Home Crystal structure of tripropylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate – [1,1′-biphenyl]-2,2′-dicarboxylic acid (2/1), C60H72N2O12
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Crystal structure of tripropylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate – [1,1′-biphenyl]-2,2′-dicarboxylic acid (2/1), C60H72N2O12

  • Xiangxiang Wu EMAIL logo and Yanbing Zai
Published/Copyright: November 12, 2016
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 232 Issue 1

Abstract

C60H72N2O12, triclinic, P1 (no. 1), a = 9.6569(4) Å, b = 10.9361(4) Å, c = 13.8551(6) Å, α = 113.198(3)°, β = 95.632(4)°, γ = 91.114(3)°, V = 1335.72(9) Å3, Z = 1, Rgt(F) = 0.0512, wRref(F2) = 0.1380, T = 150(2) K.

CCDC no.:: 1510401

The asymmetric unit of the title crystal structure is shown in the figure (hydrogen atoms are omitted for clarity). Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Yellow block
Size:0.26 × 0.16 × 0.10 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.9 cm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
2θmax, completeness:50°, >99%
N(hkl)measured, N(hkl)unique, Rint:9438, 7449, 0.023
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 6838
N(param)refined:685
Programs:Bruker programs [4], SHELX [5]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
N10.9301(3)0.3645(3)0.6838(3)0.0363(7)
H11.0229(18)0.343(5)0.683(4)0.054*
C10.1031(3)0.9018(3)0.9611(3)0.0293(7)
O10.1222(3)1.0297(3)0.81658(19)0.0375(6)
H1A0.127(5)1.073(4)0.777(3)0.056*
N20.4457(3)0.6138(3)0.1896(3)0.0353(7)
H20.3531(19)0.580(4)0.176(4)0.053*
C2−0.0040(3)0.9684(3)0.9306(3)0.0284(7)
O2−0.0821(3)1.1129(4)0.8510(3)0.0668(10)
O30.2223(3)1.1652(2)1.06002(19)0.0364(6)
H30.216(5)1.2468(18)1.103(3)0.055*
C3−0.1343(4)0.9670(4)0.9641(3)0.0360(8)
H3A−0.20621.01230.94280.043*
C4−0.1622(4)0.9009(4)1.0278(3)0.0394(9)
H4A−0.25220.90091.05010.047*
O40.4331(3)1.2140(3)1.0317(4)0.0820(13)
O51.2268(3)0.3222(3)0.65534(19)0.0379(6)
C5−0.0576(4)0.8353(4)1.0586(3)0.0416(9)
H5A−0.07560.78921.10200.050*
O61.1329(3)0.1754(3)0.7062(2)0.0445(6)
C60.0726(4)0.8362(4)1.0266(3)0.0373(8)
H6A0.14380.79151.04940.045*
O71.4457(3)0.4005(2)0.59524(19)0.0360(6)
H71.374(3)0.379(5)0.619(4)0.054*
C70.0088(3)1.0437(3)0.8610(3)0.0317(8)
O81.5544(3)0.3667(2)0.4545(2)0.0435(7)
C80.2457(4)0.8869(3)0.9261(3)0.0291(7)
C90.3516(3)0.9882(3)0.9543(3)0.0296(7)
O90.2186(3)0.4265(3)0.1603(2)0.0446(7)
C100.4815(4)0.9550(4)0.9196(3)0.0354(8)
H10A0.55391.02340.94000.042*
O100.1261(3)0.6217(2)0.22056(19)0.0389(6)
C110.5092(4)0.8259(4)0.8563(3)0.0429(9)
H11A0.59810.80610.83210.051*
O11−0.0903(3)0.7472(2)0.28426(19)0.0359(6)
H11−0.009(2)0.716(5)0.273(4)0.054*
C120.4045(4)0.7270(4)0.8294(3)0.0423(9)
H12A0.42090.63750.78630.051*
O12−0.1907(3)0.8537(3)0.4288(2)0.0413(6)
C130.2767(4)0.7574(4)0.8646(3)0.0379(8)
H13A0.20660.68740.84640.045*
C140.3399(3)1.1327(4)1.0204(3)0.0349(8)
C151.4168(3)0.1068(3)0.5566(3)0.0269(7)
C161.3631(4)0.1457(3)0.6550(3)0.0304(7)
C171.4394(4)0.1222(4)0.7365(3)0.0393(9)
H17A1.40140.14210.80130.047*
C181.5672(4)0.0712(4)0.7246(3)0.0405(9)
H18A1.61990.06120.78240.049*
C191.6208(4)0.0335(4)0.6281(3)0.0358(8)
H19A1.7091−0.00370.61920.043*
C201.5442(3)0.0509(3)0.5453(3)0.0301(7)
