Startseite Crystal structure of bis(μ-nitrato-κ2O:O)-bis[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]disilver(I) dicloromethane monosolvate, C54H64B20Cl4O6P4Ag2
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Crystal structure of bis(μ-nitrato-κ2O:O)-bis[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]disilver(I) dicloromethane monosolvate, C54H64B20Cl4O6P4Ag2

  • Wang Yanfei , Wang Xin , Gao Qianqian und Yang Liguo EMAIL logo
Veröffentlicht/Copyright: 29. Oktober 2016
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 232 Heft 1

Abstract

C54H64B20Cl4O6P4Ag2, triclinic, P1̅ (no. 2), a = 10.1200(10) Å, b = 11.9101(11) Å, c = 14.4999(15) Å, α = 86.432(2)°, β = 80.670(1)°, γ = 84.031(2)°, V = 1713.4(3)Å3, Z = 1, Rgt(F) = 0.0535, wRref(F2) = 0.1544, T = 298 K.

CCDC no.:: 768110

The crystal structure is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Yellow blocks
Size:0.80 × 0.43 × 0.18 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:8.7 cm−1
Diffractometer, scan mode:Bruker SMART, φ and ω
2θmax, completeness:50°, >98%
N(hkl)measured, N(hkl)unique, Rint:8733, 5920, 0.038
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 4341
N(param)refined:415
Programs:SHELX [7], Bruker programs [8]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Ag10.09951(4)0.09046(3)0.39690(3)0.04984(17)
P10.32796(12)0.10265(10)0.31109(8)0.0384(3)
P20.00759(12)0.23383(10)0.28739(8)0.0395(3)
Cl10.3154(5)0.2567(5)0.7494(3)0.265(3)
Cl20.0975(6)0.3305(5)0.8800(2)0.268(3)
N10.0408(5)0.1597(4)0.6003(3)0.0534(11)
O10.0043(4)0.0854(3)0.5541(2)0.0534(9)
O20.1177(5)0.2259(4)0.5602(3)0.0727(12)
O30.0018(6)0.1602(5)0.6841(3)0.1086(19)
B10.2590(6)0.2522(5)0.1386(4)0.0437(13)
H10.23460.17780.10550.052*
B20.4277(6)0.2775(5)0.1463(4)0.0507(14)
H20.51480.22130.11570.061*
B30.4231(6)0.3413(5)0.2540(4)0.0481(14)
H30.50650.32720.29470.058*
B40.2524(6)0.3536(4)0.3088(4)0.0422(13)
H40.22350.34400.38520.051*
B50.1611(6)0.4511(5)0.2388(4)0.0495(14)
H50.07490.50840.26920.059*
B60.1652(7)0.3869(5)0.1314(4)0.0494(14)
H60.08150.40190.09100.059*
B70.3340(7)0.3690(5)0.0748(4)0.0547(16)
H70.35930.3717−0.00190.066*
B80.4349(7)0.4253(5)0.1480(5)0.0609(17)
H80.52610.46610.11860.073*
B90.3280(7)0.4726(5)0.2506(5)0.0545(15)
H90.34970.54340.28920.065*
B100.2748(7)0.4916(5)0.1392(5)0.0579(16)
H100.26270.57570.10400.070*
C10.3193(5)0.2406(4)0.2423(3)0.0395(11)
C20.1565(5)0.3096(4)0.2334(3)0.0399(10)
C30.4704(5)0.1114(4)0.3718(3)0.0436(11)
C40.4411(6)0.1590(5)0.4574(4)0.0563(14)
H4A0.35270.18410.48090.068*
C50.5429(7)0.1697(6)0.5093(4)0.0718(17)
H5A0.52340.20400.56640.086*
C60.6726(7)0.1292(6)0.4753(5)0.078(2)
H6A0.74170.13710.50890.094*
C70.6997(6)0.0771(6)0.3920(5)0.0733(18)
H7A0.78690.04680.37050.088*
C80.6001(5)0.0691(5)0.3398(4)0.0579(14)
H8A0.62020.03500.28260.069*
C90.3729(5)−0.0076(4)0.2272(3)0.0440(11)
C100.4781(6)−0.0159(5)0.1540(4)0.0621(15)
H10A0.53490.04160.14090.074*
C110.4996(7)−0.1096(5)0.0997(4)0.0727(18)
H110.5715−0.11530.05080.087*
C120.4157(7)−0.1942(5)0.1175(5)0.0709(17)
H120.4298−0.25630.08010.085*
C130.3130(7)−0.1875(5)0.1891(5)0.0758(18)
H130.2575−0.24590.20170.091*
C140.2891(6)−0.0954(4)0.2436(4)0.0564(14)
H140.2165−0.09120.29200.068*
C15−0.1099(5)0.3413(4)0.3477(4)0.0469(12)
C16−0.2313(6)0.3816(5)0.3217(5)0.0676(17)
H16−0.25440.36020.26630.081*
C17−0.3193(6)0.4546(6)0.3792(6)0.085(2)
H17−0.40200.48150.36230.102*
C18−0.2856(7)0.4868(6)0.4597(6)0.088(2)
H18−0.34440.53730.49670.105*
C19−0.1694(7)0.4471(7)0.4861(5)0.090(2)
H19−0.14700.46960.54140.108*
C20−0.0823(6)0.3729(6)0.4319(4)0.0699(17)
H20−0.00290.34320.45230.084*
C21−0.0618(5)0.1887(4)0.1895(3)0.0477(12)
C22−0.0559(5)0.0728(4)0.1814(4)0.0528(13)
H22−0.01590.02400.22360.063*
C23−0.1093(7)0.0296(6)0.1105(5)0.0738(18)
H23−0.1033−0.04820.10470.089*
C24−0.1695(7)0.0988(8)0.0504(5)0.084(2)
H24−0.20580.06830.00370.100*
C25−0.1786(7)0.2121(7)0.0563(4)0.0785(19)
H25−0.22090.25870.01380.094*
C26−0.1245(6)0.2596(5)0.1263(4)0.0627(15)
H26−0.13050.33760.13050.075*
C270.1641(10)0.3281(8)0.7698(6)0.115(3)
H27A0.17120.40530.74530.139*
H27B0.10400.29480.73580.139*

