Home Precipitation of carbides in a nickel-based cast heat-resistant alloy during thermal exposure: evolution of microstructure, hardness and corrosion properties
Article
Licensed
Unlicensed Requires Authentication

Precipitation of carbides in a nickel-based cast heat-resistant alloy during thermal exposure: evolution of microstructure, hardness and corrosion properties

  • Kubilay Öztürk

    Kubilay Öztürk graduated with MSc degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey. He is working as an engineer at TOFAS company. His main research areas are composite materials and heat treatment.

    , Alptekin Kısasöz

    Dr. Alptekin Kısasöz, graduated with PhD degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey in 2015. He is working as an associate professor at Yildiz Technical University in the Department of Metallurgical and Materials Engineering. His main research areas are physical metallurgy and welding metallurgy.

    ORCID logo EMAIL logo
    , Gökhan Özer

    Dr. Gökhan Özer graduated with PhD degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey. He is working as an assistant professor at Fatih Sultan Mehmet Vakif University. His main research areas are the corrosion properties of non-ferrous alloys.

    and Ahmet Karaaslan

    Dr. Ahmet Karaaslan graduated with PhD degree in Metallurgical and Materials Engineering Montanuniversität Leoben. He is working at Gedik Company as a Welding Director. His main research areas are physical metallurgy and welding metallurgy.

Published/Copyright: February 3, 2023
Become an author with De Gruyter Brill

Abstract

Ni-based G-NiCr28W alloy, which is widely preferred in high-temperature applications, has an austenite matrix as well as carbides dispersed in the structure. The morphology of the carbides in the structure varies depending on the chemical composition and heat treatment. Carbide phases commonly seen in these alloys are MC, M7C3, and M23C6. These carbides can transform into each other and the mechanical properties of the alloy can be affected by the carbide transformation. In this study, the effects of the carbides on the morphology, distribution, and strength of the alloy were investigated following the solution treatment applied at different temperatures and durations. Samples were characterized by light metal microscopy, SEM, EDS, XRD analysis, hardness, and potentiodynamic polarization tests. After the process, due to the excess of more stable carbides and their homogeneous distribution within the structure, the highest hardness and corrosion values were revealed in the sample that was processed at 1000 °C for 100 h.


Corresponding author: Alptekin Kısasöz, Yildiz Technical University, Istanbul, 34349, Türkiye, E-mail:

About the authors

Kubilay Öztürk

Kubilay Öztürk graduated with MSc degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey. He is working as an engineer at TOFAS company. His main research areas are composite materials and heat treatment.

Alptekin Kısasöz

Dr. Alptekin Kısasöz, graduated with PhD degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey in 2015. He is working as an associate professor at Yildiz Technical University in the Department of Metallurgical and Materials Engineering. His main research areas are physical metallurgy and welding metallurgy.

Gökhan Özer

Dr. Gökhan Özer graduated with PhD degree in Metallurgical and Materials Engineering from Yildiz Technical University, Istanbul, Turkey. He is working as an assistant professor at Fatih Sultan Mehmet Vakif University. His main research areas are the corrosion properties of non-ferrous alloys.

Ahmet Karaaslan

Dr. Ahmet Karaaslan graduated with PhD degree in Metallurgical and Materials Engineering Montanuniversität Leoben. He is working at Gedik Company as a Welding Director. His main research areas are physical metallurgy and welding metallurgy.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

[1] C. F. Tang, F. Pan, X. H. Qu, B. H. Duan, and X. B. He, “Nickel base superalloy gh4049 prepared by powder metallurgy,” J. Alloys Compd., vol. 474, pp. 201–205, 2019, https://doi.org/10.1016/j.jallcom.2008.06.038.Search in Google Scholar

[2] C. Tian, G. Han, C. Cui, and X. Sun, “Effects of stacking fault energy on the creep behaviors of Ni-base superalloy,” Mater. Des., vol. 64, pp. 316–323, 2014, https://doi.org/10.1016/j.matdes.2014.08.007.Search in Google Scholar

[3] Z. L. Zhao, Y. Q. Ning, H. Z. Guo, Z. K. Yao, and M. W. Fu, “Discontinuous yielding in Ni-base superalloys during high-speed deformation,” Mater. Sci. Eng., A, vol. 620, pp. 282–289, 2015, https://doi.org/10.1016/j.msea.2014.10.041.Search in Google Scholar

[4] V. V. Nasteka, I. R. Kuzeev, B. O. Bolshakov, A. D. Mingazhev, and V. A. Gafarova, “Effect of high energy ion-implantation treatment on properties of heat-resistant nickel alloys of blades of gas-compressor units,” Mater. Today Proc., vol. 19, pp. 2056–2059, 2019, https://doi.org/10.1016/j.matpr.2019.07.073.Search in Google Scholar

[5] A. Kisasoz, M. Tumer, and A. Karaaslan, “Microstructure, mechanical and corrosion properties of nickel superalloy weld metal,” Mater. Test., vol. 63, pp. 895–900, 2021, https://doi.org/10.1515/mt-2021-0016.Search in Google Scholar