H20A1.58000.02380.47900.036*
C211.2323(4)0.2175(4)0.6742(3)0.0352(8)
C221.3319(3)0.1182(3)0.4644(2)0.0276(7)
C231.3566(4)0.2211(3)0.4317(3)0.0281(7)
C241.2826(4)0.2203(4)0.3391(3)0.0352(8)
H24A1.30210.28910.31580.042*
C251.1813(4)0.1199(4)0.2815(3)0.0370(8)
H25A1.12940.12100.22000.044*
C261.1560(4)0.0175(4)0.3141(3)0.0359(8)
H26A1.0867−0.05190.27480.043*
C271.2317(4)0.0168(3)0.4034(3)0.0309(7)
H27A1.2150−0.05490.42410.037*
C281.4608(4)0.3349(3)0.4944(3)0.0325(8)
C29−0.0607(3)0.4890(3)0.3132(3)0.0268(7)
C30−0.0103(4)0.4362(3)0.2148(3)0.0327(8)
C31−0.0864(4)0.3345(4)0.1318(3)0.0413(9)
H31A−0.05030.29720.06560.050*
C32−0.2144(4)0.2855(4)0.1427(3)0.0421(9)
H32A−0.26690.21640.08450.051*
C33−0.2650(4)0.3396(3)0.2410(3)0.0374(8)
H33A−0.35300.30760.24970.045*
C34−0.1884(4)0.4388(3)0.3250(3)0.0326(8)
H34A−0.22310.47350.39180.039*
C350.1205(4)0.4974(4)0.1973(3)0.0347(8)
C360.0240(3)0.5920(3)0.4092(3)0.0269(7)
C370.0011(4)0.7274(3)0.4456(3)0.0285(7)
C380.0752(4)0.8170(3)0.5392(3)0.0346(8)
H38A0.05760.90890.56490.041*
C390.1746(4)0.7722(4)0.5949(3)0.0387(8)
H39A0.22640.83380.65780.046*
C400.1983(4)0.6387(4)0.5593(3)0.0361(8)
H40A0.26630.60830.59750.043*
C410.1227(4)0.5488(3)0.4676(3)0.0320(8)
H41A0.13820.45660.44400.038*
C42−0.1015(4)0.7826(3)0.3874(3)0.0302(7)
C430.8673(5)0.3564(4)0.7749(3)0.0467(10)
H43A0.87740.26550.77280.056*
H43B0.76620.36850.76560.056*
C440.9272(5)0.4558(5)0.8837(3)0.0547(11)
H44A0.91180.54700.88800.066*
H44B0.87550.44200.93720.066*
C451.0802(6)0.4467(6)0.9111(4)0.0683(13)
H45A1.11100.51440.98180.102*
H45B1.13280.46170.85930.102*
H45C1.09640.35790.90980.102*
C460.9376(4)0.5030(3)0.6862(3)0.0363(8)
H46A0.98870.50220.62740.044*
H46B0.99260.56260.75310.044*
C470.7978(4)0.5614(4)0.6774(3)0.0411(9)
H47A0.74080.50270.61120.049*
H47B0.74700.56720.73760.049*
C480.8199(5)0.6989(4)0.6777(3)0.0484(10)
H48A0.72930.73590.67200.073*
H48B0.86920.69270.61750.073*
H48C0.87550.75700.74360.073*
C490.8572(4)0.2621(4)0.5823(3)0.0367(8)
H49A0.85860.17400.58670.044*
H49B0.75840.28340.57580.044*
C500.9181(4)0.2517(4)0.4839(3)0.0389(8)
H50A1.01660.22890.48840.047*
H50B0.91580.33860.47730.047*
C510.8360(4)0.1455(4)0.3878(3)0.0423(9)
H51A0.87640.13940.32400.063*
H51B0.73880.16880.38300.063*
H51C0.83940.05940.39410.063*
C520.5143(4)0.6182(4)0.2925(3)0.0368(8)
H52A0.61170.65500.30270.044*
H52B0.51780.52580.28820.044*
C530.4443(4)0.6999(4)0.3890(3)0.0391(8)
H53A0.34650.66480.38030.047*
H53B0.44340.79380.39660.047*
C540.5231(5)0.6932(4)0.4880(3)0.0455(9)
H54A0.47710.74570.55000.068*
H54B0.61940.72950.49710.068*
H54C0.52330.60030.48040.068*
C550.4227(4)0.7497(4)0.1895(3)0.0366(8)
H55A0.36810.79910.24820.044*
H55B0.36640.73860.12260.044*
C560.5554(4)0.8320(4)0.2011(3)0.0415(9)
H56A0.61000.78510.14180.050*
H56B0.61270.84440.26790.050*
C570.5205(5)0.9665(4)0.2013(3)0.0471(10)
H57A0.60691.01980.20940.071*
H57B0.46671.01280.26020.071*
H57C0.46530.95390.13450.071*
C580.5257(4)0.5284(4)0.1007(3)0.0440(9)
H58A0.53500.44040.10460.053*
H58B0.62080.57070.11180.053*
C590.4600(5)0.5068(5)−0.0091(3)0.0539(11)
H59A0.37310.4492−0.02630.065*
H59B0.43500.5937−0.01010.065*
C600.5555(7)0.4435(7)−0.0918(5)0.0852(17)
H60A0.50890.4317−0.16130.128*
H60B0.57890.3565−0.09230.128*
H60C0.64100.5010−0.07590.128*

