Kinetics and Mechanisms of the Reaction of Aluminium(III) with Polyaminocarboxylic Acids
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Claire Τ. Tomany
Abstract
The kinetics and mechanisms of the reactions of aluminium(III) with ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) have been investigated in aqueous solution at 25°C and ionic strength 0.5 mol dm-3 NaClO4. Al3+ reacts with the H4DTPA- and H3DTPA2- with rate constants of 2.06(±0.35) and 19.3(±1.6) respectively while Al(OH)2+ reacts with H3DTPA2- with a rate constant of 1.34(±0.20) × 103 dm3 mol-1 s-1. The outersphere association constant for reaction of Al3+ with H3DTPA2- was found to be 175(±38) mol-1 dm3. Al3+ reacts with H3EDTA and H2EDTA2- with rate constants of 4.73(±1.25) and 21.5(±2.21) dm3 mol-1 s-1 respectively. The outer-sphere association constant for reaction of Al3+ with H2EDTA2- is 164(±52.9) mol-1 dm3.
© 2014 by Walter de Gruyter Berlin/Boston
Artikel in diesem Heft
- Tribute
- Kinetics of Dissociation of the Cobalt(II) and Copper(II) Complexes of 2,2′,2″-tris(monomethylamino)triethylamine in Aqueous Acidic Solution
- The Influence of Steric Effects on the Oxidation Kinetics of [FeII(aminopolycarboxylato)] Complexes with Dioxygen
- The Hydrolysis Kinetics of ds-diamminedichloroplatinum(II). 10. Activation Volumes for Halide Anation of Some czs-[Pt(N)2(OH2)2]2+ Systems
- The Dependence of the Copper Dissociation Rate Constants from Human(Serum)- and Ονο-Transferrin on pH and the Anions
- Kinetics of the Photosubstitution of ds-Bis(benzonitrile)dichloroplatinum(II) in Chloroform
- Kinetics and Mechanisms of the Reaction of Aluminium(III) with Polyaminocarboxylic Acids
- Kinetics and Mechanism of Oxidation of Tellurium(IV) by Alkaline Diperiodatonickelate(IV)
- Complexation of Pendant Arm Macrocycles with Cu(II) Hydroxo Complexes in Strongly Alkaline Solutions. Investigation of pH Dependences
- Kinetics and Mechanism of the Chromium(VI) Oxidation of Formic Acid in the Presence of Picolinic Acid and in the Presence and Absence of Surfactants
- Kinetics and Mechanism of Chromium(III) Catalysed Oxidation of Propan-1-ol and Butan-1-ol by Cerium(IV) in Aqueous Sulfuric acid Media
- Notes for Contributors. Inorganic Reaction Mechanisms
- Journal Order Form
Artikel in diesem Heft
- Tribute
- Kinetics of Dissociation of the Cobalt(II) and Copper(II) Complexes of 2,2′,2″-tris(monomethylamino)triethylamine in Aqueous Acidic Solution
- The Influence of Steric Effects on the Oxidation Kinetics of [FeII(aminopolycarboxylato)] Complexes with Dioxygen
- The Hydrolysis Kinetics of ds-diamminedichloroplatinum(II). 10. Activation Volumes for Halide Anation of Some czs-[Pt(N)2(OH2)2]2+ Systems
- The Dependence of the Copper Dissociation Rate Constants from Human(Serum)- and Ονο-Transferrin on pH and the Anions
- Kinetics of the Photosubstitution of ds-Bis(benzonitrile)dichloroplatinum(II) in Chloroform
- Kinetics and Mechanisms of the Reaction of Aluminium(III) with Polyaminocarboxylic Acids
- Kinetics and Mechanism of Oxidation of Tellurium(IV) by Alkaline Diperiodatonickelate(IV)
- Complexation of Pendant Arm Macrocycles with Cu(II) Hydroxo Complexes in Strongly Alkaline Solutions. Investigation of pH Dependences
- Kinetics and Mechanism of the Chromium(VI) Oxidation of Formic Acid in the Presence of Picolinic Acid and in the Presence and Absence of Surfactants
- Kinetics and Mechanism of Chromium(III) Catalysed Oxidation of Propan-1-ol and Butan-1-ol by Cerium(IV) in Aqueous Sulfuric acid Media
- Notes for Contributors. Inorganic Reaction Mechanisms
- Journal Order Form
