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Determination of characteristic properties of Co3O4 loaded LaFe x Al12−x O19 hexaaluminates

  • Meltem Karaismailoglu Elibol

    Asst. Prof. Meltem Karaismailoglu Elibol, born in 1986, received her B.Sc. in Chemistry from Yildiz Technical University, Turkey in 2010 and her M. Sc. from Munich Technical University, Germany in 2012. In 2019 she finished her Ph.D. in Chemical Engineering at YTU. Her research interests include the development of catalysts for catalytic hydrogen generation from methane and biomass. She is currently working as an assistant professor at Turkish-German University, Turkey.

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Published/Copyright: January 5, 2024
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Abstract

Hexaaluminates are drawing attention due to their exceptional mechanical and thermal stability. They can be proposed for applications as catalysts or catalyst support materials in high-temperature reactions. In this study, various LaFe x Al12−x O19 samples (x = 0.25, 0.5, 1, and 2) have been synthesized using the sol–gel method. Subsequently, these hexaaluminate samples were impregnated with cobalt oxide to form more active centers on the hexaaluminate support. The influence of the iron (Fe) content on the crystal structure, redox properties, and oxygen immobility has been investigated through X-ray diffraction, hydrogen temperature-programmed reduction, and oxygen temperature-programmed desorption techniques. Among the Co3O4@LaFe x Al12−x O19 samples, those with x ≥ 1 exhibited a hexaaluminate crystalline structure, demonstrating a higher lattice oxygen mobility.


Corresponding author: Meltem Karaismailoglu Elibol, Department of Energy Science and Technology, Turkish-German University, Istanbul, 34820, Turkey, E-mail:

Funding source: Turkish-German University Scientific Research Projects Commission under the grant no: 2021BF05

About the author

Meltem Karaismailoglu Elibol

Asst. Prof. Meltem Karaismailoglu Elibol, born in 1986, received her B.Sc. in Chemistry from Yildiz Technical University, Turkey in 2010 and her M. Sc. from Munich Technical University, Germany in 2012. In 2019 she finished her Ph.D. in Chemical Engineering at YTU. Her research interests include the development of catalysts for catalytic hydrogen generation from methane and biomass. She is currently working as an assistant professor at Turkish-German University, Turkey.

  1. Research ethics: Not applicable.

  2. Author contributions: The author has accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The author states no conflict of interest.

  4. Research funding: This study was supported by Turkish-German University Scientific Research Projects Commission under the grant no: 2021BF05.

  5. Data availability: Not applicable.

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Published Online: 2024-01-05
Published in Print: 2024-02-26

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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