Abstract
The crystallization of organic-based materials occurs under conditions far from equilibrium, leading to patterns that grow as propagating waves into the surrounding unstable fluid medium. This problem was reformulated considering the concept of thermal forces of preexisting 2D patterns. A new finite difference numerical scheme was tested. Dendritic islands were distributed in the liquid-viscous fluid. It induced a heterogeneous thermal distribution nearby the dendritic islands. The evolution of the isoline of the temperature versus time reveals fractal patterns within the inter-dendritic liquid. The physical origin of the fluctuations is guided by the proximity of the dendrites, i.e. lack of space. Moreover, the gradient of temperature is depicted by isocline pictures. Fractal patterns may be considered advantageous and be taken as a key point to the next step, i.e. the crystal growth in an environment subjected to rapid variations of temperature.
Acknowledgments
The authors are pleased to acknowledge CNRS and mines paris PSL.
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Research ethics: Not applicable.
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Informed consent: Informed consent was obtained from all individuals included in this study, or their legal guardians or wards.
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Author contributions: Séverine A.E. Boyer: Conceptualization, Formal analysis, Methodology, Calculation, Visualization, Resources, Writing – original draft, Writing – Review & Editing. Alain Burr: Conceptualization, Formal analysis, Methodology, Calculation, Visualization, Resources, Writing – Original draft, Writing – Review & Editing.
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Use of Large Language Models, AI and Machine Learning Tools: LLM-AI-MLT not used.
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Conflict of interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: Not applicable.
References
Ahmed, A., Hasan, M.M., and Mahmood, Z.A. (2016). Inhibition of calcium oxalate crystals growth by Macrotyloma uniflorum (lam.) Verdc, Phaseolus lunatus Linn, and Phaseolus vulgaris linn: an in vitro study. J. Pharmacognosy. Phytochem. 5: 124–130.10.7897/2277-4572.0516Suche in Google Scholar
Aziz, M. and Kaplan, T. (1988). Continuous growth model for interface motion during alloy solidification. Acta Metall. 36: 2335–2347, https://doi.org/10.1016/0001-6160(88)90333-1.Suche in Google Scholar
Beers, K.L., Douglas, J.F., Amis, E.J., and Karim, A. (2003). Combinatorial measurements of crystallization growth rate and morphology in thin films of isotactic polystyrene. Langmiur 19: 3935–3940, https://doi.org/10.1021/la026751r.Suche in Google Scholar
Bergman, T.L., Lavine, A.S., and Incropera, F.P. (2011). Fundamentals of Heat and mass transfer, 7th ed. John Wiley & Sons, Incorporated. ISBN 9781118137253.Suche in Google Scholar
Buchmann, M. and Rettenmayr, M. (2007). Rapid solidification theory revisited – a consistent model based on a sharp interface. Scr. Mater. 57: 169–172, https://doi.org/10.1016/j.scriptamat.2007.02.039.Suche in Google Scholar
Buchmann, M. and Rettenmayr, M. (2008a). Non-equilibrium transients during solidification - a numerical study. Scr. Mater. 58: 106–109, https://doi.org/10.1016/j.scriptamat.2007.09.022.Suche in Google Scholar
Buchmann, M. and Rettenmayr, M. (2008b). Numerical study of steady state melting of a binary alloy. J. Cryst. Growth 310: 4623–4627, https://doi.org/10.1016/j.jcrysgro.2008.07.096.Suche in Google Scholar
Cengel, Y.A. and Ghajar, A.J. (2011). Heat and Mass Transfer: Fundamentals & Applications. McGraw-Hill Education, New York.Suche in Google Scholar
Galenko, P. and Danilov, D. (1999). Model for free dendritic alloy growth under interfacial and bulk phase nonequilibrium conditions. J. Crystal Growth 197: 992–1002, https://doi.org/10.1016/S0022-0248(98)00977-4.Suche in Google Scholar
Hillert, M. (1999). Solute drag, solute trapping and diffusional dissipation of Gibbs energy. Acta Mater. 47: 4481–4505, https://doi.org/10.1016/S1359-6454(99)00336-5.Suche in Google Scholar
Hillert, M. and Rettenmayr, M. (2003). Deviation from local equilibrium at migrating phase interfaces. Acta Mater. 51: 2803–2809, https://doi.org/10.1016/S1359-6454(03)00085-5.Suche in Google Scholar
Jackson, K.A., Beatty, K.M., and Gudgel, K.A. (2004). An analytical model for non-equilibrium segregation during crystallization. J. Crystal Growth 271: 481–494, https://doi.org/10.1016/j.jcrysgro.2004.07.073.Suche in Google Scholar
Le Goff, R., Poutot, G., Delaunay, D., Fulchiron, R., and Koscher, E. (2005). Study and modeling of heat transfer during the solidification of semi-crystalline polymers. Int. J. Heat Mass Transfer 48: 5417–5430, https://doi.org/10.1016/j.ijheatmasstransfer.2005.06.015.Suche in Google Scholar
Loffler, A., Hack, K., and Rettenmayr, M. (2010). Predicting microsegregation in multi-component aluminum alloys – progress in thermodynamic consistency. IJMR 101: 1398–1404, https://doi.org/10.3139/146.110423.Suche in Google Scholar
Okerberg, B.C., Marand, H., and Douglas, J.F. (2008). Dendritic crystallization in thin films of PEO/PMMA blends: a comparison to crystallization in small molecule liquids. Polymer 49: 579–587, https://doi.org/10.1016/j.polymer.2007.11.034.Suche in Google Scholar
Rettenmayr, M. and Buchmann, M. (2008). Modeling rapid liquid/solid and solid/liquid phase transformations inalalloys. IJMR 99: 613–617, https://doi.org/10.3139/146.101679.Suche in Google Scholar
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Artikel in diesem Heft
- Frontmatter
- Review Article
- Epoxy vitrimers: from essence to utility
- Research Articles
- Tamarind seed powder as filler in polypropylene and its impact on the mechanical and biodegradability of the composites
- Development and characterization of glass fiber composites impregnated with limestone powder and bagasse fiber
- Hyaluronic acid/κ-carrageenan films for mupirocin-controlled delivery
- Temperature field study and numerical computation of carbon fiber epoxy composite materials under unilateral thermal radiation
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- Influence of different surface textures on wettability of UHMWPE and POM- an experimental study
- Use of machine learning methods for modelling mechanical parameters of PLA and PLA/native potato starch compound using aging data
- Influence of the viscosity of polymer melts on the coextrusion process based on wall slip conditions