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Investigation of in situ synthesized TiB2 particles in iron-based composite coatings processed by hybrid submerged arc welding

  • Mustafa Kaptanoglu

    Asst. Prof. Mustafa Kaptanoglu (0000-0002-6295-610X), born in 1981, graduated from the Metallurgy and Materials Engineering Department at Cumhuriyet University, Sivas, Turkey in 2006. He obtained his MSc degree in 2011 and completed his Ph.D. degree in 2016 from the Metallurgy and Materials Engineering Department of Firat University, Elazig, Turkey. He is currently an Assistant Professor in the Metallurgy and Materials Engineering Department at Firat University, Elazig, Turkey. His research area includes coating, hardfacing, heat treatment, non-destructive testing, welding technology, etc.

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    and Mehmet Eroglu

    Prof. Dr. Mehmet Eroglu (0000-0002-50971943), born in 1969, works at Firat University, Engineering Faculty, Metallurgy and Materials Engineering Department, Elazig, Turkey. He obtained his Ph.D. degree in the Metallurgy and Materials Engineering Department at Firat University, Elazığ, Turkey in 1998. His area of research includes material science, polymers, heat treatment, non-destructive testing, coating, welding technology, etc.

Published/Copyright: July 29, 2021
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Abstract

In the study for this contribution, production of in situ synthesized TiB2 particles in iron-based composite coatings using four different submerged arc welding powders (fluxes) containing increasing amounts of ferrotitanium and ferroboron with S1 welding wire, were targeted. For this purpose, coating deposition was carried out to improve the hardness and wear properties of the AISI 1020 steel surfaces using hybrid submerged arc welding. In hybrid submerged arc welding, the welding pool is protected by both welding powders and an argon gas atmosphere. To examine the composite coatings, visual, chemical, microstructural analyses and hardness and wear tests were carried out. With the use of increasing amounts of ferrotitanium and ferroboron in the welding powders, it was observed that the microstructure of the coatings changed in terms of TiB2 particle geometries such as rectangular and hexagonal; volume fractions of TiB2 particles in the coating microstructures increased; hardness values of coatings were enhanced from 34 HRC to 41 HRC; the wear resistance of the coatings improved, and worn surface images of the coatings caused by the counter body changed from continuous with deep scratches to discontinuous with fine scratches and crater cavities.


Dr. Mustafa Kaptanoglu Department of Metallurgy and Materials Engineering Faculty Firat University Elazig, Turkey

About the authors

Asst. Prof. Mustafa Kaptanoglu

Asst. Prof. Mustafa Kaptanoglu (0000-0002-6295-610X), born in 1981, graduated from the Metallurgy and Materials Engineering Department at Cumhuriyet University, Sivas, Turkey in 2006. He obtained his MSc degree in 2011 and completed his Ph.D. degree in 2016 from the Metallurgy and Materials Engineering Department of Firat University, Elazig, Turkey. He is currently an Assistant Professor in the Metallurgy and Materials Engineering Department at Firat University, Elazig, Turkey. His research area includes coating, hardfacing, heat treatment, non-destructive testing, welding technology, etc.

Prof. Dr. Mehmet Eroglu

Prof. Dr. Mehmet Eroglu (0000-0002-50971943), born in 1969, works at Firat University, Engineering Faculty, Metallurgy and Materials Engineering Department, Elazig, Turkey. He obtained his Ph.D. degree in the Metallurgy and Materials Engineering Department at Firat University, Elazığ, Turkey in 1998. His area of research includes material science, polymers, heat treatment, non-destructive testing, coating, welding technology, etc.

Acknowledgement

This work was supported by a grant from the Scientific and Technological Research Council of Turkey, TUBITAK (Project No: 114M016). The authors acknowledge the laboratory staff of the Department of Metallurgical and Materials Engineering at Firat University, TR for helping to set up the experimental design.