Source of material

The reaction was carried out under an atmosphere of dry nitrogen. Ethanol and dichloromethane were dried and distilled under nitrogen prior to use. 1,2-(PPh2)2-1,2-C2B10H10, was synthesized according to the literature [1]. All the other chemicals were purchased and used as received. AgNO3 (16.9 mg, 0.1 mmol) and 1,2-(PPh2)2-1,2-C2B10H10 (51.2 mg, 0.1 mmol) were mixed in chloromethane (10 mL). The mixture was stirred for 6 h under a dry N2 atmosphere, during which a yellow solution formed. After filtration, the solution was concentrated. The crystals were grown from a dichloromethane/n-hexane solution. (54.1%, m.p. 275–277 K). FT-IR (KBr) v (cm−l): 2989, 2966 2930, 2872 (C—H); 2614, 2602, 2585, 2556 (B—H); 1071 (C—P).

Experimental details

All H atoms were placed geometrically and treated as riding on their parent atoms, with B—H 1.10, C—H 0.96, with Uiso(H) = 1.2Ueq(B), Uiso(H) = 1.5Ueq(C).

Discussion

The title structure possesses a binuclear structure with two bidentate organic ligands and two bridiging nitrato ligands (cf. the figure). Both Ag atoms have the same coordination environment because the complex is located round an inversion center. The Ag atom is tetrahedrally surrounded by two P atoms and two oxygen atoms of two nitrato ligands. The Ag—O bond lengths are 2.326(3) and 2.455(3) Å, which is longer than the corresponding bond reported for the complex [(Ag2(μ-ONO2)2){1,2-(PCy)2-1,2-C2B10H10}2] [2]. The Ag—P bond lengths are 2.4554(13) and 2.4726(13) Å, which are similar with the corresponding bond length of 2.49(3) in the complex [(Ag2(μ-I)2){1,2-(PCy)2-1,2-C2B10H10}2] [2]. The P—Ag—P angle is 90.80(4)°, which is smaller than the corresponding value of [(Ag2(μ-ONO2)2){1,2-(PCy)2-1,2-C2B10H10}2]. A similar change of P—Ag—P angles has also been observed previously [3]. The P(1)—C(1)—C(2)—P(2) angle in the title structure is 0°, while the value of the free ligand is 10.9(4)° [4, 5], indicating that this fragment is planar. The average bond lengths of C—P in the complexes (1.872(3) Å) are in agreement with that of 1.894(3)Å in the free ligand, suggesting that the coordination with the metal atom has no obvious influence on this distance [6].

