Startseite Facile fabrication of superhydrophobic filter paper with improved durability and water repellency
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Facile fabrication of superhydrophobic filter paper with improved durability and water repellency

  • Lizheng Sha EMAIL logo , Chao Ma , Huifang Zhao , Supeng Qiu , Zhongyu Yan und Daliang Guo
Veröffentlicht/Copyright: 27. Mai 2021
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Abstract

Superhydrophobic surfaces have high potential in self-cleaning and oil-water separation applications. We developed a three-step method for the preparation of superhydrophobic filter paper. It involved citric acid (CA) pretreatment to activate cellulose fibers, coating with cellulose nanofibrils/functionalized silica (CNFs/m-SiO2) slurry to increase surface roughness, and grafting of hexadecyltrimethoxysilane (HDTMS) to enhance water resistance. The water contact angle (WCA) and siding angle (SA) of the prepared filter paper reached 151.5° and 7.5°, respectively. The results showed that, compared to the coated filter paper without the added CNFs, the coated paper with CNFs had higher retention of m-SiO2, thus roughness required for superhydrophobic surface was achieved. Further test under frequent abrasion and acid or alkali conditions showed that CA pretreatment improved the durability of superhydrophobic filter paper due to chemical crosslinking between the modified substrate and m-SiO2. Besides, the prepared superhydrophobic filter paper had outstanding self-cleaning property and high oil-water separation efficiency for various oil-water mixtures. Therefore, it is expected to be used for the treatment of oily wastewater.

Funding statement: This work was supported by the key research and development plan of Zhejiang province (Grant No. 2021C01094).

  1. Conflict of interest: The authors declare no conflicts of interest.

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Supplemental Material

The online version of this article offers supplementary material (https://doi.org/10.1515/npprj-2021-0010).


Received: 2021-02-08
Accepted: 2021-05-15
Published Online: 2021-05-27
Published in Print: 2021-12-20

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