References

1 P. Zhang, X. Wang, L. Guo, L. Cai, H. Sun: Characterization of in situ synthesized TiB2 reinforcements in iron-based composite coating, Applied Surface Science 258 (2011), pp. 1592-1598 DOI:10.1016/j.apsusc.2011.10.00410.1016/j.apsusc.2011.10.004Search in Google Scholar

2 N. G. Chaidemenopoulos, P. P. Psyllaki, E. Pavlidou, G. Vourlias: Aspects on carbides transformations of Fe-based hardfacing deposits, Surface and Coatings Technology 357 (2019), pp. 651-661 DOI:10.1016/j.surfcoat.2018.10.06110.1016/j.surfcoat.2018.10.061Search in Google Scholar

3 B. Srikarun, P. Muangjunburee: The effect of iron-based hardfacing with chromium powder addition onto low carbon steel, Materials Todays: Proceedings 5 (2018), pp. 9272-9280 DOI:10.1016/j.matpr.2017.10.10010.1016/j.matpr.2017.10.100Search in Google Scholar

4 H. Abed, F. M. Ghaini, H. R. Shahverdi: Characterization of Fe49Cr18Mo7B16C4Nb6 high-entropy hardfacing layers produced by gas tungsten arc welding (GTAW) process, Surface and Coatings Technology 352 (2018), pp. 360-369 DOI:10.1016/j.surfcoat.2018.08.01910.1016/j.surfcoat.2018.08.019Search in Google Scholar

5 I. Kirik, Z. Balalan, A. Imak, M. Yaz: Properties of different TIG coatings of Stellite on the Hardox 450 and St 52 steel, Materials Testing 62 (2020), pp. 1089-1093 DOI:10.3139/120.11159010.3139/120.111590Search in Google Scholar

6 L. Zhou, M. Yu, B. Liu, Z. Zhang, S. Liu, X. Song, H. Zhao: Microstructure and mechanical properties of Al/steel dissimilar welds fabricated by friction surfacing assisted friction stir lap welding, Journal of Materials Research and Technology 9 (2019), pp. 212-221 DOI:10.1016/j.jmrt.2019.10.04610.1016/j.jmrt.2019.10.046Search in Google Scholar

7 J. Akram, R. Puli, K. Prasad Rao, M. Misra: Microstructural studies on friction surfaced coatings of Ni-Based alloys, Materials Testing 52 (2015), pp. 590-605 DOI:10.3139/147.11035510.3139/147.110355Search in Google Scholar

8 G. P. Rajeev, M. Kamaraj, S. R. Bakshi: Comparison of microstructure, dilution and wear behavior of Stellite 21 hardfacing on H13 steel using cold metal transfer and plasma transferred arc welding processes, Surface and Coatings Technology 375 (2019), pp. 383-394 DOI:10.1016/j.surfcoat.2019.07.019.10.1016/j.surfcoat.2019.07.019Search in Google Scholar

9 T. Teker, A. Topal: Properties and chemical composition of plasma arc welded Hardox450+FeW coatings, Materials Testing, 61 (2019), pp. 35-40 DOI:10.3139/120.11127810.3139/120.111278Search in Google Scholar

10 L. Yinghua, W. Kaiming: Microstructure and properties of a laser cladded NiCrBSi alloy coating, Materials Testing 62 (2020), pp. 698-702 DOI:10.3139/120.11153510.3139/120.111535Search in Google Scholar

11 J. Tang: Mechanical and tribological properties of the TiC–TiB2 composite coating deposited on 40Cr-steel by electro spark deposition, Applied Surface Science 365 (2016), pp. 202-208 DOI:10.1016/j.apsusc.2015.12.19810.1016/j.apsusc.2015.12.198Search in Google Scholar

12 E. Contreras, Y. Galindez, M. A. Gómez: Microstructure, mechanical and tribological properties of TiBC coatings by DC magnetron sputtering onto AISI M2 steel using independent TiB2 and graphite targets, Surface and Coatings Technology 350 (2018), pp. 298-306 DOI:10.1016/j.surfcoat.2018.05.07910.1016/j.surfcoat.2018.05.079Search in Google Scholar

13 S. Özel: Microstructure and mechanical properties of HVOF sprayed WC-Co/NiCrBSi, Cr3C2 coatings on al alloys, Materials Testing 55 (2013), pp. 694-700 DOI:10.3139/120.11048910.3139/120.110489Search in Google Scholar

