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Hardness and corrosion properties of AA7075 aluminum alloy coated with WC-Co by HVOF

  • Hasan Hasırcı

    Assoc. Prof. Dr. Hasan Hasırcı, born in 1974, graduated from Gazi University in 1996. He received MSc degree at Gazi University in 2000 and Ph.D degree at Gazi University in 2006. He is currently working as a faculty member in the Department of Metallurgical and Materials Engineering at Gazi University in Ankara. His research areas include cermet coating, heat treatment, wear, casting, and composite materials.

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    and Kubilay Karacif

    Assoc. Prof. Dr. Kubilay Karacif, born in 1972, graduated from Istanbul Technical University in 1994. He received MSc degree at Gazi University in 1999 and Ph.D degree at Gazi University in 2005. Karacif worked as a research assistant at Gazi University in Ankara between 1995 and 2007. He is currently working as a faculty member in the Department of Metallurgical and Materials Engineering at Hitit University in Çorum. His research areas include powder metallurgy, corrosion, composite materials, microstructure, and mechanical properties.

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Published/Copyright: August 29, 2025
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Abstract

In this study, AA7075-T6 aluminum alloy substrates were coated with WC-Co by the high velocity oxy-fuel (HVOF) method. The coatings were applied in two and four layers to surfaces with three different roughnesses. The effects of WC-Co coating applied to the AA7075 aluminum surface on the hardness and corrosion properties of the alloy were examined. The corrosion properties of uncoated and WC-Co coated aluminum alloy samples were determined in salt water environment by potentiodynamic corrosion tests. Additionally, microstructure and XRD examinations of the samples were performed. The surface hardness of WC-Co coated samples increased by up to 140 %. According to the results of corrosion tests, it was determined that the WC-Co coating applied to the surface of AA7075 aluminum alloy improved its corrosion resistance by reducing the corrosion rate of the alloy. The best corrosion resistance was obtained in four layers of coating on the sample with the smallest surface roughness.


Corresponding author: Kubilay Karacif, Metallurgical and Materials Engineering, Hitit University, Corum, 19030, Türkiye, E-mail:

About the authors

Hasan Hasırcı

Assoc. Prof. Dr. Hasan Hasırcı, born in 1974, graduated from Gazi University in 1996. He received MSc degree at Gazi University in 2000 and Ph.D degree at Gazi University in 2006. He is currently working as a faculty member in the Department of Metallurgical and Materials Engineering at Gazi University in Ankara. His research areas include cermet coating, heat treatment, wear, casting, and composite materials.

Kubilay Karacif

Assoc. Prof. Dr. Kubilay Karacif, born in 1972, graduated from Istanbul Technical University in 1994. He received MSc degree at Gazi University in 1999 and Ph.D degree at Gazi University in 2005. Karacif worked as a research assistant at Gazi University in Ankara between 1995 and 2007. He is currently working as a faculty member in the Department of Metallurgical and Materials Engineering at Hitit University in Çorum. His research areas include powder metallurgy, corrosion, composite materials, microstructure, and mechanical properties.

  1. Research ethics: There is no problem in terms of research ethics.

  2. Informed consent: Not applicable.

  3. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors (Hasan Hasırcı and Kubilay Karacif) state no conflict of interest.

  6. Research funding: The study was not financially supported. (None declared).

  7. Data availability: The raw data can be obtained on request from the corresponding author.

References

[1] G. Bolelli, L. Lusvarghi, and M. Barletta, “HVOF-sprayed WC-CoCr coatings on Al alloy: effect of the coating thickness on the tribological properties,” Wear, vol. 267, pp. 944–953, 2009, https://doi.org/10.1016/j.wear.2008.12.066.Search in Google Scholar

[2] H. Varol Ozkavak, S. Sahin, M. F. Sarac, and Z. Alkan, “Wear properties of WC-Co and WC-CoCr coatings [applied by HVOF technique on different steel substrates,” Mater. Test., vol. 62, no. 12, pp. 1235–1242, 2020, https://doi.org/10.3139/120.111609.Search in Google Scholar

