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Diffusion kinetics of borided of low entropy soft magnetic FeCo alloy

  • Ersan Mertgenç

    Ersan Mertgenç is an Assistant Professor in the Afyon Vocational High School of Afyon Kocatepe University, Turkey. He graduated from Afyon Kocatepe University, Afyonkarahisar, Turkey, in 2002. He holds an MSc and PhD at Afyon Kocatepe University, Afyonkarahisar, Turkey, in 2004 and 2015, respectively. He became an associate professor in 2024. He studied on production of alloys, coating, surface hardening, tribological and corrosion application of materials.

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Published/Copyright: November 6, 2024
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Abstract

The growth kinetics of boride layers were investigated by boronizing the FeCo low entropy alloy produced by arc melting reverse vacuum system with the pack boriding method at temperatures of 1173 K, 1223 K, 1273 K and for 2, 4, 6 h. FeCo alloy has a single-phase FCC crystal structure and there are linear cracks and homogeneously distributed point voids in its microstructure. The hardness of FeCo alloy is between 170 HV0.05 and 265 HV0.05. The boride layer appearance has a sawtooth appearance, and the layer thickness varies between 62 µm and 172 µm depending on temperature and time. According to the XRD pattern, (CoFe)B and (CoFe)B2 triple phases are present on the boride layer surface. With pack boriding, the hardness of the boride layer increased up to 2262 HV0.05, and the surface hardness of the alloy improved by 8–10 times. The boride layer activation energy of the FeCo alloy boronized with pack boriding was calculated as 89.065 kJ mol−1.


Corresponding author: Ersan Mertgenç, Department of Railway Systems, Afyon Vocational High School, 53002 Afyon Kocatepe Universitesi , Afyon, 03200, Türkiye, E-mail:

About the author

Ersan Mertgenç

Ersan Mertgenç is an Assistant Professor in the Afyon Vocational High School of Afyon Kocatepe University, Turkey. He graduated from Afyon Kocatepe University, Afyonkarahisar, Turkey, in 2002. He holds an MSc and PhD at Afyon Kocatepe University, Afyonkarahisar, Turkey, in 2004 and 2015, respectively. He became an associate professor in 2024. He studied on production of alloys, coating, surface hardening, tribological and corrosion application of materials.

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: The author has accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The author states no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

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Published Online: 2024-11-06
Published in Print: 2024-12-17

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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