14 M. Kaptanoglu, M. Eroglu: Reusability of metallurgical slag waste in submerged arc welding powder for hardfacing, Materials Testing 62 (2020), pp. 177-183 DOI:10.3139/120.11146810.3139/120.111468Search in Google Scholar

15 K. Yang, Y. Gao, K. Yang, Y. Bao, Y. Jiang: Microstructure and wear resistance of Fe-Cr13-C-Nb hardfacing alloy with Ti addition, Wear 376-377 (2017), pp. 1091-1096 DOI:10.1016/j.wear.2016.12.06210.1016/j.wear.2016.12.062Search in Google Scholar

16 X. Wang, Z. Zou, S. Qu: Microstructure of Fe-Based alloy hardfacing coating reinforced by TiC-VC particles, Journal of Iron and Steel Research International 13 (2006), pp. 51-55 DOI:10.1016/S1006-706X(06)60078-210.1016/S1006-706X(06)60078-2Search in Google Scholar

17 V. A. Perfilov, O. V. Dushko, V. V. Yaroshik: Characteristics of alloying and structure formation of wear-resistant coatings carboborite, Materials Today Proceedings 11 (2019), pp. 77-82 DOI:10.1016/j.matpr.2018.12.11010.1016/j.matpr.2018.12.110Search in Google Scholar

18 M. Nagentrau, A. L. Mohd Tobi, M. Sambu, S. Jamian: The influence of welding condition on the microstructure of WC hardfacing coating on carbon steel substrate, International Journal of Refractory Metals and Hard Materials 82 (2019), pp. 43-57 DOI:10.1016/j.ijrmhm.2019.03.02910.1016/j.ijrmhm.2019.03.029Search in Google Scholar

19 X. Wang, H. Shun, C. Li, X. Wang, D. Sun: The performances of TiB2-contained iron-based coatings at high temperature, Surface and Coatings Technology 201 (2006), pp. 2500-2504 DOI:10.1016/j.surfcoat.2006.04.02510.1016/j.surfcoat.2006.04.025Search in Google Scholar

20 Z. Wang, X. Zhou, G. Zhao: Microstructure and formation mechanism of in-situ TiC-TiB2/Fe composite coating, Transactions of Nonferrous Metals Society of China 18 (2008), pp. 831-835 DOI:10.1016/S1003-6326(08)60144-210.1016/S1003-6326(08)60144-2Search in Google Scholar

21 D. Wu, X. Wang, P. Zhang, L. Cai, H. Sun: Defects in the in situ synthesized TiB2/Fe composite coatings during PTA process, Applied Surface Science 257 (2011), pp. 10119-10125 DOI:10.1016/j.apsusc.2011.06.16010.1016/j.apsusc.2011.06.160Search in Google Scholar

22 United States Patent: System And Method For Submerged Arc Welding, Patent No. US009821402B2, USA (2017)Search in Google Scholar

23 https://www.magmaweld.com/welding-consumables/subarc-wires-fluxes/o/4020.11.2020Search in Google Scholar

24 J. R. Davis (Ed.): ASM Handbook: Welding, Brazing and Soldering 6, ASM International, Materials Park, Ohio, USA (1993)Search in Google Scholar

25 R. Oates, M. A. Saitta (Eds.): Welding Handbook 4 Materials and Applications, American Welding Society, Miami, Florida, USA (2000)Search in Google Scholar

26 V. V. Golovko, N. Potapov: Special features of agglomerated (ceramic) fluxes in welding, Welding International 25 (2011), pp. 889-893 DOI:10.1080/09507116.2011.58143110.1080/09507116.2011.581431Search in Google Scholar

27 R. Mugele, H. D. Evans: Droplet size distribution in sprays, Journal of Industrial and Engineering Chemistry 43 (1951), pp. 1317-1324 DOI:10.1021/ie50498a02310.1021/ie50498a023Search in Google Scholar