[3] S. Islak, et al.., “Microstructure characterization of WCCo-Mo based coatings produced using high velocity oxygen fuel,” Pamukkale Uni. J. Eng. Sci., vol. 21, no. 8, pp. 344–347, 2015, https://doi.org/10.5505/pajes.2015.56933.Search in Google Scholar

[4] C. Özorak, F. Okay, E. Özorak, and S. Islak, “Wear and microstructural properties of coatings on Weldox 700 steel,” Mater. Test., vol. 62, no. 6, pp. 645–651, 2020, https://doi.org/10.3139/120.111526.Search in Google Scholar

[5] S. Özel, “Microstructure and mechanical properties of HVOF sprayed WC-Co/NiCrBSi, Cr3C2 coatings on Al alloys,” Mater. Test., vol. 55, no. 9, pp. 694–700, 2013, https://doi.org/10.3139/120.110489.Search in Google Scholar

[6] O. P. Oladijo, N. Sacks, L. A. Cornish, and A. M. Venter, “Effect of substrate on the 3 body abrasion wear of HVOF WC-17 wt.% Co coatings,” Int. J. Refract. Met. Hard Mater., vol. 35, pp. 288–294, 2012, https://doi.org/10.1016/j.ijrmhm.2012.06.011.Search in Google Scholar

[7] M. Couto, S. Dosta, and J. M. Guilemany, “Comparison of the mechanical and electrochemical properties of WC-17 and 12Co coatings onto Al7075-T6 obtained by high velocity oxy-fuel and cold gas spraying,” Surf. Coat. Technol., vol. 268, pp. 180–189, 2015, https://doi.org/10.1016/j.surfcoat.2014.04.034.Search in Google Scholar

[8] H. Durmuş, M. Türkmen, and U. Çalıgülü, “Investigation of tribological properties of WC coatings applied to different substrate materials,” Technol. Appl. Sci., vol. 15, no. 2, pp. 23–28, 2020, https://doi.org/10.12739/NWSA.2020.15.2.2A0181.Search in Google Scholar

[9] Y. Özgürlük, “Evaluation of hot corrosion behavior of WC-Co-Cr coatings coated by the HVOF method,” J. Mater. Mechatron., vol. 4, no. 1, pp. 286–301, 2023, https://doi.org/10.55546/jmm.1287543.Search in Google Scholar

[10] A. Lekatou, D. Zois, A. E. Karantzalis, and D. Grimanelis, “Electrochemical behaviour of cermet coatings with a bond coat on Al7075: Pseudopassivity, localized corrosion and galvanic effect considerations in a saline environment,” Corros. Sci., vol. 52, pp. 2616–2635, 2010, https://doi.org/10.1016/j.corsci.2010.04.010.Search in Google Scholar

[11] D. S. Prasad, P. T. Radha, C. Shoba, and P. S. Rao, “Dynamic mechanical behavior of WC-Co coated A356.2 aluminum alloy,” J. Alloys Compd., vol. 767, pp. 988–993, 2018, https://doi.org/10.1016/j.jallcom.2018.07.203.Search in Google Scholar

[12] A. Lekatou, D. Zois, and D. Grimanelis, “Corrosion properties of HVOF cermet coatings with bond coats in an aqueous chloride environment,” Thin Solid Films, vol. 516, pp. 5700–5705, 2008, https://doi.org/10.1016/j.tsf.2007.07.130.Search in Google Scholar

[13] R.V. Prasad, R. Rajesh, D. Thirumalaikumarasamy, M. Ashokkumar, and S. Rajakumar, “Multi response optimization of HVOF process parameters in low carbon steels,” Sadhana, vol. 47, pp. 265–282, 2022, https://doi.org/10.1007/s12046-022-02045-4.Search in Google Scholar

[14] R. V. Prasad, R. Rajesh, D. Thirumalaikumarasamy, S. Vignesh, and A. Sreesabari, “Sensitivity analysis and optimisation of HVOF process inputs to reduce porosity and maximise hardness of WC-10Co-4Cr coatings,” Sadhana, vol. 46, pp. 149–172, 2021, https://doi.org/10.1007/s12046-021-01667-4.Search in Google Scholar

