Startseite The in situ green synthesis of metal organic framework (HKUST-1)/cellulose/chitosan composite aerogel (CSGA/HKUST-1) and its adsorption on tetracycline
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

The in situ green synthesis of metal organic framework (HKUST-1)/cellulose/chitosan composite aerogel (CSGA/HKUST-1) and its adsorption on tetracycline

  • Tianhao Wang , Luyang Wang , Shun Liu , Lin Chen , Xin Jin , Haitang Liu ORCID logo EMAIL logo und Xiaoyuan Liao EMAIL logo
Veröffentlicht/Copyright: 19. Dezember 2024
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Nordic Pulp & Paper Research Journal
Aus der Zeitschrift Nordic Pulp & Paper Research Journal Band 40 Heft 1

Abstract

In this work, a strategy of in situ 3D hierarchical porous HKUST-1/cellulose/chitosan (CSGA/HKUST-1) composite aerogels were synthesized using ethylene glycol diglycidyl ether (EGDE) as a cross-linking agent. The effect of EGDE on CSGA/HKUST-1 and the adsorption of tetracycline (TC) was investigated: the composite aerogel (CSGA) was produced by the ring-opening reaction of the epoxy group of EGDE in alkaline solution. The chemical structure of CSGA/HKUST-1 composite aerogel was characterized by FT-IR, XRD and XPS.49.33 % mass loading of CSGA1/HKUST-1 was achieved and N2 adsorption and desorption experiment showed the BET specific surface area reached 694.514 m2 g−1. SEM observed the CSGA/HKUST-1 composite aerogel pores were filled with a large number of octahedral HKUST-1 crystal particles. CSGA/HKUST-1 composite aerogel has excellent tetracycline adsorption capacity (285.7 mg g−1), and the removal efficiency remained at 92.7 % after five cycles of adsorption–desorption. The pseudo-second-order kinetic model and Langmuir model adsorption mechanism was successfully concluded. This study can provide ideas for in situ synthesis of MOFs on 3D composite aerogel to prepare adsorption materials, improve the mass loading rate of MOFs and prevent MOFs from falling off, etc., and enrich the application of MOFs materials in the treatment of antibiotic pollutants.

Keywords: Solvothermal method; water treatment; reusable; In-situ green synthetic; tetracycline; environmental protection
Corresponding authors: Haitang Liu and Xiaoyuan Liao, State Key Laboratory of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457, P.R. China; Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin, 300457, P.R. China; and China Light Industry Key Laboratory of Papermaking and Biorefinery, Tianjin University of Science and Technology, Tianjin, 300457, P.R. China, E-mail: (H. Liu), (X. Liao).
Tianhao Wang and Luyang Wang are co-first authors and contributed equally to this work.

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: no. 31700516

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: Tianhao Wang: writing, reviewing. Luyang Wang: writing, reviewing. Shun Liu: editing. Lin Chen: conceptualization, methodology, software, investigation, drawing application, data curation, writing – original draft preparation, Xin Jin: software, writing, reviewing. Haitang Liu: supervision, funding acquisition, conceptualization, writing – review & editing.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: This work was supported by the National Natural Science Foundation of China (no. 31700516).

  7. Data availability: The raw data can be obtained on request from the corresponding author.

References

Ahmadijokani, F., Molavi, H., Bahi, A., Fernández, R., Alaee, P., Wu, S., Wuttke, S., Ko, F., and Arjmand, M. (2022). Metal-organic frameworks and electrospinning: a happy marriage for wastewater treatment. Adv. Funct. Mater. 32, https://doi.org/10.1002/adfm.202207723.Suche in Google Scholar

Ambaye, T.G., Vaccari, M., Prasad, S., van Hullebusch, E.D., Rtimi, S. (2022). Preparation and applications of chitosan and cellulose composite materials. J. Environ. Manage. 301: 113850, https://doi.org/10.1016/J.JENVMAN.2021.113850.Suche in Google Scholar PubMed