Source of material

Biphenyl-2,2′-dicarboxylic acid and tripropylamine, which were purchased from Aladdin Corporation, were mixed with a molar ratio of 1:4 and dissolved in the water/ethanol solvent (1:2 v/v). The mixture was vigorously stirred for 1 h at room temperature to get a yellow solution. After setting aside for 1 week at room temperature, yellow block crystals of the title compound were obtained.

Experimental details

In the crystal structure, non-hydrogen atoms were refined with anisotropic displacement parameters, and all H atoms bonded to C atoms were positioned at calculated positions, riding on the parent atom. The H atoms bonded to O and N atoms were located in difference maps and refined with the riding model of the fixed O—H distance of 0.86 ± 0.01 Å and N—H of 0.93 ± 0.01 Å.

Discussion

As an aromatic acid with two carboxyl groups, biphenyl-2,2′-dicarboxylic acid can be used to interact with different compounds to obtain various crystal structures [1], [2], [3]. However, the crystal structure of biphenyl-2,2′-dicarboxylic acid and tripropylamine has not been reported till now. Herein we report the related title crystal structure, which can help to understand the crystallography of biphenyl-2,2′-dicarboxylic acid and the deprotonated anions under basic conditions. Due to its two carboxyl groups, biphenyl-2,2′-dicarboxylic acid tends to form the related anions [2, 3].