[15] C. J. Villalobos-Gutierrez, et al.., “Fatigue and corrosion fatigue behavior of an AA6063-T6 aluminum alloy coated with a WC-10Co-4Cr alloy deposited by HVOF thermal spraying,” Surf. Coat. Technol., vol. 202, pp. 4572–4577, 2008, https://doi.org/10.1016/j.surfcoat.2008.04.044.Search in Google Scholar

[16] A. Lekatou, D. Sioulas, A. E. Karantzalis, and D. Grimanelis, “A comparative study on the microstructure and surface property evaluation of coatings produced from nanostructured and conventional WC-Co powders HVOF-sprayed on Al7075,” Surf. Coat. Technol., vol. 276, pp. 539–556, 2015, https://doi.org/10.1016/j.surfcoat.2015.06.017.Search in Google Scholar

[17] M. Magnani, et al.., “Influence of HVOF parameters on the corrosion and wear resistance of WC-Co coatings sprayed on AA7050 T7,” Surf. Coat. Technol., vol. 202, pp. 4746–4757, 2008, https://doi.org/10.1016/j.surfcoat.2008.04.055.Search in Google Scholar

[18] R. S. Ghai, K. Chen, and N. Baddour, “Modelling thermal conductivity of porous thermal barrier coatings,” Coatings, vol. 9, no. 2, pp. 1–28, 2019, https://doi.org/10.3390/coatings9020101.Search in Google Scholar

[19] L. Wang, et al.., “Influence of pores on the thermal insulation behavior of thermal barrier coatings prepared by atmospheric plasma spray,” Mater. Des., vol. 32, no. 1, pp. 36–47, 2011, https://doi.org/10.1016/j.matdes.2010.06.040.Search in Google Scholar

[20] S. Wei, F. Wang, Q. B. Fan, and Z. Ma, “Effects of defects on the effective thermal conductivity of thermal barrier coatings,” Appl. Math. Model., vol. 36, no. 5, pp. 1995–2002, 2012, https://doi.org/10.1016/j.apm.2011.08.018.Search in Google Scholar

[21] C. J. Li and A. Ohmori, “Relationships between the microstructure and properties of thermally sprayed deposits,” J. Therm. Spray Technol., vol. 11, no. 3, pp. 365–374, 2002, https://doi.org/10.1361/105996302770348754.Search in Google Scholar

[22] M. P. Schmitt, A. K. Rai, R. Bhattacharya, D. Zhu, and D. E. Wolfe, “Multilayer thermal barrier coating (TBC) architectures utilizing rare earth doped YSZ and rare earth pyrochlores,” Surf. Coat. Technol., vol. 251, pp. 56–63, 2014, https://doi.org/10.1016/j.surfcoat.2014.03.049.Search in Google Scholar

[23] M. Zhao and W. Pan, “Effect of lattice defects on thermal conductivity of Ti-doped, Y2O3-stabilized ZrO2,” Acta Mater., vol. 61, no. 14, pp. 5496–5503, 2013, https://doi.org/10.1016/j.actamat.2013.05.038.Search in Google Scholar

[24] I. D. Utu, I. Hulka, and V. A. Serban, “Microstructure and abrasion wear resistance of thermally sprayed cermet coatings,” Mater. Test., vol. 55, no. 1, pp. 47–50, 2013, https://doi.org/10.3139/120.110402.Search in Google Scholar

[25] C. Monticelli, A. Frignani, and F. Zucchi, “Investigation on the corrosion process of carbon steel coated by HVOF WC/Co cermets in neutral solution,” Corros. Sci., vol. 46, no. 5, pp. 1225–1237, 2004, https://doi.org/10.1016/j.corsci.2003.09.013.Search in Google Scholar

[26] J. M. Guilemany, S. Dosta, J. Nin and J.R. Miguel, “Study of the properties of WC-Co nanostructured coatings sprayed by high-velocity oxyfuel,” J. Therm. Spray Technol., vol. 14, no. 3, pp. 405–413, 2005, https://doi.org/10.31399/asm.cp.itsc2005p0530.Search in Google Scholar

Published Online: 2025-08-29
Published in Print: 2025-10-27

© 2025 Walter de Gruyter GmbH, Berlin/Boston

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