Bingbing, Y., Yang, L., Zhiyin, L., Yanan, L., Pinhua, R., and Guanghui, L. (2022). Durable substrates incorporated with MOFs: recent advances in engineering strategies and water treatment applications. Chem. Eng. J. 455(P2), https://doi.org/10.1016/j.cej.2022.140840.Suche in Google Scholar

Blaga, A.C., Zaharia, C., and Suteu, D. (2021). Polysaccharides as support for microbial biomass-based adsorbents with applications in removal of heavy metals and dyes. Polymers 13: 2893, https://doi.org/10.3390/polym13172893.Suche in Google Scholar PubMed PubMed Central

Cesco, C.T., Valente, A.J.M., and Paulino, A.T. (2021). Methylene blue release from chitosan/pectin and chitosan/DNA blend hydrogels. Pharmaceutics 13: 842, https://doi.org/10.3390/PHARMACEUTICS13060842.Suche in Google Scholar PubMed PubMed Central

Cheng, H., Gu, B., Pennefather, M.P., Nguyen, T.X., Phan-Thien, N., and Duong, H.M. (2017). Cotton aerogels and cotton-cellulose aerogels from environmental waste for oil spillage cleanup. Mater. Des. 130: 452–458, https://doi.org/10.1016/j.matdes.2017.05.082.Suche in Google Scholar

Chiam, S.-L., Pung, S.-Y., and Yeoh, F.-Y. (2020). Recent developments in MnO2-based photocatalysts for organic dye removal: a review. Environ. Sci. Pollut. Res. 27: 5759–5778, https://doi.org/10.1007/s11356-019-07568-8.Suche in Google Scholar PubMed

Chung, C., Lee, M., and Choe, E. (2004). Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr. Polym. 58: 417–420, https://doi.org/10.1016/j.carbpol.2004.08.005.Suche in Google Scholar

Dongxue, H., Hongjie, Z., Lili, G., Zhihui, Q., Jinming, M., Yong, H., and Tifeng, J. (2021). Preparation of carboxymethyl chitosan/phytic acid composite hydrogels for rapid dye adsorption in wastewater treatment. Colloids Surf., A 628: 127355, https://doi.org/10.1016/j.colsurfa.2021.127355.Suche in Google Scholar

Du, L., Ahmad, S., Liu, L., Wang, L., and Tang, J. (2023). A review of antibiotics and antibiotic resistance genes (ARGs) adsorption by biochar and modified biochar in water. Sci. Total Environ. 858: 159815, https://doi.org/10.1016/j.scitotenv.2022.159815.Suche in Google Scholar PubMed

Duong, H.M., Lim, Z.K., Nguyen, T.X., Gu, B., Penefather, M.P., and Phan-Thien, N. (2018). Compressed hybrid cotton aerogels for stopping liquid leakage. Colloids Surf., A 537: 502–507, https://doi.org/10.1016/j.colsurfa.2017.10.067.Suche in Google Scholar

El Messaoudi, N., El Khomri, M., El Mouden, A., Bouich, A., Jada, A., Lacherai, A., Iqbal, H.M.N., Mulla, S.I., Kumar, V., and Americo-Pinheiro, J.H.P. (2022). Regeneration and reusability of non-conventional low-cost adsorbents to remove dyes from wastewaters in multiple consecutive adsorption-desorption cycles: a review. Biomass Convers. Biorefin. 14: 11739–11756, https://doi.org/10.1007/s13399-022-03604-9.Suche in Google Scholar

Gaeta, M., Sanfilippo, G., Fraix, A., Sortino, G., Barcellona, M., Oliveri Conti, G., Elena Fragalà, M., Ferrante, M., Purrello, R., and D’Urso, A. (2020). Photodegradation of antibiotics by noncovalent porphyrin-functionalized TiO2 in water for the bacterial antibiotic resistance risk management. Int. J. Mol. Sci. 21: 3775, https://doi.org/10.3390/ijms21113775.Suche in Google Scholar PubMed PubMed Central

Geng, H.J. (2018). A facile approach to light weight, high porosity cellulose aerogels. Int. J. Biol. Macromol. 118:921–931, https://doi.org/10.1016/j.ijbiomac.2018.06.167.Suche in Google Scholar PubMed