28 J. P. Snyder, A. W. Pense: The effects of titanium on submerged arc weld metal, Welding Journal Research Supplement (1982), pp. 201-211Search in Google Scholar

29 D. C. Hill, C. L. Choi: A study of the submerged arc welding of titanium, Welding Research Supplement, (1976), pp. 152-158Search in Google Scholar

30 A. Chamanfar, M. Huang, T. Pasang, M. Tsukamoto, W. Z. Misiolek: Microstructure and mechanical properties of laser welded Ti–10V–2Fe–3Al (Ti1023) titanium alloy, Journal of Materials Research and Technology 9 (2020), pp. 7721-7731 DOI:10.1016/j.jmrt.2020.04.02810.1016/j.jmrt.2020.04.028Search in Google Scholar

31 V. Dhinakaran, S. V. Shriragav, A. F. Y. Fahmidha, M. Ravichandran: A review on the categorization of the welding process of pure titanium and its characterization, Materials Today Proceedings 27 (2020), pp. 742-747 DOI:10.1016/j.matpr.2019.12.03410.1016/j.matpr.2019.12.034Search in Google Scholar

32 R. Bendikiene, S. Baskutis, J. Baskutiene, A. Ciuplys, T. Kacinskas: Comparative study of TIG welded commercially pure titanium, Journal of Manufacturing Processes 36 (2018), pp. 155-163 DOI:10.1016/j.jmapro.2018.10.00710.1016/j.jmapro.2018.10.007Search in Google Scholar

33 Z. Sun, I. Annergren, D. Pan, T. A. Mai: Effect of laser surface remelting on the corrosion behavior of commercially pure titanium sheet, Materials Science and Engineering A 345 (2003), pp. 293-300 DOI:10.1016/S0921-5093(02)00477-X10.1016/S0921-5093(02)00477-XSearch in Google Scholar

34 ASTM G132-96: Standard test method for pin abrasion testing, ASTM International, West Conshohocken, Pennsylvania, USA (2018)Search in Google Scholar

35 M. Z. Sylwester, L. Gai, S. Miura: Effect of (Ti: B) atomic ratio on mechanical properties of TiB2–Fe composites ‘‘in situ’’ fabricated via Self-propagating High-temperature synthesis, Materials and Design 69 (2015), pp. 1-11 DOI:10.1016/j.matdes.2014.12.03610.1016/j.matdes.2014.12.036Search in Google Scholar

36 W. Xibao, L. Yong, Y. Songlan: Formation of TiB2 whiskers in laser clad Fe-Ti-B coatings, Surface and Coatings Technology 137 (2001), pp. 209-216 DOI:10.1016/S0257-8972(00)01113-010.1016/S0257-8972(00)01113-0Search in Google Scholar

37 H. Lin, L. Ying, L. Jun, L. Binghong: Microstructure and mechanical properties for TIG welding joint of high boron Fe-Ti-B Alloy, Rare Metal Materials and Engineering 43 (2014), pp. 283-286 DOI:10.1016/S1875-5372(14)60059-X10.1016/S1875-5372(14)60059-XSearch in Google Scholar

38 W. Xibao, W. Xiaofeng, S. Zhongquan: The composite Fe–Ti–B–C Coatings by PTA powder surfacing process, Surface and Coatings Technology 192 (2005), pp. 257-262 DOI:10.1016/j.surfcoat.2004.08.21010.1016/j.surfcoat.2004.08.210Search in Google Scholar

39 H. Y. Wang, Q. C. Jiang, B. X. Ma, Y. Wang, F. Zhao: Reactive infiltration synthesis of TiB2-TiC particles reinforced steel matrix composites, Journal of Alloys Compounds 391 (2005), pp. 55-59 DOI:10.1016/j.jallcom.2004.08.04510.1016/j.jallcom.2004.08.045Search in Google Scholar

40 A. Farid, S. Guo, F. Cui, P. Feng, T. Lin: TiB2 and TiC stainless steel matrix composites, Materials Letters 61 (2007), pp. 189-190 DOI:10.1016/j.matlet.2006.04.02810.1016/j.matlet.2006.04.028Search in Google Scholar