In the asymmetric unit of the title compound, there are one molecule of biphenyl-2,2′-dicarboxylic acid, two biphenyl-2,2′-dicarboxylate monoanions and two tripropyl-ammonium cations. The two anions display very similar configurations with the similar interplanar angles of 81.7° and 83.5° and the torsion angles of 51.7° and 56.0° between the carboxyl groups and the related benzene rings. The neutral molecule shows a smaller interplanar angle of 65.5° and the carboxyl groups are almost coplanar with the adjacent ring with angles of 6.1° and 10.2° between the planes. Obviously, the deprotonation of biphenyl-2,2′-dicarboxylic acid result in very different configurations between the neutral molecule and the related anions. It can be observed that the neutral molecule mentioned above can link two related anions with intermolecular O—H⋯O hydrogen bonding to yield a butterfly-like motif, in which the molecule can be regarded as the ‘body’ of the ‘butterfly’ and the two anions are just like two ‘wings’. Furthermore, there exist intramolecular O—H⋯O hydrogen bonds in these two anions to stabilize their spacial configurations. Then the two counterions of tripropylazanium interact with the two anions to generate the final structure with strong N—H⋯O hydrogen bonds, in which the cations are just like two ‘streamers’ decorated on the two ‘wings’. Undoubtedly, various O—H⋯O and N—H⋯O hydrogen bonding are crucial factors in forming the crystal structure of the title compound.

Acknowledgements

We thank for the support from Henan University of Traditional Chinese Medicine.

References

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Received: 2016-6-1
Accepted: 2016-10-18
Published Online: 2016-11-12
Published in Print: 2017-1-1