Geng, H.J., Qin, M.H., Li, J.L.. A facile approach to cellulose/multi-walled carbon nanotube gels-Structure, formation process and adsorption to methylene blue. Int. J. Biol. Macromol., 2022, 217:417–427, https://doi.org/10.1016/J.IJBIOMAC.2022.07.076.Suche in Google Scholar

Goyal, P., Paruthi, A., Menon, D., Behara, R., Jaiswal, A., V, K., Kumar, A., Krishnan, V., and Misra, S.K. (2022a). Fe doped bimetallic HKUST-1 MOF with enhanced water stability for trapping Pb(II) with high adsorption capacity. Chem. Eng. J. 430: 133088, https://doi.org/10.1016/j.cej.2021.133088.Suche in Google Scholar

Goyal, P., Paruthi, A., Menon, D., Behara, R., Jaiswal, A., Keerthy, V., Kumar, A., Krishnan, V., and Misra, Superb K. (2022b). Fe doped bimetallic HKUST-1 MOF with enhanced water stability for trapping Pb(II) with high adsorption capacity. Chem. Eng. J. 430: 133088, https://doi.org/10.1016/J.CEJ.2021.133088.Suche in Google Scholar

Gupta, S., Graham, D.W., Sreekrishnan, T.R., and Ahammad, S.Z. (2022). Heavy metal and antibiotic resistance in four Indian and UK rivers with different levels and types of water pollution. Sci. Total Environ. 857: 159059, https://doi.org/10.1016/J.SCITOTENV.2022.159059.Suche in Google Scholar

Hammi, N., Chen, S., Primo, A., Royer, S., Garcia, H., and El Kadib, A. (2022). Shaping MOF oxime oxidation catalysts as three-dimensional porous aerogels through structure-directing growth inside chitosan microspheres. Green Chem. 24: 4533–4543, https://doi.org/10.1039/d2gc00097k.Suche in Google Scholar

Han, S., Ciufo, R.A., Meyerson, M.L., Keitz, B.K., and Mullins, B. (2019). Solvent-free vacuum growth of oriented HKUST-1 thin films. J. Mater. Chem. A 7: 19396–19406, https://doi.org/10.1039/C9TA90298H.Suche in Google Scholar

H.P.S, Abdul Khalil, Saurabh, Chaturbhuj K., A.S, Adnan, Nurul Fazita, M.R., Syakir, M.I., Davoudpour, Y., Rafatullah, M., Abdullah, C.K., Haafiz, M.K.M., and Dungani, R. (2016). A review on chitosan-cellulose blends and nanocellulose reinforced chitosan biocomposites: properties and their applications. Carbohydr. Polym., https://doi.org/10.1016/j.carbpol.2016.05.028.Suche in Google Scholar PubMed

Huang, H., Ge, H., Song, J., Yao, Y., Chen, Q., and Xu, M. (2018). NMR study on the roles of Li+ in the cellulose dissolution process. ACS Sustain. Chem. Eng. 7: 618–624, https://doi.org/10.1021/acssuschemeng.8b04177.Suche in Google Scholar

Huang, G., Li, Y., Qin, Z., Liang, Q., Xu, C., Lin, B. (2020). Hybridization of carboxymethyl chitosan with MOFs to construct recyclable, long-acting and intelligent antibacterial agent carrier. Carbohydr. Polym. 233: 115848, https://doi.org/10.1016/j.carbpol.2020.115848.Suche in Google Scholar PubMed

Jeong, C., Ansari, M.Z., Hakeem Anwer, A., Kim, S.-H., Nasar, A., Shoeb, M., and Mashkoor, F. (2023). A review on metal-organic frameworks for the removal of hazardous environmental contaminants. Sep. Purif. Technol. 305: 122416, https://doi.org/10.1016/j.seppur.2022.122416.Suche in Google Scholar

Karkhani, R. and Javanbakht, V. (2022). A polyurethane foam membrane filled with double cross-linked chitosan/carboxymethyl cellulose gel and decorated with ZSM-5 nano zeolite: simultaneous dye removal. Int. J. Biol. Macromol. 213: 699–717, https://doi.org/10.1016/J.IJBIOMAC.2022.05.120.Suche in Google Scholar

