Abstract
Rigid polyurethane foams are one of the most important cellular plastics. Castor oil was modified with glycerol to form the polyol and reacted with methyl diisocyanate and different proportions of silicon oil to achieve rigid polyurethane foam. Prepared foam was tested for its density and mechanical properties. It was found that compressive and flexural strength was improved with silicon oil content. The morphology of the resulted foams was also studied using scanning electron microscope, and it was observed that the cell size was reduced with silicon oil content, indicating a more dense and packed structure. With further increase in the silicon oil content, foam properties showed a slight decrease in value.
References
[1] Tan TTM. Polym. Intl. 1996, 1, 13–16.Search in Google Scholar
[2] Saraf VP, Glasser WG, Wilkes GL. J. Appl. Poly. Sci. 1985, 30, 3809–3823.Search in Google Scholar
[3] Nakamura K, Morck R, Reimann A, Krigstad KP, Hatakeyama H. Polym. Adv. Technol. 1991, 2, 41–47.Search in Google Scholar
[4] Kendaganna Swamy BK, Siddaramaiah, SR. J. Mater. Sci. 2003, 38, 451–460.Search in Google Scholar
[5] Alma MH, Basturk MA, Digrak M. J. Mater. Sci. Lett. 2003, 22, 1225–1228.Search in Google Scholar
[6] Lim H, Kim SH, Kim BK. Express Polym. Lett. 2008, 2, 194–200.Search in Google Scholar
[7] Modesti M, Baldoin N, Simioni F. Eur. Polym. J. 1998, 34, 1233–1241.Search in Google Scholar
[8] Lee CS, Ooi TL, Chuah CH, Ahmad S. J. Am. Oil Chem. Soc. 2007, 84, 1161–1167.Search in Google Scholar
[9] Akintayo CO, Akintaya ET. Adv. Nat. Appl. Sci. 2010, 4, 210–215.Search in Google Scholar
[10] Yang LT, Zhao CS, Dai CL, Fu LY, Lin SQ. Polym. Environ. 2012, 20, 230–236.Search in Google Scholar
[11] Zlantic A, Lava C, Zhang W, Petrovic ZS. J. Polym. Sci., Part B: Polym. Phy. 2004, 42, 809–819.Search in Google Scholar
[12] Ehrlich A, Smith MK, Patton TC. J. Am. Oil Chem. Soc. 1959, 36, 149–154.Search in Google Scholar
[13] Leitheiser RH, Peloza CC, Lyon CK. J. Cell. Plast. 1969, 5, 364–372.Search in Google Scholar
[14] Guo A, Demydoy D, Zhang W, Petrovic ZS. J. Polym. Environ. 2002, 10, 49–52.Search in Google Scholar
[15] Petrovic ZS. Polym. Rev. 2008, 48, 109–155.Search in Google Scholar
[16] Goldblatt LA, Lyon CK. J. Am. Oil Chem. Soc. 1963, 40, 157–161.Search in Google Scholar
[17] Monteavaro LL, Silva EOD, Costa APO, Samois D, Gerbase EG, Petzhold CL. J. Am. Oil. Chem. Soc. 2005, 82, 365–371.Search in Google Scholar
[18] Guo A, Zhang W, Petrovic ZS. J. Mater. Sci. 2006, 41, 4914–4920.Search in Google Scholar
[19] Chian KS, Gan LH. J. Appl. Polym. Sci. 1998, 68, 509–515.Search in Google Scholar
[20] Krupers MJ, Bartelink CF, Grünhauer H, Moller M. Polymer 1998, 39, 2049–2053.10.1016/S0032-3861(87)00375-6Search in Google Scholar
[21] Tu YC. Polyurethane Foams from Novel Soy-Based Polyols, Ph.D. Dissertation, University of Missouri: Columbia, 2008.Search in Google Scholar
[22] Kapps M, Buschkamp S. The production of rigid polyurethane foam Tech. Info., Bayer Material Science Co.: Leverkusen, Germany, 2004.Search in Google Scholar
[23] Shah V. Handbook of Plastic Testing and Failure Analysis, 3rd ed., Wiley-Interscience: Hoboken, New Jersey, 2007.Search in Google Scholar
[24] Zhang XD, Macosko CW, Davis HT, Nikolov AD, Wasan DT. J. Colloid Interface Sci. 1999, 215, 270–279.Search in Google Scholar
[25] Gedde UW. Polymer Physics, Chapman and Hall: London, 1995.Search in Google Scholar
[26] Oertel G. Polyurethane Handbook, Hanser Publishers: New York, 1985.Search in Google Scholar
[27] Szycher M. Szycher’s Handbook of Polyurethanes, CRC Press: New York, 1999.10.1201/9781482273984Search in Google Scholar
©2013 by Walter de Gruyter Berlin Boston
Articles in the same Issue
- Masthead
- Masthead
- Original articles
- Solvent-initiator compatibility and sensitivity of conversion of styrene homo-polymerization
- Synthesis and effect of secondary dopant on the conductivity of conducting polymer polyaniline
- Potential utilization of recycled PET in comparison with liquid crystalline polymer as an additive for HDPE based composite fibers: Comparative investigation on mechanical performance of cross-ply laminates
- Study on the effect of virgin and recycled chloroprene rubber (vCR and rCR) on the properties of natural rubber/chloroprene rubber (NR/CR) blends
- Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization
- Post-irradiation effects on gamma-irradiated nylon 6,12 fibers
- Preparation and properties of sodium alginate films
- Study on crystallization and compatibility of nitrile butadiene rubber (NBR)/polyoxymethlene (POM) blends modified by a polyether polyol
- Polyamide grafting onto ethylene-vinyl alcohol copolymer
- Acoustic parameter investigation of polyvinyl acetate with acetic acid using ultrasonic technique
- Electrospun cellulosic structure nanofibre based on rice straw
- Function of silicon oil in the castor oil based rigid polyurethane foams
Articles in the same Issue
- Masthead
- Masthead
- Original articles
- Solvent-initiator compatibility and sensitivity of conversion of styrene homo-polymerization
- Synthesis and effect of secondary dopant on the conductivity of conducting polymer polyaniline
- Potential utilization of recycled PET in comparison with liquid crystalline polymer as an additive for HDPE based composite fibers: Comparative investigation on mechanical performance of cross-ply laminates
- Study on the effect of virgin and recycled chloroprene rubber (vCR and rCR) on the properties of natural rubber/chloroprene rubber (NR/CR) blends
- Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization
- Post-irradiation effects on gamma-irradiated nylon 6,12 fibers
- Preparation and properties of sodium alginate films
- Study on crystallization and compatibility of nitrile butadiene rubber (NBR)/polyoxymethlene (POM) blends modified by a polyether polyol
- Polyamide grafting onto ethylene-vinyl alcohol copolymer
- Acoustic parameter investigation of polyvinyl acetate with acetic acid using ultrasonic technique
- Electrospun cellulosic structure nanofibre based on rice straw
- Function of silicon oil in the castor oil based rigid polyurethane foams