Home Investigation of the miscibility gap region in liquid Ga–Pb alloys
Article
Licensed
Unlicensed Requires Authentication

Investigation of the miscibility gap region in liquid Ga–Pb alloys

  • Yu. Plevachuk EMAIL logo , V. Filippov , V. Kononenko , P. Popel , A. Rjabina , V. Sidorov and V. Sklyarchuk
Published/Copyright: February 7, 2022
Become an author with De Gruyter Brill

Abstract

The miscibility gap of the Ga–Pb system has been investigated by different experimental methods and techniques. Viscosity, acoustic and electrical conductivity measurements were carried out through the entire immiscibility region. Possible reasons of revealed discrepancies in the absolute values of the phase separation temperatures are discussed in relation with peculiarities of the experimental methods employed. The shape of the miscibility gap has been analysed.

Abstract

Mit Hilfe verschiedener Methoden wurde die Mischungslücke des Systems Ga –Pb untersucht. Dabei wurden die Viskosität, die Akustik und die elektrische Leitfähigkeit gemessen. Die Lage der Binodale im Zustandsdiagramm und der kritische Punkt wurden bestimmt. Es wird diskutiert, wie verschiedene Methoden zu unterschiedlichen Mischungslücken im Flüssigen führen können.


Dr. Yuriy Plevachuk Ivan Franko National University, Faculty of Physics 49 General Chuprynka St., 79044 Lviv, Ukraine Tel.: +380 322 35 34 75 Fax: +380 322 63 15 65

References

[1] B. Predel: Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys, Subvolume G, Springer-Verlag, Berlin (1997).Search in Google Scholar

[2] B. Sokolovskii, V. Didoukh, M. Wobst, W. Hoyer: phys. stat. sol. (a) 139 (1993) 153.10.1002/pssa.2211390113Search in Google Scholar

[3] V. Didoukh, Yu. Plevachuk, B. Sokolovskii: J. Phase Equilib. 17 (1996) 414.10.1007/BF02667632Search in Google Scholar

[4] I. Ansara, F. Ajersch: J. Phase Equilib. 12 (1991) 73.10.1007/BF02663678Search in Google Scholar

[5] B. Prinz, A. Romero: New Casting Process for Hypermonotectic Alloys, in: L. Ratke (Ed.), Immiscible Liquid Metals and Organics, DGM-Informationsgesellschaft, Oberursel (1993) 281.Search in Google Scholar

[6] I.G. Brodova, P.S. Popel, G.I. Eskin: Liquid Metal Processing: Application to Aluminum Alloy Production, Taylor & Francis, London (2002).10.1201/9781482264913Search in Google Scholar

[7] S.P. Jacenko, V.I. Kononenko: Russ. Izvestija AN SSSR. Neorganicheskije materialy 3 (1967) 1569.Search in Google Scholar

[8] Yu. Plevachuk, V. Sklyarchuk: Meas. Sci. Technol. 12 (2001) 23.10.1088/0957-0233/12/1/303Search in Google Scholar

[9] V.M. Glazov, S.G. Kim, G.K. Mambeterzina: Russ. Zavodskaja Laboratorija 57 (1991) 45.Search in Google Scholar

[10] M. Rosen, Z. Satton: Mater. Sci. Eng. 58 (1983) 189.10.1016/0025-5416(83)90045-9Search in Google Scholar

[11] A.R. Regel, V.M. Glazov, S.G. Kim: Russ. Fizika i Technika Poluprovodnikov 20 (1986) 1353.Search in Google Scholar

[12] B. Predel: Z. Metallkd. 50 (1959) 663.10.1515/ijmr-1959-501106Search in Google Scholar

[13] M. Mathon, J.M. Miane, P. Gaune, M. Gambino, J.P. Bros: J. Alloys Comp. 237 (1996) 155.10.1016/0925-8388(95)02178-7Search in Google Scholar

[14] B. Sokolovskii, Yu. Plevachuk, V. Didoukh: phys. stat. sol. (a) 148 (1995) 123.10.1002/pssa.2211480108Search in Google Scholar

[15] Yu. Plevachuk, V. Didoukh, B. Sokolovskii, in: K.E. Spear (Ed.), High Temperature Materials Chemistry IX, The Electrochemical Society, Pennington, New Jersey, 97–39 (1997) 203.Search in Google Scholar

[16] R. Singh, F. Sommer: Z. Metallkd. 83 (1992) 533.10.1515/ijmr-1992-830710Search in Google Scholar

[17] L. Bulavin, in: V. Antonchenko (Ed.), Critical Characteristics of Binary Solutions, The Basics of Physics of Water, Naukova Dumka, Kiev (1991).Search in Google Scholar

[18] T.B. Massaski (Editor-in-Chief): Binary Alloy Phase Diagrams, ASM International, Materials Park, OH (1990) 1837.Search in Google Scholar

Received: 2002-06-04
Published Online: 2022-02-07

© 2003 Carl Hanser Verlag München

Downloaded on 11.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ijmr-2003-0187/html
Scroll to top button