Li, L., Liu, X.L., Geng, H.Y., Hu, B., Song, G.W., and Xu, Z.S. (2013). A MOF/graphite oxide hybrid (MOF: HKUST-1) material for the adsorption of methylene blue from aqueous solution. J. Mater. Chem. A 1: 10292–10299, https://doi.org/10.1039/C3TA11478C.Suche in Google Scholar

Li, C.J., Zhang, Y.J., Chen, H., He, P.Y., and Meng, Q. (2022). Development of porous and reusable geopolymer adsorbents for dye wastewater treatment. J. Cleaner Prod. 348: 131278, https://doi.org/10.1016/j.jclepro.2022.131278.Suche in Google Scholar

Liang, X., Duan, J., Xu, Q., Wei, X., Lu, A., Zhang, L. (2017). Ampholytic microspheres constructed from chitosan and carrageenan in alkali/urea aqueous solution for purification of various wastewater. Chem. Eng. J. 317: 766–776, https://doi.org/10.1016/j.cej.2017.02.089.Suche in Google Scholar

Liu, Q., Yu, H., Zeng, F., Li, X., Sun, J., Li, C., Lin, H., and Su, Z. (2021a). HKUST-1 modified ultrastability cellulose/chitosan composite aerogel for highly efficient removal of methylene blue. Carbohydr. Polym. 255: 117402, https://doi.org/10.1016/j.carbpol.2020.117402.Suche in Google Scholar PubMed

Liu, J., Dong, Y., Zhang, L., Liu, W., Zhang, C., Shi, Y., and Lin, H. (2021b). Regulating superoxide radicals and light absorption ability for enhancing photocatalytic performance of MoS2@Z by CeO2 rich in adsorbed oxygen. J. Cleaner Prod. 322: 129059, https://doi.org/10.1016/J.JCLEPRO.2021.129059.Suche in Google Scholar

Liu, A., Liu, J., He, S., Zhang, J., and Shao, W. (2022). Bimetallic MOFs loaded cellulose as an environment friendly bioadsorbent for highly efficient tetracycline removal. Int. J. Biol. Macromol. 225: 40–50, https://doi.org/10.1016/j.ijbiomac.2022.11.321.Suche in Google Scholar PubMed

Ma, X., Wang, L., Wang, H., Deng, J., Song, Y., Li, Q., Li, X., and Andrea, M. D. (2022). Insights into metal-organic frameworks HKUST-1 adsorption performance for natural organic matter removal from aqueous solution. J. Hazard. Mater. 424: 126918, https://doi.org/10.1016/J.JHAZMAT.2021.126918.Suche in Google Scholar PubMed

Maru, K., Kalla, S., and Jangir, R. (2021). Dye contaminated wastewater treatment through metal–organic framework (MOF) based materials. New J. Chem. 46: 3054–3072, https://doi.org/10.1039/d1nj05015j.Suche in Google Scholar

Mason, A., Soprani, M., Cullen, J., Muradov, M., Carmona, S.N., Sberveglieri, G., Sberveglieri, V., and Al-Shamma’ a, A. (2018). Real-time microwave, dielectric, and optical sensing of lincomycin and tylosin antibiotics in water: sensor fusion for environmental safety. J. Sensors 2018: 1–11, https://doi.org/10.1155/2018/7976105.Suche in Google Scholar

Masoomi, M.Y., Morsali, A., Dhakshinamoorthy, A., and Garcia, H. (2019). Mixed-metal MOFs: unique opportunities in metal-organic framework (MOF) functionality and design. Angew. Chem. Int. Ed. 58: 15188–15205, https://doi.org/10.1002/anie.201902229.Suche in Google Scholar PubMed

Najafi, M., Abednatanzi, S., Gohari Derakhshandeh, P., Mollarasouli, F., Bahrani, S., Behbahani, E.S., Van Der Voort, P., and Ghaedi, M. (2022). Metal-organic and covalent organic frameworks for the remediation of aqueous dye solutions: adsorptive, catalytic and extractive processes. Coord. Chem. Rev. 454: 214332, https://doi.org/10.1016/j.ccr.2021.214332.Suche in Google Scholar

