Abstract
Rapid generation of natural gas hydrates is the basis for the application of hydrate storage and transportation. In this work, the kinetic parameters of methane hydrate formation (gas consumption, gas consumption rate constant and reaction space velocity) both in the liquid continuous impinging stream (LIS) system and sodium dodecyl sulfate (SDS) + water and LIS combination system were investigated in a liquid-continuous impinging stream reactor. The gas consumption rate constant was 3.40 × 10−8 mol2 s−1 J−1 without the impinging stream, while it increased with the increase of impinging strength and reached the maximum value of 3.68 × 10−8 mol2 s−1 J−1 when the impinging strength was 0.21. In the SDS + water and LIS combination system, when the SDS concentration was 600 mg/L, the maximum gas consumption rate constant was 3.99 × 10−8 mol2 s−1 J−1 without the impinging stream, while it reached the maximum value of 4.61 × 10−8 mol2 s−1 J−1 when the impinging strength was 0.38. The results showed that the impinging stream can effectively promote the formation rate of methane hydrate, and single mechanical promotion was better than non-promoting mode but combination promotion methods was better than single mechanical promotion.
Funding source: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809,"National Natural Science Foundation of China"
Award Identifier / Grant number: NSFC- 52006200
Award Identifier / Grant number: NSFC-U1404519
Funding source: Science and Technology Department of Henan Province http://dx.doi.org/10.13039/501100011447,"Science and Technology Department of Henan Province"
Award Identifier / Grant number: GZS2018004
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was supported by the National Natural Science Fund of China [grant number NSFC-U1404519]; the National Natural Science Fund of China [grant number NSFC-52006200]; and the Program of Biomass Resources Processing and Efficient Utilization of Outstanding Foreign Scientists’ Workroom [grant number GZS2018004].
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Artikel in diesem Heft
- Frontmatter
- Articles
- Tribological characterization of graphene oxide by laser ablation as a grease additive
- Hydro-liquefaction of asphaltene catalyzed by molybdenum-nickel bimetallic catalysts in slurry bed
- Leaching kinetics of copper and valuable metal extraction from copper-cadmium residues of zinc hydrometallurgy by oxidation acid leaching
- Numerical investigation on optimization of wall jet to reduce high temperature corrosion in 660 MW opposed wall fired boiler
- Kinetics of catalytic treatment of coking wastewater (COD, phenol and cyanide) using wet air oxidation
- Controllable oxidation of cyclohexanone to produce sodium adipate in an electrochemical reactor with a Pt NPs/Ti membrane electrode
- Numerical study on key issues in the Eulerian-Eulerian simulation of fluidization with wide particle size distributions
- Dynamics investigation on methane hydrate formation process with combined promotion methods
Artikel in diesem Heft
- Frontmatter
- Articles
- Tribological characterization of graphene oxide by laser ablation as a grease additive
- Hydro-liquefaction of asphaltene catalyzed by molybdenum-nickel bimetallic catalysts in slurry bed
- Leaching kinetics of copper and valuable metal extraction from copper-cadmium residues of zinc hydrometallurgy by oxidation acid leaching
- Numerical investigation on optimization of wall jet to reduce high temperature corrosion in 660 MW opposed wall fired boiler
- Kinetics of catalytic treatment of coking wastewater (COD, phenol and cyanide) using wet air oxidation
- Controllable oxidation of cyclohexanone to produce sodium adipate in an electrochemical reactor with a Pt NPs/Ti membrane electrode
- Numerical study on key issues in the Eulerian-Eulerian simulation of fluidization with wide particle size distributions
- Dynamics investigation on methane hydrate formation process with combined promotion methods