Abstract
VOx/CeO2 catalysts with various nanostructure were synthesized by the hydrothermal method and used in catalytic combustion of chlorobenzene (CB) at a low temperature. XRD, BET, TEM, Raman, XPS, and H2-TPR were employed to reveal that catalysts VOx on CeO2 support had considerable activity for CB combustion. VOx/CeO2 catalysts prepared with ammonium to adjust pH value and added P123 as a surfactant, showed the highest CB conversion ratio of 60 % at 250 °C and 100 % at 400 °C. It showed that preparation method could infect the shape evolution and surface species during the synthesis. The new phase CeVO4 formed in VOx/CeO2 catalysts improved the catalysts efficiency by increasing oxygen vacancies.
Acknowledgements
The authors acknowledge financial support from General Program of National Nature Science Foundation of China (51674002) and the Key Project of National Nature Science Foundation of China (U1660206).
References
Abreu, G. C., J. A. D. C. Jr, B. E. C. D. Silva, and R. H. Pedrini. 2015. “Operational and Environmental Assessment on the Use of Charcoal Iniron Ore Sinter Production.” Journal of Cleaner Production 101 (101): 387–94.10.1016/j.jclepro.2015.04.015Suche in Google Scholar
Bertinchamps, F., A. Attianese, M. M. Mestdagh, and E. M. Gaigneaux. 2006. “Catalysts for Chlorinated VOCs Abatement: Multiple Effects of Water on the Activity of VOx Based Catalysts for the Combustion of Chlorobenzene.” Catalysis Today 112 (1): 165–68.10.1016/j.cattod.2005.11.043Suche in Google Scholar
Chia Cheng, Y., C. S. Hao, H. B. Zhen, C. K. Hsien, and C. Moo Been. 2008. “Innovative PCDD/F-containing Gas Stream Generating System Applied in Catalytic Decomposition of Gaseous Dioxins over V2O5-WO3/TiO2-based Catalysts.” Chemosphere 73 (6): 890–95.10.1016/j.chemosphere.2008.07.027Suche in Google Scholar
Chul-Hoon, C., and I. Son-Ki. 2002. “Development of New Vanadium-based Oxide Catalysts for Decomposition of Chlorinated Aromatic Pollutants.” Environmental Science & Technology 36 (7): 1600–06.10.1021/es015687hSuche in Google Scholar
Costine, A., T. O’Sullivan, and B. K. Hodnett. 2006. “Reactivity of Electrophilic Oxygen Species Generated over Mesoporous Iron-containing Catalysts.” Catalysis Today 112 (1): 103–06.10.1016/j.cattod.2005.11.032Suche in Google Scholar
Cousin, R., D. Courcot, E. Abi-Aad, S. Capelle, J. P. Amoureux, M. Dourdin, M. Guelton, and A. Aboukaı̈S. 1999. “51 V MAS NMR Characterization of V–Ce–O Catalysts.” Colloids & Surfaces A Physicochemical & Engineering Aspects 158 (1–2): 43–49.10.1016/S0927-7757(99)00129-6Suche in Google Scholar
Dai, Q., S. Bai, X. Wang, and L. U. Guanzhong. 2013. “Catalytic Combustion of Chlorobenzene over Ru-doped Ceria Catalysts: Mechanism Study.” Applied Catalysis B Environmental 129 (3): 580–88.10.1016/j.apcatb.2012.10.006Suche in Google Scholar
Dai, Q., S. Bai, Z. Wang, X. Wang, and L. U. Guanzhong. 2012. “Catalytic Combustion of Chlorobenzene over Ru-doped Ceria Catalysts.” Applied Catalysis B Environmental 126 (126): 64–75.10.1016/j.apcatb.2012.07.008Suche in Google Scholar
Debecker, D. P., R. Delaigle, K. Bouchmella, P. Eloy, E. M. Gaigneaux, and P. H. Mutin. 2010. “Total Oxidation of Benzene and Chlorobenzene with MoO3 - and WO3 -promoted V2O5 /tio2 Catalysts Prepared by a Nonhydrolytic Sol–gel Route.” Catalysis Today 157 (1): 125–30.10.1016/j.cattod.2010.02.010Suche in Google Scholar
Fei, H., C. Yong, Z. Pei, and S. Liu. 2016. “Effect of Calcination Temperature on the Structure and Performance of CeOx - MnOX /tio2 Nanoparticles for the Catalytic Combustion of Chlorobenzene.” Journal of Nanoparticle Research 18 (5): 1–10.Suche in Google Scholar