Quan, L. (2021). Study on the preparation and adsorption properties of metal-organic framework monolithic materials [D]. Changchun University of Science and Technology, Changchun.Suche in Google Scholar

Sessarego, S., Rodrigues, S.C.G., Xiao, Y., Lu, Q., and Hill, J.M. (2019). Phosphonium-Enhanced chitosan for Cr(VI) adsorption in wastewater treatment. Carbohydr. Polym. 211: 249–256, https://doi.org/10.1016/j.carbpol.2019.02.003.Suche in Google Scholar PubMed

Shi, Y., Yang, A.F., Cao, C.S., and Zhao, B. (2019). Applications of MOFs: recent advances in photocatalytic hydrogen production from water. Coord. Chem. Rev. 390: 50–75, https://doi.org/10.1016/j.ccr.2019.03.012.Suche in Google Scholar

Song, W., Zhu, M., Zhu, Y., Zhao, Y., Yang, M., Miao, Z., Ren, H., Ma, Q., and Qian, L. (2020). Zeolitic imidazolate framework-67 functionalized cellulose hybrid aerogel: an environmentally friendly candidate for dye removal. Cellulose 27: 2161–2172, https://doi.org/10.1007/s10570-019-02883-2.Suche in Google Scholar

Sriram, G., Bendre, A., Mariappan, E., Altalhi, T., Kigga, M., Ching, Y.C., Jung, H.-Y., Bhaduri, B., and Kurkuri, M. (2022). Recent trends in the application of metal-organic frameworks (MOFs) for the removal of toxic dyes and their removal mechanism-a review. Sustainable Mater. Technol. 31: e00378, https://doi.org/10.1016/j.susmat.2021.e00378.Suche in Google Scholar

Sun, J., Shang, M., Zhang, M., Yu, S., Yuan, Z., Yi, X., Filatov, S., and Zhang, J. (2022). Konjac glucomannan/cellulose nanofibers composite aerogel supported HKUST-1 for CO(2) adsorption. Carbohydr. Polym. 293: 119720, https://doi.org/10.1016/j.carbpol.2022.119720.Suche in Google Scholar PubMed

Tchinsa, A., Hossain, M.F., Wang, T., and Zhou, Y.B. (2021). Removal of organic pollutants from aqueous solution using metal organic frameworks (MOFs)-based adsorbents: a review. Chemosphere 284: 131393, https://doi.org/10.1016/j.chemosphere.2021.131393.Suche in Google Scholar PubMed

Wang, J. and Liu, S. (2019). Remodeling of raw cotton fiber into flexible, squeezing-resistant macroporous cellulose aerogel with high oil retention capability for oil/water separation. Sep. Purif. Technol. 221: 303–310, https://doi.org/10.1016/j.seppur.2019.03.097.Suche in Google Scholar

Wang, C., Qian, X., and An, X. (2015). In situ green preparation and antibacterial activity of copper-based metal-organic frameworks/cellulose fibers (HKUST-1/CF) composite. Cellulose 22: 3789–3797, https://doi.org/10.1007/s10570-015-0754-4.Suche in Google Scholar

Wang, G., Wang, J., Chen, Z., and Hu, J. (2022). Metal-organic framework grown in situ on chitosan microspheres as robust host of palladium for heterogeneous catalysis: Suzuki reaction and the p-nitrophenol reduction. Int. J. Biol. Macromol. 206: 232–241, https://doi.org/10.1016/J.IJBIOMAC.2022.02.010.Suche in Google Scholar PubMed

Wisser, D., Wisser, F.M., Raschke, S., Klein, N., Leistner, M., Grothe, J., Eike, B., and Stefan, K. (2015). Biological Chitin-MOF composites with hierarchical pore systems for air-filtration applications. Angew. Chem., Int. Ed. 54: 12588–12591, https://doi.org/10.1002/anie.201504572.Suche in Google Scholar PubMed

