Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization

Hamid Javaherian Naghash; Mohammad Hossein Sheikhbahaei

doi:10.1515/polyeng-2013-0156

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Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization

Hamid Javaherian Naghash and Mohammad Hossein Sheikhbahaei

Published/Copyright: November 23, 2013

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From the journal Journal of Polymer Engineering Volume 33 Issue 9

Abstract

A novel silicone-containing acrylic monomer, trimethylsiloxybutoxy dimethylsiloxybutyl acrylate (TSBA) and diethylene glycol monoallyl ether (DGME) was synthesized successfully. Then, a novel copolymeric surfactant was prepared by the free radical polymerization of TSBA and DGME in the presence of dioxane and azobisisobutyronitrile (AIBN) as a solvent and initiator, respectively. Next, a series of polyvinyl acetate (PVAc), 2-ethylhexyl acrylate (2-EHA) and polystyrene (PSt) latexes were successfully synthesized, each one throughout by the emulsion copolymerization in the presence of a copolymeric surfactant. This copolymeric surfactant exhibited excellent surface activity and the surface tension decreased with an increase in the concentration of the copolymeric surfactant.

Keywords: : copolymeric surfactant; diethylene glycol monoallyl ether; siliconated acrylic copolymer; surface tension

Corresponding author: Hamid Javaherian Naghash, Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, I. R. Iran, e-mail: Javaherian@iaush.ac.ir

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Received: 2013-7-3

Accepted: 2013-9-20

Published Online: 2013-11-23

Published in Print: 2013-12-01

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Articles in the same Issue

https://doi.org/10.1515/polyeng-2013-0156

Keywords for this article

copolymeric surfactant; diethylene glycol monoallyl ether; siliconated acrylic copolymer; surface tension