Acknowledgements

This work was supported by the Key Scientific Research Projects of Colleges and Universities, Henan Province (Nos. 16A150001, 16A430012) and the Research Fund of Anyang Institute of Technology (Nos. YJJ2015021, YJJ2015022).

References

1 Zhang, D. P.; Dou, J. M.; Li, D. C.; Wang, D. Q.: 1,2-Bis(diphenylphosphino) -1,2-dicarba-closo-dodecaborane. Acta Crystallogr. E62 (2006) o418.10.1107/S1600536805042510Suche in Google Scholar

2 Yang, L. G.; Zhu, C. C.; Zhang, D. D.; Li, D. C., Wang, D. Q.; Dou, D. M.: 1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C-H⋯H-B dihydrogen bonding interactions. Polyhedron 30 (2011) 1469–1477.10.1016/j.poly.2011.02.052Suche in Google Scholar

3 Caruso, F.; Camalli, M.; Rimml, H.; Venanzi, L. M.: Coordination properties of silver diphosphine complexes. Crystal and molecular structures of Ag2X2(m-PP)2 (X = I, Cl, NO3; m-PP = 1,3-bis[(diphenylphosphino)methyl]benzene) and Ag2X2(o-PP)2 (X = I, Cl; o-PP = 1,2-bis[(diphenylphosphino)methyl]benzene). Synthesis and 1H- and 31P-NMR spectroscopy of silver diphosphine complexes. Inorg. Chem. 34 (1995) 673–679.10.1021/ic00107a022Suche in Google Scholar

4 Dou, D. M.; Zhang, D. P.; Li, D. C.; Wang, D. Q.: Two type skeleton heterobimetallic trinuclear Cu-Mo-S clusters containing closo carborane diphosphine ligand 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane. Inorg. Chem. Comm. 9 (2006) 1109–1102.10.1016/j.inoche.2006.07.006Suche in Google Scholar

5 Dou, D. M.; Zhang, D. P.; Zhu, Y. H.; Li, D. C.; Wang, D. Q.: Synthesis and characterization of two types of skeleton heterobimetallictrinuclear Mo(W)-Cu-S clusters containing 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane. Polyhedron 26 (2007) 4216–4222.10.1016/j.poly.2007.05.030Suche in Google Scholar

6 Dou, D. M.; Zhang, D. P.; Gong, S. W.; Li, D. C.; Wang, D. Q.: Synthesis and characterization of three dinuclear copper(I) complexes of 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane. Appl. Organometal. Chem. 20 (2006) 632–637.10.1002/aoc.1119Suche in Google Scholar

7 Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Suche in Google Scholar PubMed

8 Bruker. APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, Wisconsin, USA, (2009).Suche in Google Scholar

Received: 2016-7-20
Accepted: 2016-10-14
Published Online: 2016-10-29
Published in Print: 2017-1-1

