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Solvation heterogeneity in ionic liquids as demonstrated by photo-chemical reactions

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Published/Copyright: February 28, 2020
Pure and Applied Chemistry
From the journal Pure and Applied Chemistry Volume 92 Issue 10

Abstract

It has been recognised that ionic liquids (ILs) with long alkyl-chains have a segregated structure due to the inhomogeneous distribution of polar parts and non-polar parts. This inhomogeneity of ILs brings about unique solvation phenomena of solute molecules dissolved in ILs. We have investigated various solvation-state selective phenomena by using laser spectroscopic techniques such as solvation state selective vibrational spectroscopy, translational and rotational dynamics of small molecules in ILs, and solvation state selective fundamental chemical reactions. In this paper, we have reviewed an intramolecular electron transfer (ET) reaction in the Marcus inverted region of N,N-dimethyl-p-nitroaniline and an intramolecular proton transfer (IPT) reaction in 4′-N,N-diethylamino-3-hydroxyflavone as examples of chemical reactions affected by unique solvation in ILs.

Keywords: excitation wavelength dependence; heterogenous structure; ICSC-36; intramolecular electron transfer; intramolecular proton transfer; ionic liquids

Article note

A collection of invited papers based on presentations at the 36th International Conference of Solution Chemistry (ICSC-36), held in Xining, China, 4–8 August 2019.

Corresponding author: Yoshifumi Kimura, Department of molecular science and biochemistry, Faculty of science and engineering, Doshisha University, Kyotanabe-city, Kyoto 610-0321, Japan, E-mail:

Acknowledgement

The author is very grateful to the co-workers of the original papers. Our works presented here are mainly supported by Grants-in-Aid for Scientific Research from JSPS (Grant Nos. 16350010, 17073012, 23350006, and 17KT0012, Funder Id: http://dx.doi.org/10.13039/501100001691) and partially supported by the MEXT-Supported Program for the Strategic Research Foundation at Private Universities 2015–2019 (S1511025, Funder Id: http://dx.doi.org/10.13039/501100001700).

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Published Online: 2020-02-28
Published in Print: 2020-10-25

©2020 IUPAC & De Gruyter. This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. For more information, please visit: http://creativecommons.org/licenses/by-nc-nd/4.0/

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Selected papers from the 36th International Conference on Solution Chemistry (ICSC-36)
  5. Conference papers
  6. Using computational chemistry to explore experimental solvent parameters – solvent basicity, acidity and polarity/polarizability
  7. Solution chemistry in the surface region of aqueous solutions
  8. Water confined in solutions of biological relevance
  9. Real-time in-situ 1H NMR of reactions in peptide solution: preaggregation of amyloid-β fragments prior to fibril formation
  10. Free energy profile of permeation of Entecavir through Hepatitis B virus capsid studied by molecular dynamics calculation
  11. Dielectric relaxation spectroscopy: an old-but-new technique for the investigation of electrolyte solutions
  12. Excess spectroscopy and its applications in the study of solution chemistry
  13. Structure of aqueous sodium acetate solutions by X-Ray scattering and density functional theory
  14. Desymmetrization in geometry optimization: application to an ab initio study of copper(I) hydration
  15. Interactions between adsorbents and adsorbates in aqueous solutions
  16. Modeling vapor-liquid-liquid-solid equilibrium for acetone-water-salt system
  17. Apparent molar volumes of sodium arsenate aqueous solution from 283.15 K to 363.15 K at ambient pressure: an experimental and thermodynamic modeling study
  18. Extraction of various metal ions by open-chain crown ether bridged diphosphates in supercritical carbon dioxide
  19. Solvation heterogeneity in ionic liquids as demonstrated by photo-chemical reactions
  20. The structure and composition of solid complexes comprising of Nd(III), Ca(II) and D-gluconate isolated from solutions relevant to radioactive waste disposal
  21. Separation of phenols from oils using deep eutectic solvents and ionic liquids
https://doi.org/10.1515/pac-2019-1116
Keywords for this article
excitation wavelength dependence; heterogenous structure; ICSC-36; intramolecular electron transfer; intramolecular proton transfer; ionic liquids

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Selected papers from the 36th International Conference on Solution Chemistry (ICSC-36)
  5. Conference papers
  6. Using computational chemistry to explore experimental solvent parameters – solvent basicity, acidity and polarity/polarizability
  7. Solution chemistry in the surface region of aqueous solutions
  8. Water confined in solutions of biological relevance
  9. Real-time in-situ 1H NMR of reactions in peptide solution: preaggregation of amyloid-β fragments prior to fibril formation
  10. Free energy profile of permeation of Entecavir through Hepatitis B virus capsid studied by molecular dynamics calculation
  11. Dielectric relaxation spectroscopy: an old-but-new technique for the investigation of electrolyte solutions
  12. Excess spectroscopy and its applications in the study of solution chemistry
  13. Structure of aqueous sodium acetate solutions by X-Ray scattering and density functional theory
  14. Desymmetrization in geometry optimization: application to an ab initio study of copper(I) hydration
  15. Interactions between adsorbents and adsorbates in aqueous solutions
  16. Modeling vapor-liquid-liquid-solid equilibrium for acetone-water-salt system
  17. Apparent molar volumes of sodium arsenate aqueous solution from 283.15 K to 363.15 K at ambient pressure: an experimental and thermodynamic modeling study
  18. Extraction of various metal ions by open-chain crown ether bridged diphosphates in supercritical carbon dioxide
  19. Solvation heterogeneity in ionic liquids as demonstrated by photo-chemical reactions
  20. The structure and composition of solid complexes comprising of Nd(III), Ca(II) and D-gluconate isolated from solutions relevant to radioactive waste disposal
  21. Separation of phenols from oils using deep eutectic solvents and ionic liquids
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