An experimental validation of diffusion-based devolatilization models in extruders using post-industrial and post-consumer plastic waste
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Chi Nghia Chung
, Christian Marschik
, Mohamad Hassan Akhras
Abstract
Extrusion is a key process in mechanical recycling. In a degassing step, volatile components, including all impurities and moisture, are removed from a polymer melt to ensure consistently high quality of the recyclates. Predicting devolatilization performance is therefore of interest in the design of degassing screws; in the plastics industry, it also plays an important role in the transition from a linear to a circular economy. Using two different devolatilization models, we first modelled the degassing process of a lab-scale twin-screw extruder and an industrial-scale recycling single-screw extruder. We then predicted the devolatilization performance of both machines, validated the results with experimental data obtained from emissions tests carried out with post-industrial and post-consumer polypropylene materials and performed linear regression analysis to compare our two models in terms of predictive quality. Our results showed that both models are equally suitable for reliable prediction of the devolatilization performance.
Acknowledgements
The authors acknowledge financial support from the COMET Centre CHASE, funded within the COMET − Competence Centers for Excellent Technologies program by the BMK, the BMDW and the Federal Provinces of Upper Austria and Vienna. The COMET program is managed by the Austrian Research Promotion Agency (FFG).
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Research ethics: Not applicable.
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Informed consent: Informed consent was obtained from all individuals included in this study, or their legal guardians or wards.
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Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflict of interest.
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Research funding: The authors acknowledge financial support from the COMET Centre CHASE, funded within the COMET − Competence Centers for Excellent Technologies program by the BMK, the BMDW and the Federal Provinces of Upper Austria and Vienna. The COMET program is managed by the Austrian Research Promotion Agency (FFG).
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Data availability: The raw data can be obtained on request from the corresponding author.
References
Akhras, M.H. and Fischer, J. (2022). Sampling scheme conception for pretreated polyolefin waste based on a review of the available standard procedures. Polymers 14: 3450, https://doi.org/10.3390/polym14173450.Search in Google Scholar PubMed PubMed Central
Albalak, R.J. (1996). An introduction to devolatilization. In: Albalak, R.J. (Ed.). Polymer devolatilization. Marcel Decker, New York.Search in Google Scholar
Biesenberger, J.A. (1980). Polymer devolatilization: theory of equipment. Polym. Eng. Sci. 20: 1015–1022, https://doi.org/10.1002/pen.760201506.Search in Google Scholar
Biesenberger, J.A. (1987). Polymer melt devolatilization: on equipment design equations. Adv. Polym. Tech. 7: 267–278, https://doi.org/10.1002/adv.1987.060070304.Search in Google Scholar
Biesenberger, J.A. (1993). Entgasung von Kunststoffen in Scherströmungsfeldern. VDI-Verlag. Duesseldorf.Search in Google Scholar
Biesenberger, J.A. and Kessidis, G. (1982). Devolatilization of polymer melts in single-screw extruders. Polym. Eng. Sci. 22: 832–835, https://doi.org/10.1002/pen.760221308.Search in Google Scholar
Biesenberger, J.A. and Sebastian, D.H. (1983). Principles of polymerization engineering. John Wiley and Sons Inc., New York.Search in Google Scholar
Chen, L. and Lindt, J.T. (1996). „3-D flow effects on residence time distribution in screw extruders. AIChE J. 43: 1525–1535, https://doi.org/10.1002/aic.690420604.Search in Google Scholar
Chung, C.N., Marschik, C., Klimoschek, J., Kosek, J., Akhras, M.H., and Steinbichler, G. (2023). An experimental approach to determining the average diffusion coefficient of volatile components in polymer waste materials. Recycling 8: 72, https://doi.org/10.3390/recycling8050072.Search in Google Scholar
Collins, G.P., Denson, C.D., and Astarita, G. (1983). The length of a transfer unit (LTU) for polymer devolatilization processes in screw extruders. Polym. Eng. Sci. 23: 323–327, https://doi.org/10.1002/pen.760230606.Search in Google Scholar
Coughlin, R.W. and Canevari, G.P. (1969). Drying polymers during screw extursion. AIChE J. 15: 560–564, https://doi.org/10.1002/aic.690150416.Search in Google Scholar
Crank, J. (1975). The mathematics of diffusion, 2nd ed. Clarendon Press, Oxford.Search in Google Scholar
EREMA (2023). INTAREMA TVEplus: recycling system with high-performance degassing. Available online: https://www.erema.com/en/intarema_tveplus/ (Accessed 6 September 2023).Search in Google Scholar
