Startseite Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties
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Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties

  • Zoulikha Khiati und Lahouari Mrah EMAIL logo
Veröffentlicht/Copyright: 11. Juli 2023
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International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 38 Heft 5

Abstract

An in-depth study of polyvinylidene fluoride (PVDF) based nanocomposite systems will be the focus of this research. This polymer being hydrophobic and apolar, it will be unlikely to generate strong interactions with clay leaves called organophilic maghnite. The challenge of this study will therefore be to manage the load/polymer interfaces by using montmorillonite with specific surface treatments by adding a surfactant Cetyltrimethylammonium bromide. Therefore, a significant improvement in mechanical and thermal properties was observed. The properties of PVDFNC nanocomposites were evaluated using various physico-chemical techniques (XRD, FTIR, TGA, DSC, TEM, SEM). The results of the structural and thermal measurements carried out on these products reveal that the structural concept of the surfactant influences both the morphological profile, the thermal and mechanical properties of the nanocomposites obtained. Accelerated crystallization is observed in PVDNC nanocomposites as an effective nucleation agent, the crystals formed are predominantly β shaped and have a small number of polar α crystals. Measurements by X-ray diffraction, as well as transmission and scanning electron microscopy indicated that modified maghnite was perfectly distributed 3 % by weight in the polyvinylidene fluoride matrix. The mechanical properties of the nanocomposites were evaluated according to the filler material used and the polyvinylidene fluoride matrix.

Keywords: dynamic mechanical thermal analysis; index of fluidity; mechanical properties; polyvinylidene fluoride
Corresponding author: Lahouari Mrah, Ecole Supérieure en Génie Electrique et Energétique d’Oran, chemin vicinal n°9, Oran, Algérie; and Laboratory of Polymer Chemistry, Department of Chemistry, Faculty of Exact and Applied Sciences, University Oran 1 Ahmed Ben Bella, BP 1524 El’Menouer, 31000 Oran, Algérie, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors gratefully acknowledge the financial support of Ecole Supérieure en Génie Electrique et Energétique d’Oran, BP64, ACHABA HANIFI, USTO, Oran, Algeria. The Natural Sciences Fund for Colleges and the Ecole Supérieure en Génie Electrique et Energétique d’Oran (grant), and the Polymer Chemistry Laboratory, Department of Chemistry, Faculty of Exact and Applied Sciences, University Oran1. The site Culture and Innovation Project of the graduate students of Polymer Chemistry Laboratory, Department of Chemistry, Faculty of Exact and Applied Sciences, University Oran1 is also recognized.

  3. Ethical responsibilities of authors:

    • 1-The manuscript is not submitted to more than one journal for simultaneous review.

    • 2-The manuscript is not the subject of a previous publication (in part or in full), transparency is required on the re-use of the material in order to avoid any suspicion of text recycling (“self-plagiarism”).

    • 3-A single study does not have multiple parts in order to increase the number of submissions and is not submitted to multiple journals.

    • 4-No data has been fabricated or manipulated (including images).

    • 5-Consent to the submission is formally given by all co-authors, as well as by the responsible authorities both tacitly and explicitly of the institute where the work was carried out, before the work is submitted.

    • 6-The authors named in the submission have sufficiently contributed to the scientific work and therefore share the collective responsibility and accountability for the results.

    • 7-The group of authors ensures that the corresponding author and the order of authors are correct at the time of submission.

  4. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-10-26
Accepted: 2023-06-28
Published Online: 2023-07-11
Published in Print: 2023-11-27

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Research Articles
  3. Mechanical strength enhancement of natural fibre composites via localized hybridization with stitch reinforcement
  4. A comparative study on the mechanical properties of African teff and snake grass fiber-reinforced hybrid composites: effect of bio castor seed shell/glass/SiC fillers
  5. Mechanical characterization of randomly oriented short Sansevieria Trifasciata natural fibre composites
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  7. Chicken feather protein for the thermal stability and combustion performance of rigid polyurethane foam
  8. Free vibration behaviour and some mechanical properties of micro particle reinforced epoxy composites
  9. Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties
https://doi.org/10.1515/ipp-2022-4302
Schlagwörter für diesen Artikel
dynamic mechanical thermal analysis; index of fluidity; mechanical properties; polyvinylidene fluoride

Artikel in diesem Heft

  1. Frontmatter
  2. Research Articles
  3. Mechanical strength enhancement of natural fibre composites via localized hybridization with stitch reinforcement
  4. A comparative study on the mechanical properties of African teff and snake grass fiber-reinforced hybrid composites: effect of bio castor seed shell/glass/SiC fillers
  5. Mechanical characterization of randomly oriented short Sansevieria Trifasciata natural fibre composites
  6. Mechanical and tribological properties of snake grass fibers reinforced epoxy composites: effect of Java plum seed filler weight fraction
  7. Chicken feather protein for the thermal stability and combustion performance of rigid polyurethane foam
  8. Free vibration behaviour and some mechanical properties of micro particle reinforced epoxy composites
  9. Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties
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