©2016 Wang Yanfei et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Editorial
  3. Twenty years of crystal structure publication and the road ahead
  4. Crystal Structures
  5. Crystal structure of poly-[triaqua-(μ4-5′-carboxy-[1,1′-biphenyl]-2,3,3′-tricarboxylate-κ6O1,O2:O3,O4:O5:O6)praseodymium(III), C16H13O11Pr
  6. Crystal structure of (R)-1-(2,3-dihydro-1H-pyrrolizin-5-yl)-2,3-dihydroxypropan-1-one, C10H13NO3
  7. Crystal structure of (E)-4-nitro-2-((2-phenoxyphenylimino)methyl)phenol, C19H14N2O4
  8. Crystal structure of 3,3′-di(furan-2-yl)-5,5′-bi-1,2,4-triazine
  9. Crystal structure of 11-(p-coumaroyloxy)-tremetone, C22H20O5
  10. The crystal structure of 1,3-bis(2,6-diiso-propylphenyl)imidazol-2-ylidene)-dibromido-(1-methyl-1H-imidazole-κ1N)palladium(II) – ethyl acetate – water (1/1/1), C31H42Br2N4Pd
  11. Crystal structure of 2-((3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene)-1H-indene-1,3(2H)-dione, C28H19N5O2
  12. Crystal structure of 2-(5-(4-fluorophenyl)-3-p-tolyl-4,5-dihydro-1H-pyrazol-1-yl)-4-(5-methyl-1-p-tolyl-1H-1,2,3-triazol-4-yl)thiazole, C29H25FN6S
  13. Crystal structure of poly-[aqua-(μ7-benzene-1,3,5-tricarboxylato)-(μ3-1,2,4-triazol-1-ido)dicobalt(II)], C11H7Co2N3O7
  14. Crystal constructure of 16(S)-methyl-6α-carboxy-1, 15-dioxo-6, 7-seco-ent-kaur-2-en-7, 20-olide, C20H24O6
  15. Crystal structure of 1-(benzo[d]thiazol-2-yl)-3-phenylthiourea, C14H11N3S2
  16. Crystal structure of 3-(2-bromophenyl)-1,1-dimethylthiourea, C9H11BrN2S
  17. Crystal structure of 1-(adamantan-1-yl)-3-(3-chlorophenyl)thiourea, C17H21ClN2S
  18. Crystal structure of 3-(adamantan-1-yl)-1-(4-bromophenyl)urea, C17H21BrN2O
  19. Crystal structure of (Z)-Ethyl 2-cyano-2-(3-phenylthiazolidin-2-ylidene) acetate, C14H14N2O2S
  20. Crystal structure of methyl 2b-ethyl-1a,2a,2b,2b1,3,5,10,11-octahydro-1H-oxireno[2′,3′:6,7]indolizino[8,1-cd]carbazole-4-carboxylate, C21H24N2O3
  21. Crystal structure of 2-amino-5-oxo-4-(3,4,5-trimethoxy-phenyl)-4,5,6,7-tetrahydro-cyclopenta[b]pyran-3-carbonitrile, C18H18N2O5
  22. Crystal structure of 1,2,3-trimethyl-2,3-dihydro-1H-perimidine, C14H16N2
  23. Crystal structure of bis(2,6-dihydroxymethyl)pyridine-κ3N,O,O′)-bis(μ2-6-chloropyridin-2-olato-κ3N,O:O)-bis(6-chloropyridin-2-olato-κO)-bis(nitrato-κ2O,O′)digadolinium(III), C34H30Cl4Gd2N8O14
  24. Crystal structure of 8-isopropyl-8-aza-bicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate, C19H27NO3
  25. Crystal structure of 1-methyl-3-[((naphthalen-2-ylsulfonyl)oxy)imino]indolin-2-one, C19H14N2O4S
  26. Crystal structure (7,8-bis(diisopropylphosphino)-7,8-dicarba-nido-undecaborane-κ2P,P′)-(benzoato-κ2O,O′)nickel(II), C21H42B9NiO2P2
  27. Crystal structure of methyl-2-methyl-4-(2-oxo-2-phenylethyl)-5-phenyl-1H-pyrrole-3-carboxylate, C21H19NO3
  28. Crystal structure of 2-[(2-oxo-thiazolidine-3-carbonyl)sulfamoyl]-methy-benzoic acid methyl ester, C13H14N2O6S2
  29. Crystal structure of N′-(2-phenylacetyl)thiophene-2-carbohydrazide monohydrate, C13H14N2O3S
  30. Crystal structure of 1,1′-(hexane-1,6-diyl)bis(3-methyl-1H-imidazol-3-ium) bis(hexafluoro phosphate), C14H24F12N4P2
  31. Crystal structure of di-μ-chlorido-bis[1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]zinc(II), C52H108B20Cl2P4Zn2
  32. Crystal structure of dibromido-bis[μ-1-[(2-methyl-1H-benzoimidazol-1-yl)methyl]-1H-benzotriazole-κN]mercury(II), C30H26Br2HgN10
  33. Crystal structure of bis(μ-nitrato-κ2O:O)-bis[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]disilver(I) dicloromethane monosolvate, C54H64B20Cl4O6P4Ag2