©2016 Xiangxiang Wu et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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  51. Crystal structure of 2-[3,5-bis(trifluoromethyl)benzylsulfanyl]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C15H7BrF6N2OS2
  52. Crystal structure of (E)-3-((naphthalen-1-ylimino)methyl)-4-nitrophenol, C17H12N2O3
  53. Crystal structure of 2-dichloromethyl-2-p-nitrophenyl-1,3-dioxolane, C10H9Cl2NO4
  54. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanopalladate(II), C14H24N8Pd2
  55. Crystal structure of 2-(4-oxo-2-thioxothiazolidin-3-yl)acetic acid monohydrate, C5H7NO4S2
  56. Crystal structure of a P4-bridged (η5-pentamethyl-cyclopentadienyl)(η5-adamantylcyclopentadienyl) titanium(III)complex, C50H66P4Ti2
  57. Crystal structure of cis-bis(2,2′-bipyrimidine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C18H12N10NiS2
  58. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)dibromidomanganese(II), C20H16Br2MnN4
  59. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C22H16N6NiS2
  60. Crystal structure of trans-dibromido(1,4,8,11-tetraazacyclotetradecane)nickel(II), C10H24Br2N4Ni
  61. Crystal structure of cis-tetrabromidobis(pyridine-κN)platinum(IV), C10H10Br4N2Pt
  62. Crystal structure of (E)-5-((4-chlorophenyl)diazenyl)-2-(5-(4-fluorophenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-4-methylthiazole, C23H17ClFN5S2
  63. The crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetrachloridocobaltate(II) monohydrate, C10H18Cl4CoN2O
https://doi.org/10.1515/ncrs-2016-0177
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Editorial
  3. Twenty years of crystal structure publication and the road ahead
  4. Crystal Structures
  5. Crystal structure of poly-[triaqua-(μ4-5′-carboxy-[1,1′-biphenyl]-2,3,3′-tricarboxylate-κ6O1,O2:O3,O4:O5:O6)praseodymium(III), C16H13O11Pr
  6. Crystal structure of (R)-1-(2,3-dihydro-1H-pyrrolizin-5-yl)-2,3-dihydroxypropan-1-one, C10H13NO3
  7. Crystal structure of (E)-4-nitro-2-((2-phenoxyphenylimino)methyl)phenol, C19H14N2O4
  8. Crystal structure of 3,3′-di(furan-2-yl)-5,5′-bi-1,2,4-triazine
  9. Crystal structure of 11-(p-coumaroyloxy)-tremetone, C22H20O5
  10. The crystal structure of 1,3-bis(2,6-diiso-propylphenyl)imidazol-2-ylidene)-dibromido-(1-methyl-1H-imidazole-κ1N)palladium(II) – ethyl acetate – water (1/1/1), C31H42Br2N4Pd
  11. Crystal structure of 2-((3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene)-1H-indene-1,3(2H)-dione, C28H19N5O2
  12. Crystal structure of 2-(5-(4-fluorophenyl)-3-p-tolyl-4,5-dihydro-1H-pyrazol-1-yl)-4-(5-methyl-1-p-tolyl-1H-1,2,3-triazol-4-yl)thiazole, C29H25FN6S
  13. Crystal structure of poly-[aqua-(μ7-benzene-1,3,5-tricarboxylato)-(μ3-1,2,4-triazol-1-ido)dicobalt(II)], C11H7Co2N3O7
  14. Crystal constructure of 16(S)-methyl-6α-carboxy-1, 15-dioxo-6, 7-seco-ent-kaur-2-en-7, 20-olide, C20H24O6
  15. Crystal structure of 1-(benzo[d]thiazol-2-yl)-3-phenylthiourea, C14H11N3S2
  16. Crystal structure of 3-(2-bromophenyl)-1,1-dimethylthiourea, C9H11BrN2S
  17. Crystal structure of 1-(adamantan-1-yl)-3-(3-chlorophenyl)thiourea, C17H21ClN2S
  18. Crystal structure of 3-(adamantan-1-yl)-1-(4-bromophenyl)urea, C17H21BrN2O
  19. Crystal structure of (Z)-Ethyl 2-cyano-2-(3-phenylthiazolidin-2-ylidene) acetate, C14H14N2O2S
  20. Crystal structure of methyl 2b-ethyl-1a,2a,2b,2b1,3,5,10,11-octahydro-1H-oxireno[2′,3′:6,7]indolizino[8,1-cd]carbazole-4-carboxylate, C21H24N2O3
  21. Crystal structure of 2-amino-5-oxo-4-(3,4,5-trimethoxy-phenyl)-4,5,6,7-tetrahydro-cyclopenta[b]pyran-3-carbonitrile, C18H18N2O5
  22. Crystal structure of 1,2,3-trimethyl-2,3-dihydro-1H-perimidine, C14H16N2
  23. Crystal structure of bis(2,6-dihydroxymethyl)pyridine-κ3N,O,O′)-bis(μ2-6-chloropyridin-2-olato-κ3N,O:O)-bis(6-chloropyridin-2-olato-κO)-bis(nitrato-κ2O,O′)digadolinium(III), C34H30Cl4Gd2N8O14
  24. Crystal structure of 8-isopropyl-8-aza-bicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate, C19H27NO3
  25. Crystal structure of 1-methyl-3-[((naphthalen-2-ylsulfonyl)oxy)imino]indolin-2-one, C19H14N2O4S
  26. Crystal structure (7,8-bis(diisopropylphosphino)-7,8-dicarba-nido-undecaborane-κ2P,P′)-(benzoato-κ2O,O′)nickel(II), C21H42B9NiO2P2
  27. Crystal structure of methyl-2-methyl-4-(2-oxo-2-phenylethyl)-5-phenyl-1H-pyrrole-3-carboxylate, C21H19NO3
