Modeling of tensile modulus of polyolefin-layered silicate nanocomposites: modified micro-mechanical and statistical methods
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Vikas Mittal
Abstract
Applicability and subsequent modification of various composite models for the prediction of the relative tensile modulus of polyolefin nanocomposites has been studied. A number of models, such as the modified Halpin-Tsai, Guth, Mori-Tanaka, Hui and Shia and Takayanagi models, as well as factorial and mixture designs, were considered. Various assumptions in the models, such as uniform shape and size of filler (i.e., complete exfoliation), alignment, as well as interfacial bonding between the components, restrict their application for the prediction of the nanocomposite modulus. The modified Guth model and Halpin-Tsai model, with the ∅m concept, were developed further to incorporate the modulus reduction factors for polyolefin nanocomposites. This allowed the generation of master curves of the modulus reduction factor as a function of the aspect ratio of the filler in the composite. It was observed that the Mori Tanaka model, modified by constructing models of various representative volume elements (RVEs) of the underlying structure of the nanoclay filled polymers, matched the experimental values of the tensile modulus of polyolefin nanocomposites. The modified Hui and Shia model, incorporating the non-bonding interfacial effects, as well as the three component modified Takayanagi model, were also able to predict the tensile modulus of polyolefin nanocomposites efficiently. Factorial and mixture designs did not require the conventionally used assumptions and satisfactorily reflected the material behavior, and were specific to the particular components used to generate nanocomposites. These models were also helpful in predicting the aspect ratio of the filler in the composites, when synergistically combined with other modified models.
©2012 by Walter de Gruyter Berlin Boston
Artikel in diesem Heft
- Masthead
- Masthead
- Original Articles
- Sensitivity analysis of free-volume theory parameters in multicomponent polymer-solvent-solvent systems
- Effect of intercalant types on the properties of melt blended metallocene polyethylene/metallocene polyethylene-g-silane/clay nanocomposites
- Compatibilization and toughening of immiscible ternary blends of polyamide 1010, polypropylene, and ABS resin
- Clay modification with silane compounds and characterization of the silicone rubber/clay composites
- Effects of surface treatments of AA 2024-T3 aluminum sheet on bonding to epoxy-based film adhesive
- Thermooxidative degradation and its kinetics of natural rubber coagulated by microwave radiation
- Modeling of tensile modulus of polyolefin-layered silicate nanocomposites: modified micro-mechanical and statistical methods
- Comparative study and characterization of starches isolated from unconventional tuber sources
- Unsaturated polyester/E-glass fiber composites made by vacuum assisted compression resin transfer molding
- Influence of stacking sequence on mechanical properties of basalt-jute fiber-reinforced polymer hybrid composites
- Effect of processing variables on mechanical properties of montmorillonite clay/unsaturated polyester nanocomposite using Taguchi based grey relational analysis
- Study on DTBP initiated MAH onto polybutene-1 with melt-grafting
- Investigation of rapid manufacturing technology with ABS material for wind tunnel models fabrication
- Potential solvent for reconditioning polyolefin waste materials
Artikel in diesem Heft
- Masthead
- Masthead
- Original Articles
- Sensitivity analysis of free-volume theory parameters in multicomponent polymer-solvent-solvent systems
- Effect of intercalant types on the properties of melt blended metallocene polyethylene/metallocene polyethylene-g-silane/clay nanocomposites
- Compatibilization and toughening of immiscible ternary blends of polyamide 1010, polypropylene, and ABS resin
- Clay modification with silane compounds and characterization of the silicone rubber/clay composites
- Effects of surface treatments of AA 2024-T3 aluminum sheet on bonding to epoxy-based film adhesive
- Thermooxidative degradation and its kinetics of natural rubber coagulated by microwave radiation
- Modeling of tensile modulus of polyolefin-layered silicate nanocomposites: modified micro-mechanical and statistical methods
- Comparative study and characterization of starches isolated from unconventional tuber sources
- Unsaturated polyester/E-glass fiber composites made by vacuum assisted compression resin transfer molding
- Influence of stacking sequence on mechanical properties of basalt-jute fiber-reinforced polymer hybrid composites
- Effect of processing variables on mechanical properties of montmorillonite clay/unsaturated polyester nanocomposite using Taguchi based grey relational analysis
- Study on DTBP initiated MAH onto polybutene-1 with melt-grafting
- Investigation of rapid manufacturing technology with ABS material for wind tunnel models fabrication
- Potential solvent for reconditioning polyolefin waste materials