  34. Crystal structure of dinuclear dichloridobis(dimethylformamide-kO)bis[μ2-3-(2-oxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazol-1ido-κ4-O,N:N′,N′′(2−)]diiron(III) − dimethylformamide (1/1), C36H42Cl2Fe2N14O6
  35. Crystal structure of diaqua-dinitrato-κO-bis(4-(1H-pyrazol-3-yl)pyridine-κN)manganese(II), C16H18MnN8O8
  36. Crystal structure of (Z)-6-methoxy-2-(2,2,2-trifluoro-1-hydroxyethylidene)-2,3-dihydro-1H-inden-1-one, C12H6F6O3
  37. Crystal Structure of 4-(2-chloroacetamido)pyridinium chloride monohydrate, C7H10Cl2N2O2
  38. Crystal structure of 2-amino-4-(4-chloro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13ClN2O2
  39. Crystal structure of (E)-1-(2-(thiophen-2-ylmethylene)hydrazinyl)phthalazine hydrochloride–ethanol (1/1), C15H17ClN4OS
  40. Crystal structure of N,N-diethyl-5-bromo-3,4-dihydro-2,4-dioxopyrimidine-1(2H)-carboxamide, C9H12BrN3O3
  41. Crystal structure of 3-(2-(4-chlorophenyl)-3-hydroxy-3,3-diphenylpropyl)-1,1-dimethylurea, C24H25ClN2O2
  42. Crystal structure of 3-(4-chlorophenyl)-1,1-dimethylthiourea, C9H11ClN2S
  43. Crystal structure of 2-amino-4-(4-bromo-phenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carbonitrile, C16H11BrN2O3
  44. Crystal structure of 4-(3,4-dimethyl-phenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester, C21H25NO3
  45. Crystal structure of (E)-2-({4-hydroxy-5-methoxy-3-[(4-methyl-1-piperazinyl)methyl]phenyl} methylidene)-1-indanone, C23H26N2O3
  46. Crystal structure of tripropylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate – [1,1′-biphenyl]-2,2′-dicarboxylic acid (2/1), C60H72N2O12
  47. Crystal structure of catena-poly-{aqua-[μ2-1,2-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′]-[μ2-4,4′-(dimethylsilanediyl)dibenzato-κ3O,O′:O′]nickel(II)}, C30H30N4NiO5Si
  48. The crystal structure of 1-(4-bromophenyl)-2-(4-(4-fluorophenyl)piperazin-1-yl)ethanol, C18H20BrFN2O1
  49. Crystal structure of trimethylammonium 4-((4-carboxyphenyl)sulfonyl)benzoate, C17H19NO6S
  50. Crystal structure of syn-2,4-di-o-tolylpentane-2,4-diol, C19H24O2
  51. Crystal structure of 2-[3,5-bis(trifluoromethyl)benzylsulfanyl]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C15H7BrF6N2OS2
  52. Crystal structure of (E)-3-((naphthalen-1-ylimino)methyl)-4-nitrophenol, C17H12N2O3
  53. Crystal structure of 2-dichloromethyl-2-p-nitrophenyl-1,3-dioxolane, C10H9Cl2NO4
  54. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanopalladate(II), C14H24N8Pd2
  55. Crystal structure of 2-(4-oxo-2-thioxothiazolidin-3-yl)acetic acid monohydrate, C5H7NO4S2
  56. Crystal structure of a P4-bridged (η5-pentamethyl-cyclopentadienyl)(η5-adamantylcyclopentadienyl) titanium(III)complex, C50H66P4Ti2
  57. Crystal structure of cis-bis(2,2′-bipyrimidine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C18H12N10NiS2
  58. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)dibromidomanganese(II), C20H16Br2MnN4
  59. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C22H16N6NiS2
  60. Crystal structure of trans-dibromido(1,4,8,11-tetraazacyclotetradecane)nickel(II), C10H24Br2N4Ni
  61. Crystal structure of cis-tetrabromidobis(pyridine-κN)platinum(IV), C10H10Br4N2Pt
  62. Crystal structure of (E)-5-((4-chlorophenyl)diazenyl)-2-(5-(4-fluorophenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-4-methylthiazole, C23H17ClFN5S2
  63. The crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetrachloridocobaltate(II) monohydrate, C10H18Cl4CoN2O
https://doi.org/10.1515/ncrs-2016-0160
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Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Editorial