Wu, K., Yue, X., Wu, S., Peng, X., Zhang, T., and Qiu, F. (2024). All cellulose-based superwetting aerogel/wood composite with disordered/ordered pores structure for rapid emulsion separation. J. Environ. Chem. Eng. 12: 113905, https://doi.org/10.1016/j.jece.2024.113905.Suche in Google Scholar

Xiaoliang, Q., Xianqin, T., Wenhao, P., Qiankun, Z., Shengye, Y., and Jianliang, S. (2021). Recent advances in polysaccharide-based adsorbents for wastewater treatment. J. Cleaner Prod. 315: 128221, https://doi.org/10.1016/j.jclepro.2021.128221.Suche in Google Scholar

Yang, J., Medronho, B., Lindman, B., and Norgren, M. (2020). Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea. Polymers 12: 373, https://doi.org/10.3390/polym12020373.Suche in Google Scholar PubMed PubMed Central

Yang, C., He, P., Wang, W., Han, R., Zhang, H., Nie, M., and Liu, Y. (2024). Layer-by-layer assembled aramid nanofiber/MXene aerogel: exceptional resistance to extreme temperatures and robust anisotropy for advanced applications. Compos. Sci. Technol. 257: 110833, https://doi.org/10.1016/j.compscitech.2024.110833.Suche in Google Scholar

Ying, T., Su, J., Jiang, Y., Ni, L., Jiang, X., Ke, Q., and Xu, H. (2021). Superhydrophobic MOFs decorated on hierarchically micro/nanofibrous membranes for high-performance emulsified oily wastewater separation and cationic dyes adsorption. J. Mater. Chem. A 10: 829–845, https://doi.org/10.1039/d1ta04982h.Suche in Google Scholar

Zhang, S., Feng, J., Feng, J., and Jiang, Y. (2017). Oxidation-mediated chitosan as additives for creation of chitosan aerogels with diverse three-dimensional interconnected skeletons. Appl. Surf. Sci. 396: 1220–1225, https://doi.org/10.1016/j.apsusc.2016.11.116.Suche in Google Scholar

Zhang, S., Wang, Y., and Yun, T. (2019). Research progress on sources and detection methods of antibiotic pollution in water. J. Jiangxi Agric. Sci. 31: 111–116.Suche in Google Scholar

Zhang, Y., Li, Y., Wang, M., Chen, B., Sun, Y., Chen, K., Qiujv, D., Xinxin, P., and Yuqi, W. (2022). Adsorption of methylene blue from aqueous solution using gelatin-based carboxylic acid-functionalized carbon Nanotubes@Metal-organic framework composite beads. Nanomaterials 12: 2533, https://doi.org/10.3390/NANO12152533.Suche in Google Scholar PubMed PubMed Central

Zhao, R., Ma, T., Zhao, S., Rong, H., Tian, Y., and Zhu, G. (2020). Uniform and stable immobilization of metal-organic frameworks into chitosan matrix for enhanced tetracycline removal from water. Chem. Eng. J. 382: 122893, https://doi.org/10.1016/j.cej.2019.122893.Suche in Google Scholar

