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Enhanced supercapacitive performance of electrophoretically deposited nanostructured molybdenum-doped Mn3O4 thin films

  • Tanaji S. Patil , Raviraj S. Kamble , Rahul B. Patil , Mansing V. Takale and Satish A. Gangawane EMAIL logo
Published/Copyright: December 14, 2023
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 115 Issue 1

Abstract

Nanostructured molybdenum (Mo)-doped Mn3O4 thin films were successfully deposited on stainless steel substrates by a facile electrophoretic deposition technique. The effect of Mo doping on the structural and supercapacitive properties of Mn3O4 thin films was investigated. The nanostructured morphology of spinel tetragonal Hausmannite Mn3O4 thin films was elucidated with the help of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman studies. The presence of mesopores in the nanostructure with an average pore size of 41 nm was confirmed by Brunauer–Emmett–Teller studies. The different valence states of Mn and Mo are confirmed by X-ray photoelectron spectroscopy. The symmetrical quasi-rectangular-shaped cyclic voltammetry curves without any redox peak and nearly triangular/symmetric galvanostatic charge–discharge curves for Mn3O4 thin films elucidated the pseudocapacitive behavior. Electrochemical impedance spectroscopy revealed that pure and Mo-doped Mn3O4 thin films have lower resistances. Improved supercapacitive performance of 2 % Mo-doped Mn3O4 thin film was confirmed by higher specific capacitance 497 F g−1 at a current density of 1.6 A g−1. The boosted supercapacitive performance of Mo-doped Mn3O4 thin films has identified the outstanding incorporation of Mo ions into the Mn3O4 lattice.

Keywords: Mo-Doped Mn3O4 Thin Films; Electrophoretic deposition; Pseudocapacitance
Corresponding author: Satish A. Gangawane, Department of Physics, Doodhsakhar Mahavidyalaya Bidri, Shivaji University Kolhapur, Tal- Kagal, Dist- Kolhapur, Maharashtra, India, E-mail:

Acknowledgment

The authors are thankful to the co-ordinators of Sophisticated Analytical Instrument Facilities (SAIF) center- Shivaji University Kolhapur, DST-FIST research lab-Devchand College Arjunnagar, Nipani, CFC-Y.C. Institute of Science, Satara, DST-FIST Analytical Instrumentation Laboratory-Jaysingpur College, Jaysingpur, and Department of Physics, Shivaji University, Kolhapur for providing the experimental facilities to carry out this research work in a successful manner.

  1. Research ethics: Not applicable.

  2. Author contributions: Tanaji S. Patil: Conceptualization, Writing – Original draft preparation, Methodology. Raviraj S. Kamble: Methodology, Reviewing and editing. Rahul B. Patil: Formal analysis. Mansing V. Takale: Supervision. Satish A. Gangawane: Supervision, Reviewing, and editing.

  3. Competing interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

  4. Research funding: None declared.

  5. Data availability: The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Received: 2022-10-05
Accepted: 2023-03-06
Published Online: 2023-12-14
Published in Print: 2024-01-29

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/ijmr-2022-0414
Keywords for this article
Mo-Doped Mn3O4 Thin Films; Electrophoretic deposition; Pseudocapacitance

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. Accessing forbidden phases
  4. Original Papers
  5. Effect of oleic acid on morphologies of BaTi5O11 nanocrystals synthesized by hydrothermal method
  6. Fast and facile pH tailored green synthesized ZnO photocatalyst by biogenic reduction using water extract of Averrhoa bilimbi (L) fruit
  7. Rice husk-based cellulose nanocrystal/poly(vinyl alcohol) composite film for the removal of Cu (II) cation from aqueous solution
  8. Gelatin-based forsterite–hydroxyapatite hybrid coating on Ti6Al4V to improve its biocompatibility and corrosion resistance
  9. Enhanced supercapacitive performance of electrophoretically deposited nanostructured molybdenum-doped Mn3O4 thin films
  10. Effect of graphene additive on microstructure and properties of MAO coatings on 6063 aluminum alloy
  11. Enhancing the tensile performance of Al/Mg alloy dissimilar friction stir welded joints by reducing brittle intermetallic compounds
  12. News
  13. DGM – Deutsche Gesellschaft für Materialkunde
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