[6] A. Athiroj, P. Wangyao, F. Hartung, and G. Lothongkum, “Low heat input welding of nickel superalloy GTD-111 with Inconel 625 filler metal,” Mater. Test., vol. 60, pp. 22–30, 2017, https://doi.org/10.3139/120.111131.Search in Google Scholar

[7] C. Paa-rai, G. Lothongkum, and P. Wangyao, “Effect of cooling rates of solution treatment on rejuvenation heat-treated microstructures of a cast nickel-based superalloy,” Mater. Test., vol. 63, pp. 105–112, 2021, https://doi.org/10.1515/mt-2020-0016.Search in Google Scholar

[8] J. Polak, M. Petrenec, A. Chlupova, J. Tobias, and R. Petras, “Cyclic plastic response of nickel-based superalloy at room and at elevated temperatures,” Mater. Test., vol. 57, pp. 119–125, 2018, https://doi.org/10.3139/120.110688.Search in Google Scholar

[9] T. Jokisch, N. Doynov, R. Ossenbrink, and V. G. Michailov, “Heat source model for electron beam welding of nickel-based superalloys,” Mater. Test., vol. 63, pp. 17–28, 2021, https://doi.org/10.1515/mt-2020-0002.Search in Google Scholar

[10] M. N. Rao, “Pitting corrosion of sheets of a nickel-base superalloy,” Mater. Corros., vol. 60, pp. 49–52, 2009, https://doi.org/10.1002/maco.200805009.Search in Google Scholar

[11] J. Rodríquez, S. Haro, A. Velasco, and R. Colás, “Aging of cast Ni-base heat resisting alloy,” Int. J. Cast Metals Res., vol. 17, pp. 188–192, 2004, https://doi.org/10.1179/136404604225017500.Search in Google Scholar

[12] W. Hermann, J. Lacaze, and D. Oquab, “Effect of different heat treatments on microstructure and segregation of a nickel base alloy,” Adv. Eng. Mater., vol. 5, pp. 32–36, 2003, https://doi.org/10.1002/adem.200390003.Search in Google Scholar

[13] A. Strondl, S. Milenkovic, A. Schneider, U. Klement, and G. Frommeyer, “Effect of processing on microstructure and physical properties of three nickel-based superalloys with different hardening mechanisms,” Adv. Eng. Mater., vol. 14, pp. 427–438, 2012, https://doi.org/10.1002/adem.201100349.Search in Google Scholar

[14] Z. Liang Tian, S. Bao Jiang, Z. Zong Chen, H. Sheng Bao, and Z. Dong Liu, “Microstructural evolution and mechanical properties of a new Ni-based heat-resistant alloy during aging at 750 °C,” J. Iron Steel Res. Int., vol. 24, pp. 513–519, 2017, https://doi.org/10.1016/S1006-706X(17)30078-X.Search in Google Scholar

[15] H. R. Zhang and O. A. Ojo, “Cr-rich nanosize precipitates in a standard heat-treated Inconel 738 superalloy,” Philos. Mag., vol. 90, pp. 765–782, 2010, https://doi.org/10.1080/14786430903270643.Search in Google Scholar

[16] S. Jiang, Z. Tian, W. Liu et al.., “Microstructural evolution and hardness of a heat resistant alloy during long term aging at 700 °C,” J. Alloys Compd., vol. 765, pp. 1267–1274, 2018, https://doi.org/10.1016/j.jallcom.2018.05.263.Search in Google Scholar

[17] I. A. Sustaita-Torres, S. Haro-Rodríguez, M. P. Guerrero-Mata et al.., “Aging of a cast 35Cr-45Ni heat resistant alloy,” Mater. Chem. Phys., vol. 133, pp. 1018–1023, 2012, https://doi.org/10.1016/j.matchemphys.2012.02.010.Search in Google Scholar

[18] Y. Li, C. Li, L. Yu, Z. Ma, H. Li, and Y. Liu, “Characterization of Γ′ precipitate and γ/Γ′ interface in polycrystalline Ni3Al-based superalloys,” Vacuum, vol. 176, p. 109310, 2020, https://doi.org/10.1016/j.vacuum.2020.109310.Search in Google Scholar

[19] L. Yuan, J. Xiong, Y. Peng, J. Shi, and J. Li, “Microstructure and mechanical properties in the solid-state diffusion bonding joints of Ni3Al based superalloy,” Mater. Sci. Eng., A, vol. 772, p. 138670, 2020, https://doi.org/10.1016/j.msea.2019.138670.Search in Google Scholar

[20] Y. Li, C. Li, Y. Wu et al.., “Microstructural evolution and phase transformation of Ni3Al-based superalloys after thermal exposure,” Vacuum, vol. 171, p. 109038, 2020, https://doi.org/10.1016/j.vacuum.2019.109038.Search in Google Scholar