Zhu, R., Xia, J., Zhang, H., Kong, F., Hu, X., Shen, Y., and Zhang, W. (2021). Synthesis of magnetic activated carbons from black liquor lignin and Fenton sludge in a one-step pyrolysis for methylene blue adsorption. J. Environ. Chem. Eng. 9: 106538, https://doi.org/10.1016/J.JECE.2021.106538.Suche in Google Scholar
Received: 2024-07-07
Accepted: 2024-11-29
Published Online: 2024-12-19
Published in Print: 2025-03-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Biorefining
  3. Fractionation methods of eucalyptus kraft lignin for application in biorefinery
  4. Pulp and paper industry side-stream materials as feed for the oleaginous yeast species Lipomyces starkeyi and Rhodotorula toruloides
  5. Chemical Pulping
  6. Comparing classic time series models and state-of-the-art time series neural networks for forecasting as-fired liquor properties
  7. Optimization of kraft pulping process for Sesbania aculeata (dhaincha) stems using RSM
  8. On the nature of the selectivity of oxygen delignification
  9. Unlocking potential: the role of chemometric modeling in pulp and paper manufacturing
  10. Effects of chemical environment on softwood kraft pulp: exploring beyond conventional washing methods
  11. Bleaching
  12. Variations in carbohydrates molar mass distribution during chemical degradation and consequences on fibre strength
  13. Mechanical Pulping
  14. Energy consumption in refiner mechanical pulping
  15. Paper Technology
  16. Australian wheat and hardwood fibers for advanced packaging materials
  17. Compression refining: the future of refining? Application to bleached kraft eucalyptus pulp
  18. The effect of nanocellulose to coated paper and recycled paper
  19. Interpreting the relationship between properties of wood and pulping & paper via machine learning algorithms combined with SHAP analysis
  20. Hybridization to prepare environmentally friendly, cost-effective superhydrophobic oleophobic coatings
  21. Paper Physics
  22. Characterising the mechanical behaviour of dry-formed cellulose fibre materials
  23. Paper Chemistry
  24. Study on the properties of ground film paper prepared from lactic acid-modified cellulose
  25. Environmental Impact
  26. Characterization of sludge from a cellulose pulp mill for its potential biovalorization
  27. The in situ green synthesis of metal organic framework (HKUST-1)/cellulose/chitosan composite aerogel (CSGA/HKUST-1) and its adsorption on tetracycline
  28. Evaluation of the potential use of powdered activated carbon in the treatment of effluents from bleached kraft pulp mills
  29. Recycling
  30. Waste newspaper activation by sodium phosphate for adsorption dynamics of methylene blue
https://doi.org/10.1515/npprj-2024-0053
Schlagwörter für diesen Artikel
Solvothermal method; water treatment; reusable; In-situ green synthetic; tetracycline; environmental protection

Artikel in diesem Heft

  1. Frontmatter
  2. Biorefining
  3. Fractionation methods of eucalyptus kraft lignin for application in biorefinery
  4. Pulp and paper industry side-stream materials as feed for the oleaginous yeast species Lipomyces starkeyi and Rhodotorula toruloides
  5. Chemical Pulping
  6. Comparing classic time series models and state-of-the-art time series neural networks for forecasting as-fired liquor properties
  7. Optimization of kraft pulping process for Sesbania aculeata (dhaincha) stems using RSM
  8. On the nature of the selectivity of oxygen delignification
  9. Unlocking potential: the role of chemometric modeling in pulp and paper manufacturing
  10. Effects of chemical environment on softwood kraft pulp: exploring beyond conventional washing methods
  11. Bleaching
  12. Variations in carbohydrates molar mass distribution during chemical degradation and consequences on fibre strength
  13. Mechanical Pulping
  14. Energy consumption in refiner mechanical pulping
  15. Paper Technology
  16. Australian wheat and hardwood fibers for advanced packaging materials
  17. Compression refining: the future of refining? Application to bleached kraft eucalyptus pulp
  18. The effect of nanocellulose to coated paper and recycled paper
  19. Interpreting the relationship between properties of wood and pulping & paper via machine learning algorithms combined with SHAP analysis
  20. Hybridization to prepare environmentally friendly, cost-effective superhydrophobic oleophobic coatings
  21. Paper Physics
  22. Characterising the mechanical behaviour of dry-formed cellulose fibre materials
  23. Paper Chemistry
  24. Study on the properties of ground film paper prepared from lactic acid-modified cellulose
  25. Environmental Impact
  26. Characterization of sludge from a cellulose pulp mill for its potential biovalorization
  27. The in situ green synthesis of metal organic framework (HKUST-1)/cellulose/chitosan composite aerogel (CSGA/HKUST-1) and its adsorption on tetracycline
  28. Evaluation of the potential use of powdered activated carbon in the treatment of effluents from bleached kraft pulp mills
  29. Recycling
  30. Waste newspaper activation by sodium phosphate for adsorption dynamics of methylene blue
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 18.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/npprj-2024-0053/pdf
Button zum nach oben scrollen