41 A. Anal, T. K. Bandyopadhyay, K. Das: Synthesis and characterization of TiB2-reinforced iron-based composites, Journal of Materials Processing Technology 172 (2006), pp. 70-76 DOI:10.1016/j.jmatprotec.2005.09.01110.1016/j.jmatprotec.2005.09.011Search in Google Scholar

42 Y. Wang, H. Y. Zhang, B. X. Wang, Q. C. Ma: Effect of Fe content in Fe-Ti-B system on fabricating TiB2 particulate locally reinforced steel matrix composites, Materials Science and Engineering A 422 (2006), pp. 339-345 DOI:10.1016/j.msea.2006.02.01210.1016/j.msea.2006.02.012Search in Google Scholar

43 M. Darabara, G. D.Papadimitriou, L.Bourithis: Production of Fe-B-TiB2 Metal Matrix Composites on Steel Surface, Surface and Coatings Technology 201 (2006), pp. 3518-3523 DOI:10.1016/j.surfcoat.2006.08.10510.1016/j.surfcoat.2006.08.105Search in Google Scholar

44 J. C. Lippold, D. J. Kotecki: Welding Metallurgy and Weldability of Stainless Steel, Wiley, Hoboken, New Jersey, USA (2005)Search in Google Scholar

45 A. Emamian, F. Stephen, K. Corbin, K. Amir: In-Situ deposition of metal matrix composite in Fe-Ti-C system using laser cladding process, J. Cuppoletti (Ed.): Metal, Ceramic and Polymeric Composites for Various Uses, IntechOpen (2011) DOI:10.5772/1059310.5772/10593Search in Google Scholar

46 X. Wang, H. Leng, B. Han, X. Wang, B. Hu, H. Luo: Solidified microstructures and elastic modulus of hypo-eutectic and hyper-eutectic TiB2-reinforced high-modulus steel, Acta Materialia 176 (2019), pp. 84-95 DOI:10.1016/j.actamat.2019.06.05210.1016/j.actamat.2019.06.052Search in Google Scholar

47 Z. C. Luo, B. B. He, Y. Z. Li, M. X. Huang: Growth mechanism of primary and eutectic TiB2, particles in a hypereutectic steel matrix composite, Metallurgical and Materials Transactions A 48 (2017), pp. 1981-1989 DOI:10.1007/s11661-017-4001-510.1007/s11661-017-4001-5Search in Google Scholar

48 M. Kaptanoglu, M. Eroglu: Microstructure and wear of iron-based hardfacings reinforced with in-situ synthesized TiB2 particles, Kovove Materialy Metallic Materials, 55 (2017), pp. 123-131 DOI:10.4149/km 2017 2 12310.4149/km20172123Search in Google Scholar

49 A. Farid: Microstructure evolution and wear properties of in situ synthesized TiB2 and TiC reinforced steel matrix composites, Journal of Alloys and Compounds 459 (2008), pp. 491-497 DOI:10.1016/j.jallcom.2007.05.01810.1016/j.jallcom.2007.05.018Search in Google Scholar

50 M. F. Buchley, J. C. Gutierrez, L. M. Leon, A. Toro: The effect of microstructure on abrasive wear of hardfacing alloys, Wear 259 (2005), pp. 52-61 DOI:10.1016/j.wear.2005.03.00210.1016/j.wear.2005.03.002Search in Google Scholar

51 S. C. Tjong, K. C. Lau: Abrasion resistance of stainless-steel composites reinforced with Hard TiB2 Particle, Composites Science and Technology 60 (2000), pp. 1141-1146 DOI:10.1016/S0266-3538(00)00008-710.1016/S0266-3538(00)00008-7Search in Google Scholar

52 M. M. Khruschov: Principles of abrasive wear, Wear 28 (1974), pp. 69-88 DOI:10.1016/0043-1648(74)90102-110.1016/0043-1648(74)90102-1Search in Google Scholar

Published Online: 2021-07-29
Published in Print: 2021-07-30

© 2021 Walter de Gruyter GmbH, Berlin/Boston, Germany

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