[21] E. Essuman, L. R. Walker, P. J. Maziasz, and B. A. Pint, “Oxidation behaviour of cast Ni-Cr alloys in steam at 800°C,” Mater. Sci. Technol., vol. 29, pp. 822–827, 2013, https://doi.org/10.1179/1743284712Y.0000000103.Search in Google Scholar

[22] B. Yu, Y. Li, Y. Nie, and H. Mei, “High temperature oxidation behavior of a novel cobalt-nickel-base superalloy,” J. Alloys Compd., vol. 765, pp. 1148–1157, 2018, https://doi.org/10.1016/j.jallcom.2018.06.275.Search in Google Scholar

[23] A. Al-Meshari and J. Little, “High temperature oxidation of centrifugally cast heat-resistant alloys,” Mater. High Temp., vol. 26, pp. 233–239, 2009, https://doi.org/10.3184/096034009X472222.Search in Google Scholar

[24] M. Roy, “Approaches to enhance elevated temperature erosion resistance of Ni-base superalloys,” Mater. High Temp., vol. 36, pp. 142–156, 2019, https://doi.org/10.1080/09603409.2018.1482077.Search in Google Scholar

[25] A. Kisasoz, “Influence of solution treatment on microstructure, corrosion resistance, and oxidation behavior of cast G-NiCr28W alloy,” China Foundry, vol. 16, pp. 63–70, 2019, https://doi.org/10.1007/s41230-019-8161-3.Search in Google Scholar

[26] U. Brill, “Carbide strengthening of wrought nickel-base alloys,” Adv. Eng. Mater., vol. 3, pp. 9162–9218, 2001, https://doi.org/10.1002/1527-2648(200111)3:11<916::AID-ADEM916>3.0.CO;2-8.10.1002/1527-2648(200111)3:11<916::AID-ADEM916>3.0.CO;2-8Search in Google Scholar

[27] S. S. Handa, “Precipitation of carbides in a Ni-Based superalloy,” Master dissertation, Department of Engineering Science, University West, Trollhättan, Sweden, 2014.Search in Google Scholar

[28] X. Dong, X. Zhang, K. Du, Y. Zhou, T. Jin, and H. Ye, “Microstructure of carbides at grain boundaries in nickel based superalloys,” J. Mater. Sci. Technol., vol. 28, pp. 1031–1038, 2012, https://doi.org/10.1016/S1005-0302(12)60169-8.Search in Google Scholar

[29] R. Hu, G. Bai, J. Li, J. Zhang, T. Zhang, and H. Fu, “Precipitation behavior of grain boundary M23C6 and its effect on tensile properties of Ni-Cr-W based superalloy,” Mater. Sci. Eng., A, vol. 548, pp. 83–88, 2012, https://doi.org/10.1016/j.msea.2012.03.092.Search in Google Scholar

[30] M. Erol, A. Kisasoz, P. Yaman, S. S. Karabeyoglu, and U. Barut, “A study on high temperature dry sliding wear of AA7050-T4 and effects of the test temperature on microstructure, corrosion behavior, hardness and electrical conductivity,” Mater. Today Commun., vol. 31, p. 103410, 2022, https://doi.org/10.1016/j.mtcomm.2022.103410.Search in Google Scholar

Published Online: 2023-02-03
Published in Print: 2023-02-23

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Effect of cyclic loading on mechanical properties and microstructure of die cast magnesium alloy AZ91D
  3. Selective laser melting of Ti6Al4V alloy: effects of process parameters at constant energy density on mechanical properties, residual stress, microstructure and relative density
  4. A comparison study on experimental characterization of unidirectional fiber reinforced composites using strain-gauges and virtual extensometers
  5. A modified Johnson–Cook constitutive model for titanium alloy TA31 and its implementation into FE
  6. Anisotropy of epoxy acrylate with magnetic field-induced Ni-MWNTs
  7. A novel generalized normal distribution optimizer with elite oppositional based learning for optimization of mechanical engineering problems
  8. Improvement of metallurgical properties of A356 aluminium alloy by AlCrFeSrTiBSi master alloy
  9. Precipitation of carbides in a nickel-based cast heat-resistant alloy during thermal exposure: evolution of microstructure, hardness and corrosion properties
  10. Mechanical property improvement of a AA6082 alloy by the TV-CAP process as a novel SPD method
  11. Effect of high temperatures on dry sliding friction and wear behaviour of CuCrZr copper alloy
  12. Joint performance of medium carbon steel-austenitic stainless steel double-sided TIG welds
  13. Enhancing the wear performance of Ti-6Al-4V against Al2O3 and WC-6Co via TiBn layer produced by boriding
  14. Cutting parameters optimization of hybrid fiber composite during drilling
  15. Dry sliding wear behavior of energy density dependent PA 12/Cu composites produced by selective laser sintering
Downloaded on 25.10.2025 from https://www.degruyterbrill.com/document/doi/10.1515/mt-2022-0243/html
Scroll to top button