starch; thermal stability
Corresponding author: Shijie Cheng, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China, e-mail:

Acknowledgments

This study was financially supported by the National Natural Science Foundation of China (No. 20876081) and the Science Foundation of Shandong Province (No. ZR2012BM015).

References

[1] Lanthong P, Nuisin R, Kiatkamjornwong S. Carbohydr. Polym. 2006, 66, 229–245.Suche in Google Scholar

[2] Sorokin AB, Kachkarova-Sorokina SL, Donze C, Pinel C, Gallezot P. Top. Catal. 2004, 27, 67–76.Suche in Google Scholar

[3] Maurer HW, Kearney RL. Starch-Stärke 1998, 50, 396–402.10.1002/(SICI)1521-379X(199809)50:9<396::AID-STAR396>3.0.CO;2-8Suche in Google Scholar

[4] Koch H, R per H. Starch-Stärke 1988, 40, 121–131.10.1002/star.19880400402Suche in Google Scholar

[5] Parovuori P, Hamunen A, Forssell P, Autio K, Poutanen K. Starch-Stärke 1995, 47, 19–23.10.1002/star.19950470106Suche in Google Scholar

[6] Du Y, Zang Y-H, Du J. Ind. Eng. Chem. Res. 2011, 50, 9781–9786.Suche in Google Scholar

[7] De Bruyn H, Sprong E, Gaborieau M, Roper III JA, Gilbert RG. J. Polym. Sci. Pol. Chem. 2007, 45, 4185–4192.Suche in Google Scholar

[8] Bertholon I, Lesieur S, Labarre D, Besnard M, Vauthier C. Macromolecules 2006, 39, 3559–3567.10.1021/ma060338zSuche in Google Scholar

[9] Xu J, Long L, Hu H. J. Polym. Eng. 2013, 33, 323–330.Suche in Google Scholar

[10] De Bruyn H, Sprong E, Gaborieau M, David G, Roper Iii JA, Gilbert RG. J. Polym. Sci. Pol. Chem. 2006, 44, 5832–5845.Suche in Google Scholar

[11] Abell S. Pulp Paper 1995, 69, 99–105.10.1016/0306-4522(95)00240-JSuche in Google Scholar

[12] Carr ME. Starch-Stärke 1992, 44, 219–223.10.1002/star.19920440605Suche in Google Scholar

[13] Zhang X, Li WL. J. Appl. Polym. Sci. 2003, 88, 1563–1566.Suche in Google Scholar

[14] Nie Y, Tian X, Liu Y, Wu K, Wang J. Polym. Compos. 2013, 34, 77–87.Suche in Google Scholar

[15] Mou J, Li X, Wang H, Fei G, Liu Q. Starch-Stärke 2012, 64, 826–834.10.1002/star.201200041Suche in Google Scholar

[16] Qu B, Li H, Niu Y. J. Polym. Eng. 2013, 33, 521–526.Suche in Google Scholar

[17] Zhang YR, Wang XL, Zhao GM, Wang YZ. Carbohydr. Polym. 2011, 87, 2554–2562.Suche in Google Scholar

[18] Song H, Zhang SF, Ma XC, Wang DZ, Yang JZ. Carbohydr. Polym. 2007, 69, 189–195.Suche in Google Scholar

[19] Gaborieau M, De bruyn H, Mange S, Castignolles P, Brockmeyer A, Gilbert RG. J. Polym. Sci. Pol. Chem. 2009, 47, 1836–1852.Suche in Google Scholar

[20] Yang SC, Ge HX, Hu Y, Jiang XQ, Yang CZ. Colloid Polym. Sci. 2000, 278, 285–292.Suche in Google Scholar

[21] Athawale VD, Lele V. Starch-Stärke 2000, 52, 205–213.10.1002/1521-379X(200007)52:6/7<205::AID-STAR205>3.0.CO;2-3Suche in Google Scholar

Received: 2014-2-25
Accepted: 2014-4-24
Published Online: 2014-5-20
Published in Print: 2014-9-1

©2014 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Editorial improvements at the Journal of Polymer Engineering
  4. Original articles
  5. Cationic copolymerization of 1,3-pentadiene with α-pinene
  6. In vitro degradation of polyglycolic acid synthesized by a one-step reaction
  7. Synthesis of a novel class of mixed-type surfmers and their properties in water
  8. Unique viscosity mutation of multi-generation hyperbranched waterborne polyurethane
  9. Preparation and characterization of oxidized starch-graft-poly(styrene-butyl acrylate) latex via emulsion polymerization
  10. Peroxide vulcanization of natural rubber. Part I: effect of temperature and peroxide concentration
  11. The stimuli-response characters of hydrogels prepared using ultrasound
  12. A new conductometric biosensor based on horseradish peroxidase immobilized on chitosan and chitosan/gold nanoparticle films
  13. A new approach for the development of textile waste cotton reinforced composites (T-FRP): laminated hybridization vs. coupling agents
  14. Effects of the surface treatment of wollastonite on the tensile and flow properties for reinforced polypropylene composites
  15. Effect of the quenching temperature on the mechanical and thermophysical properties of polycarbonate pigmented with titanium dioxide
  16. Processing and characterization of poly(lactic acid) blended with polycarbonate and chain extender
  17. Characteristics analysis and mold design for ultrasonic-assisted injection molding
https://doi.org/10.1515/polyeng-2014-0047
Schlagwörter für diesen Artikel
colloidal stability; graft; latex; oxidized starch; thermal stability

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Editorial improvements at the Journal of Polymer Engineering
  4. Original articles
  5. Cationic copolymerization of 1,3-pentadiene with α-pinene
  6. In vitro degradation of polyglycolic acid synthesized by a one-step reaction
  7. Synthesis of a novel class of mixed-type surfmers and their properties in water
  8. Unique viscosity mutation of multi-generation hyperbranched waterborne polyurethane
  9. Preparation and characterization of oxidized starch-graft-poly(styrene-butyl acrylate) latex via emulsion polymerization
  10. Peroxide vulcanization of natural rubber. Part I: effect of temperature and peroxide concentration
  11. The stimuli-response characters of hydrogels prepared using ultrasound
  12. A new conductometric biosensor based on horseradish peroxidase immobilized on chitosan and chitosan/gold nanoparticle films
  13. A new approach for the development of textile waste cotton reinforced composites (T-FRP): laminated hybridization vs. coupling agents
  14. Effects of the surface treatment of wollastonite on the tensile and flow properties for reinforced polypropylene composites
  15. Effect of the quenching temperature on the mechanical and thermophysical properties of polycarbonate pigmented with titanium dioxide
  16. Processing and characterization of poly(lactic acid) blended with polycarbonate and chain extender
  17. Characteristics analysis and mold design for ultrasonic-assisted injection molding
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2014-0047/pdf?lang=de
Button zum nach oben scrollen