  3. Twenty years of crystal structure publication and the road ahead
  4. Crystal Structures
  5. Crystal structure of poly-[triaqua-(μ4-5′-carboxy-[1,1′-biphenyl]-2,3,3′-tricarboxylate-κ6O1,O2:O3,O4:O5:O6)praseodymium(III), C16H13O11Pr
  6. Crystal structure of (R)-1-(2,3-dihydro-1H-pyrrolizin-5-yl)-2,3-dihydroxypropan-1-one, C10H13NO3
  7. Crystal structure of (E)-4-nitro-2-((2-phenoxyphenylimino)methyl)phenol, C19H14N2O4
  8. Crystal structure of 3,3′-di(furan-2-yl)-5,5′-bi-1,2,4-triazine
  9. Crystal structure of 11-(p-coumaroyloxy)-tremetone, C22H20O5
  10. The crystal structure of 1,3-bis(2,6-diiso-propylphenyl)imidazol-2-ylidene)-dibromido-(1-methyl-1H-imidazole-κ1N)palladium(II) – ethyl acetate – water (1/1/1), C31H42Br2N4Pd
  11. Crystal structure of 2-((3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene)-1H-indene-1,3(2H)-dione, C28H19N5O2
  12. Crystal structure of 2-(5-(4-fluorophenyl)-3-p-tolyl-4,5-dihydro-1H-pyrazol-1-yl)-4-(5-methyl-1-p-tolyl-1H-1,2,3-triazol-4-yl)thiazole, C29H25FN6S
  13. Crystal structure of poly-[aqua-(μ7-benzene-1,3,5-tricarboxylato)-(μ3-1,2,4-triazol-1-ido)dicobalt(II)], C11H7Co2N3O7
  14. Crystal constructure of 16(S)-methyl-6α-carboxy-1, 15-dioxo-6, 7-seco-ent-kaur-2-en-7, 20-olide, C20H24O6
  15. Crystal structure of 1-(benzo[d]thiazol-2-yl)-3-phenylthiourea, C14H11N3S2
  16. Crystal structure of 3-(2-bromophenyl)-1,1-dimethylthiourea, C9H11BrN2S
  17. Crystal structure of 1-(adamantan-1-yl)-3-(3-chlorophenyl)thiourea, C17H21ClN2S
  18. Crystal structure of 3-(adamantan-1-yl)-1-(4-bromophenyl)urea, C17H21BrN2O
  19. Crystal structure of (Z)-Ethyl 2-cyano-2-(3-phenylthiazolidin-2-ylidene) acetate, C14H14N2O2S
  20. Crystal structure of methyl 2b-ethyl-1a,2a,2b,2b1,3,5,10,11-octahydro-1H-oxireno[2′,3′:6,7]indolizino[8,1-cd]carbazole-4-carboxylate, C21H24N2O3
  21. Crystal structure of 2-amino-5-oxo-4-(3,4,5-trimethoxy-phenyl)-4,5,6,7-tetrahydro-cyclopenta[b]pyran-3-carbonitrile, C18H18N2O5
  22. Crystal structure of 1,2,3-trimethyl-2,3-dihydro-1H-perimidine, C14H16N2
  23. Crystal structure of bis(2,6-dihydroxymethyl)pyridine-κ3N,O,O′)-bis(μ2-6-chloropyridin-2-olato-κ3N,O:O)-bis(6-chloropyridin-2-olato-κO)-bis(nitrato-κ2O,O′)digadolinium(III), C34H30Cl4Gd2N8O14
  24. Crystal structure of 8-isopropyl-8-aza-bicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate, C19H27NO3
  25. Crystal structure of 1-methyl-3-[((naphthalen-2-ylsulfonyl)oxy)imino]indolin-2-one, C19H14N2O4S
  26. Crystal structure (7,8-bis(diisopropylphosphino)-7,8-dicarba-nido-undecaborane-κ2P,P′)-(benzoato-κ2O,O′)nickel(II), C21H42B9NiO2P2
  27. Crystal structure of methyl-2-methyl-4-(2-oxo-2-phenylethyl)-5-phenyl-1H-pyrrole-3-carboxylate, C21H19NO3
  28. Crystal structure of 2-[(2-oxo-thiazolidine-3-carbonyl)sulfamoyl]-methy-benzoic acid methyl ester, C13H14N2O6S2
  29. Crystal structure of N′-(2-phenylacetyl)thiophene-2-carbohydrazide monohydrate, C13H14N2O3S
  30. Crystal structure of 1,1′-(hexane-1,6-diyl)bis(3-methyl-1H-imidazol-3-ium) bis(hexafluoro phosphate), C14H24F12N4P2
  31. Crystal structure of di-μ-chlorido-bis[1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]zinc(II), C52H108B20Cl2P4Zn2
  32. Crystal structure of dibromido-bis[μ-1-[(2-methyl-1H-benzoimidazol-1-yl)methyl]-1H-benzotriazole-κN]mercury(II), C30H26Br2HgN10
  33. Crystal structure of bis(μ-nitrato-κ2O:O)-bis[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]disilver(I) dicloromethane monosolvate, C54H64B20Cl4O6P4Ag2