  28. Crystal structure of 2-[(2-oxo-thiazolidine-3-carbonyl)sulfamoyl]-methy-benzoic acid methyl ester, C13H14N2O6S2
  29. Crystal structure of N′-(2-phenylacetyl)thiophene-2-carbohydrazide monohydrate, C13H14N2O3S
  30. Crystal structure of 1,1′-(hexane-1,6-diyl)bis(3-methyl-1H-imidazol-3-ium) bis(hexafluoro phosphate), C14H24F12N4P2
  31. Crystal structure of di-μ-chlorido-bis[1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]zinc(II), C52H108B20Cl2P4Zn2
  32. Crystal structure of dibromido-bis[μ-1-[(2-methyl-1H-benzoimidazol-1-yl)methyl]-1H-benzotriazole-κN]mercury(II), C30H26Br2HgN10
  33. Crystal structure of bis(μ-nitrato-κ2O:O)-bis[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]disilver(I) dicloromethane monosolvate, C54H64B20Cl4O6P4Ag2
  34. Crystal structure of dinuclear dichloridobis(dimethylformamide-kO)bis[μ2-3-(2-oxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazol-1ido-κ4-O,N:N′,N′′(2−)]diiron(III) − dimethylformamide (1/1), C36H42Cl2Fe2N14O6
  35. Crystal structure of diaqua-dinitrato-κO-bis(4-(1H-pyrazol-3-yl)pyridine-κN)manganese(II), C16H18MnN8O8
  36. Crystal structure of (Z)-6-methoxy-2-(2,2,2-trifluoro-1-hydroxyethylidene)-2,3-dihydro-1H-inden-1-one, C12H6F6O3
  37. Crystal Structure of 4-(2-chloroacetamido)pyridinium chloride monohydrate, C7H10Cl2N2O2
  38. Crystal structure of 2-amino-4-(4-chloro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13ClN2O2
  39. Crystal structure of (E)-1-(2-(thiophen-2-ylmethylene)hydrazinyl)phthalazine hydrochloride–ethanol (1/1), C15H17ClN4OS
  40. Crystal structure of N,N-diethyl-5-bromo-3,4-dihydro-2,4-dioxopyrimidine-1(2H)-carboxamide, C9H12BrN3O3
  41. Crystal structure of 3-(2-(4-chlorophenyl)-3-hydroxy-3,3-diphenylpropyl)-1,1-dimethylurea, C24H25ClN2O2
  42. Crystal structure of 3-(4-chlorophenyl)-1,1-dimethylthiourea, C9H11ClN2S
  43. Crystal structure of 2-amino-4-(4-bromo-phenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carbonitrile, C16H11BrN2O3
  44. Crystal structure of 4-(3,4-dimethyl-phenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester, C21H25NO3
  45. Crystal structure of (E)-2-({4-hydroxy-5-methoxy-3-[(4-methyl-1-piperazinyl)methyl]phenyl} methylidene)-1-indanone, C23H26N2O3
  46. Crystal structure of tripropylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate – [1,1′-biphenyl]-2,2′-dicarboxylic acid (2/1), C60H72N2O12
  47. Crystal structure of catena-poly-{aqua-[μ2-1,2-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′]-[μ2-4,4′-(dimethylsilanediyl)dibenzato-κ3O,O′:O′]nickel(II)}, C30H30N4NiO5Si
  48. The crystal structure of 1-(4-bromophenyl)-2-(4-(4-fluorophenyl)piperazin-1-yl)ethanol, C18H20BrFN2O1
  49. Crystal structure of trimethylammonium 4-((4-carboxyphenyl)sulfonyl)benzoate, C17H19NO6S
  50. Crystal structure of syn-2,4-di-o-tolylpentane-2,4-diol, C19H24O2
  51. Crystal structure of 2-[3,5-bis(trifluoromethyl)benzylsulfanyl]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C15H7BrF6N2OS2
  52. Crystal structure of (E)-3-((naphthalen-1-ylimino)methyl)-4-nitrophenol, C17H12N2O3
  53. Crystal structure of 2-dichloromethyl-2-p-nitrophenyl-1,3-dioxolane, C10H9Cl2NO4
  54. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanopalladate(II), C14H24N8Pd2
  55. Crystal structure of 2-(4-oxo-2-thioxothiazolidin-3-yl)acetic acid monohydrate, C5H7NO4S2
  56. Crystal structure of a P4-bridged (η5-pentamethyl-cyclopentadienyl)(η5-adamantylcyclopentadienyl) titanium(III)complex, C50H66P4Ti2
  57. Crystal structure of cis-bis(2,2′-bipyrimidine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C18H12N10NiS2
  58. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)dibromidomanganese(II), C20H16Br2MnN4
  59. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C22H16N6NiS2
  60. Crystal structure of trans-dibromido(1,4,8,11-tetraazacyclotetradecane)nickel(II), C10H24Br2N4Ni
  61. Crystal structure of cis-tetrabromidobis(pyridine-κN)platinum(IV), C10H10Br4N2Pt
  62. Crystal structure of (E)-5-((4-chlorophenyl)diazenyl)-2-(5-(4-fluorophenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-4-methylthiazole, C23H17ClFN5S2
  63. The crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetrachloridocobaltate(II) monohydrate, C10H18Cl4CoN2O
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