European Parliament (2018). Directive 2008/98/EC on waste and repealing certain directives. European Union.Search in Google Scholar
European Parliament (2022). Directive 94/62/EC on packaging and packaging waste (PPWD). European Union.Search in Google Scholar
Gestring, I. (2002). Entgasen von Polymeren, PhD thesis. University of Hannover, Hannover.Search in Google Scholar
Latinen, G.A. (1962). Devolatilization of viscous polymer systems. ACS Adv. Chem. 34: 235–246, https://doi.org/10.1021/ba-1962-0034.ch019.Search in Google Scholar
Maris, J., Bourdon, S., Brossard, J.M., Cauret, L., Fontaine, L., and Montembault, V. (2018). Mechanical recycling: compatibilization of mixed thermoplastic wastes. Polym. Degrad. Stab. 147: 245–266, https://doi.org/10.1016/j.polymdegradstab.2017.11.001.Search in Google Scholar
Marschik, C., Loew-Baselli, B., and Miethlinger, J. (2017a). Modeling devolatilization in single- and multi-screw extruders. AIP Conf. Proc. 1914: 080006, https://doi.org/10.1063/1.5016746.Search in Google Scholar
Marschik, C., Loew-Baselli, B., and Miethlinger, J. (2017b). Analyzing the influence of surface renewal on diffusive mass transport in vented single-screw extruders. Int. Polym. Process. 32: 387–396, https://doi.org/10.3139/217.3373.Search in Google Scholar
Marschik, C., Roland, W., and Osswald, T.A. (2022). Melt conveying in single-screw extruders: modeling and simulation. Polymers 14: 875–906, https://doi.org/10.3390/polym14050875.Search in Google Scholar PubMed PubMed Central
Plastics Europe. (2022). Plastics – the facts 2022. Plastics Europe AISBL, Brussels.Search in Google Scholar
Potente, H. (1989). Rechnergestützte extruderauslegung. Technology der Kunststoffe, Paderborn.Search in Google Scholar
Rauwendaal, C. (2014). Polymer extrusion, 5th ed. Hanser Publishers, Munich.10.3139/9781569905395.fmSearch in Google Scholar
Roberts, G.W. (1970). A surface renewal model for the drying of polymers during screw extrusion. AIChE J. 16: 878–882, https://doi.org/10.1002/aic.690160530.Search in Google Scholar
Squires, P.H. (1958). Screw-extruder pumping efficiency. SPE J. 14: 24–30.Search in Google Scholar
VDI 2100 (2019). Ambient air – Gas chromatographic determination of gaseous organic compounds. Verein Deutscher Ingenieure.Search in Google Scholar
Wang, N.H. (2000). Theoretical analysis of the devolatilization performance of an intermeshing co-rotating twin-screw extruder with a type of square-channel flighted element. Polym. Eng. Sci. 40: 1833–1842, https://doi.org/10.1002/pen.11315.Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- Review Articles
- Probing the microstructural properties of metal-reinforced polymer composites
- Advancements in chemical modifications using NaOH to explore the chemical, mechanical and thermal properties of natural fiber polymer composites (NFPC)
- Research Articles
- The effect of clay reinforcement of pine pollen grains on the mechanical, anti-corrosion and anti-microbial properties of an epoxy coating
- Influence of stacking sequence and nano-silica fortification on the physical properties of veli karuvelam – peepal hybrid natural composites
- An experimental validation of diffusion-based devolatilization models in extruders using post-industrial and post-consumer plastic waste
- Impact of filler type and proportion on the performance of rubberized coconut fiber-polystyrene composites
- Evaluation of the processing conditions on the production of expanded or plasticized wood plastic composite with cashew nutshell powder
- Irradiation of PMMA intraocular lenses by a 365 nm UV lamp
- Design and simulation analysis of an extrusion structure based on screw extrusion 3D printing
Articles in the same Issue
- Frontmatter
- Review Articles
- Probing the microstructural properties of metal-reinforced polymer composites
- Advancements in chemical modifications using NaOH to explore the chemical, mechanical and thermal properties of natural fiber polymer composites (NFPC)
- Research Articles
- The effect of clay reinforcement of pine pollen grains on the mechanical, anti-corrosion and anti-microbial properties of an epoxy coating
- Influence of stacking sequence and nano-silica fortification on the physical properties of veli karuvelam – peepal hybrid natural composites
- An experimental validation of diffusion-based devolatilization models in extruders using post-industrial and post-consumer plastic waste
- Impact of filler type and proportion on the performance of rubberized coconut fiber-polystyrene composites
- Evaluation of the processing conditions on the production of expanded or plasticized wood plastic composite with cashew nutshell powder
- Irradiation of PMMA intraocular lenses by a 365 nm UV lamp
- Design and simulation analysis of an extrusion structure based on screw extrusion 3D printing