  34. Crystal structure of dinuclear dichloridobis(dimethylformamide-kO)bis[μ2-3-(2-oxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazol-1ido-κ4-O,N:N′,N′′(2−)]diiron(III) − dimethylformamide (1/1), C36H42Cl2Fe2N14O6
  35. Crystal structure of diaqua-dinitrato-κO-bis(4-(1H-pyrazol-3-yl)pyridine-κN)manganese(II), C16H18MnN8O8
  36. Crystal structure of (Z)-6-methoxy-2-(2,2,2-trifluoro-1-hydroxyethylidene)-2,3-dihydro-1H-inden-1-one, C12H6F6O3
  37. Crystal Structure of 4-(2-chloroacetamido)pyridinium chloride monohydrate, C7H10Cl2N2O2
  38. Crystal structure of 2-amino-4-(4-chloro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13ClN2O2
  39. Crystal structure of (E)-1-(2-(thiophen-2-ylmethylene)hydrazinyl)phthalazine hydrochloride–ethanol (1/1), C15H17ClN4OS
  40. Crystal structure of N,N-diethyl-5-bromo-3,4-dihydro-2,4-dioxopyrimidine-1(2H)-carboxamide, C9H12BrN3O3
  41. Crystal structure of 3-(2-(4-chlorophenyl)-3-hydroxy-3,3-diphenylpropyl)-1,1-dimethylurea, C24H25ClN2O2
  42. Crystal structure of 3-(4-chlorophenyl)-1,1-dimethylthiourea, C9H11ClN2S
  43. Crystal structure of 2-amino-4-(4-bromo-phenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carbonitrile, C16H11BrN2O3
  44. Crystal structure of 4-(3,4-dimethyl-phenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester, C21H25NO3
  45. Crystal structure of (E)-2-({4-hydroxy-5-methoxy-3-[(4-methyl-1-piperazinyl)methyl]phenyl} methylidene)-1-indanone, C23H26N2O3
  46. Crystal structure of tripropylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate – [1,1′-biphenyl]-2,2′-dicarboxylic acid (2/1), C60H72N2O12
  47. Crystal structure of catena-poly-{aqua-[μ2-1,2-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′]-[μ2-4,4′-(dimethylsilanediyl)dibenzato-κ3O,O′:O′]nickel(II)}, C30H30N4NiO5Si
  48. The crystal structure of 1-(4-bromophenyl)-2-(4-(4-fluorophenyl)piperazin-1-yl)ethanol, C18H20BrFN2O1
  49. Crystal structure of trimethylammonium 4-((4-carboxyphenyl)sulfonyl)benzoate, C17H19NO6S
  50. Crystal structure of syn-2,4-di-o-tolylpentane-2,4-diol, C19H24O2
  51. Crystal structure of 2-[3,5-bis(trifluoromethyl)benzylsulfanyl]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C15H7BrF6N2OS2
  52. Crystal structure of (E)-3-((naphthalen-1-ylimino)methyl)-4-nitrophenol, C17H12N2O3
  53. Crystal structure of 2-dichloromethyl-2-p-nitrophenyl-1,3-dioxolane, C10H9Cl2NO4
  54. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanopalladate(II), C14H24N8Pd2
  55. Crystal structure of 2-(4-oxo-2-thioxothiazolidin-3-yl)acetic acid monohydrate, C5H7NO4S2
  56. Crystal structure of a P4-bridged (η5-pentamethyl-cyclopentadienyl)(η5-adamantylcyclopentadienyl) titanium(III)complex, C50H66P4Ti2
  57. Crystal structure of cis-bis(2,2′-bipyrimidine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C18H12N10NiS2
  58. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)dibromidomanganese(II), C20H16Br2MnN4
  59. Crystal structure of cis-bis(2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C22H16N6NiS2
  60. Crystal structure of trans-dibromido(1,4,8,11-tetraazacyclotetradecane)nickel(II), C10H24Br2N4Ni
  61. Crystal structure of cis-tetrabromidobis(pyridine-κN)platinum(IV), C10H10Br4N2Pt
  62. Crystal structure of (E)-5-((4-chlorophenyl)diazenyl)-2-(5-(4-fluorophenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-4-methylthiazole, C23H17ClFN5S2
  63. The crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetrachloridocobaltate(II) monohydrate, C10H18Cl4CoN2O
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Heruntergeladen am 5.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2016-0160/html
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