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Tribomechanical properties of direct energy deposited ceramic reinforced coatings on alloy TC4

  • Esad Kaya was born in 1990. He got a Ph.D. degree in 2021 from Eskişehir Osmangazi University in Turkey. His main research area is tribology, heat treatment, and metallic material design and characteristics. He has been an associate professor at the mechanical engineering department of Eskişehir Osmangazi University, the material science discipline. He has 14 science citation indexed publications with the h index of 5 over 100 citations.

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    Koray Kılıçay was born in 1987. He got a Ph.D. degree in 2017 from Eskişehir Osmangazi University in Turkey. His main research areas are technical sciences, metallurgical and materials engineering, materials science and engineering, material characterization, materials science, coating technology, and composite materials. He has been an associate professor at the Eskişehir Osmangazi University in the material science discipline for 5 years. He has a science citation index of 15 publications with an h index of 7 over 100 citations.

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    Tuğçe Güleç was born in 1992. She got a master of science degree in mechanical engineering from Eskişehir Osmangazi University in 2024. Her main research areas are material designs and behaviors, manufacturing technologies, and product design. She has been a research assistant at the Eskişehir Osmangazi University in the mechanical engineering department for 5 years.

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Published/Copyright: January 13, 2026
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Abstract

In this study, TC4 (Ti6Al4V) surface alloyed with TiC and C powders in varied volumetric ratios utilizing robotic plasma transferred arc (PTA) welding. The coated zone had no microstructural defects like fractures, porosity, or voids, eliminating operator errors – a durable metallurgical bond established between the substrate and coating. X-ray diffraction (XRD) analysis indicated the formation of TiC, VC, and TiV–C ternary compounds during the coating process, with the α-Ti structure frequently seen. Gibbs free energy projections confirm XRD results. Graphite-TiC combination increased hardness 1.3–1.8 times. The sole TiC powder reinforced sample had the maximum hardness (573 ± 159 HV0.1) compared to the substrate (298 ± 11 HV0.1). Coating elasticity modules were calculated. The modulus of elasticity increased up to 2.44 times. The plasticity index accurately predicted sample load and deformation resistance. Sole graphite reinforcement had the lowest friction behavior, and the sole TiC powder-enhanced sample had the maximum wear resistance. The sole TiC-coated sample had an 11.5-fold improvement in wear resistance. Graphite–TiC combined samples improved wear resistance by 2.4–2.67 times. The addition of graphite reduced COF by 55 %. The findings point to a powder mixture with a high graphite content to reduce friction in machine components.


Corresponding author: Esad Kaya, Department of Mechanical Engineering, Eskisehir Osmangazi University, 26480, Odunpazarı, Eskişehir, Türkiye, E-mail:

About the authors

Esad Kaya

Esad Kaya was born in 1990. He got a Ph.D. degree in 2021 from Eskişehir Osmangazi University in Turkey. His main research area is tribology, heat treatment, and metallic material design and characteristics. He has been an associate professor at the mechanical engineering department of Eskişehir Osmangazi University, the material science discipline. He has 14 science citation indexed publications with the h index of 5 over 100 citations.

Koray Kılıçay

Koray Kılıçay was born in 1987. He got a Ph.D. degree in 2017 from Eskişehir Osmangazi University in Turkey. His main research areas are technical sciences, metallurgical and materials engineering, materials science and engineering, material characterization, materials science, coating technology, and composite materials. He has been an associate professor at the Eskişehir Osmangazi University in the material science discipline for 5 years. He has a science citation index of 15 publications with an h index of 7 over 100 citations.

Tuğçe Güleç

Tuğçe Güleç was born in 1992. She got a master of science degree in mechanical engineering from Eskişehir Osmangazi University in 2024. Her main research areas are material designs and behaviors, manufacturing technologies, and product design. She has been a research assistant at the Eskişehir Osmangazi University in the mechanical engineering department for 5 years.

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

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Published Online: 2026-01-13
Published in Print: 2026-02-24

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