Gannoun, C., R. Delaigle, D. P. Debecker, P. Eloy, A. Ghorbel, and E. M. Gaigneaux. 2012. “Effect of Support on V2O5 Catalytic Activity in Chlorobenzene Oxidation.” Applied Catalysis A General 447–48 (24): 1–6.10.1016/j.apcata.2012.08.034Suche in Google Scholar
Gannoun, C., R. Delaigle, P. Eloy, D. P. Debecker, A. Ghorbel, and E. M. Gaigneaux. 2011. “Sol–gel Derived V2O5–TiO2 Mesoporous Materials as Catalysts for the Total Oxidation of Chlorobenzene.” Catalysis Communications 15 (1): 1–5.10.1016/j.catcom.2011.08.001Suche in Google Scholar
Giraudon, J. M., A. Elhachimi, and G. Leclercq. 2008. “Catalytic Oxidation of Chlorobenzene over Pd/perovskites.” Applied Catalysis B Environmental 84 (1–2): 251–61.10.1016/j.apcatb.2008.04.023Suche in Google Scholar
Guerriero, E., A. Guarnieri, S. Mosca, G. Rossetti, and M. Rotatori. 2009. “PCDD/Fs Removal Efficiency by Electrostatic Precipitator and Wetfine Scrubber in an Iron Ore Sintering Plant.” Journal of Hazardous Materials 172 (2): 1498–504.10.1016/j.jhazmat.2009.08.019Suche in Google Scholar
Hao, H., Y. Gu, Z. Jian, and X. Wang. 2015. “Catalytic Combustion of Chlorobenzene over VOx/CeO2 Catalysts.” Journal of Catalysis 326: 54–68.10.1016/j.jcat.2015.02.016Suche in Google Scholar
He, H., H. X. Dai, and C. T. Au. 2004. “Defective Structure, Oxygen Mobility, Oxygen Storage Capacity, and Redox Properties of RE-based (RE = Ce, Pr) Solid Solutions.” Catalysis Today 89 (3): 245–54.10.1016/j.cattod.2004.04.033Suche in Google Scholar
Hetrick, C. E., J. Lichtenberger, and M. D. Amiridis. 2008. “Catalytic Oxidation of Chlorophenol over V2O5/TiO2 Catalysts.” Applied Catalysis B Environmental 77 (3): 255–63.10.1016/j.apcatb.2007.07.022Suche in Google Scholar
Huang, H., W. Ling, L. Jin, L. Wang, and H. Lu. 2012. “Support Effect on Catalytic Activity of VOCs Combustion over Supported Cu-Mn-Ce Catalysts.” Journal of the Chinese Society of Rare Earths 30 (03): 295–300.Suche in Google Scholar
Hutchings, G. J., C. S. Heneghan, I. D. Hudson, and S. H. Taylor. 1996. “Uranium-oxide-based Catalysts for the Destruction of Volatile Chloro-organic Compounds.” Nature 384 (6607): 341–43.10.1038/384341a0Suche in Google Scholar
Jagtap, N., and V. Ramaswamy. 2006. “Oxidation of Aniline over Titania Pillared Montmorillonite Clays.” Applied Clay Science 33 (2): 89–98.10.1016/j.clay.2006.04.001Suche in Google Scholar
Kan, J., D. Lei, L. Bing, Q. Huang, S. Zhu, S. Shen, and Y. Chen. 2016. “Performance of Co-doped Mn-Ce Catalysts Supported on Cordierite for Low Concentration Chlorobenzene Oxidation.” Applied Catalysis A General 530: 21–29.10.1016/j.apcata.2016.11.013Suche in Google Scholar
Kaspar, J., P. Fornasiero, and M. Graziani. 1999. “Use of CeO2-based Oxides in the Three-way Catalysis.” Catalysis Today 50 (2): 285–98.10.1016/S0920-5861(98)00510-0Suche in Google Scholar
Krajnc, M. 1997. “Oxidation of Phenol over a Transition-Metal Oxide Catalyst in Supercritical Water.” Industrial & Engineering Chemistry Research 36 (9): 3439–45.10.1021/ie9701130Suche in Google Scholar
Lars, S., and T. Andersson. 1990. “An XPS Study of Dispersion and Valence State of TiO2 Supported Vanadium Oxide Catalysts.” Catalysis Letters 7 (5–6): 351–58.10.1007/BF00764924Suche in Google Scholar
Lavric, E. D., A. A. Konnov, and R. J. De. 2005. “Surrogate Compounds for Dioxins in Incineration. A Review.” Waste Management 25 (7): 755–65.10.1016/j.wasman.2004.12.026Suche in Google Scholar PubMed
Lichtenberger, J., and M. D. Amiridis. 2004. “Catalytic Oxidation of Chlorinated Benzenes over V2O5/TiO2 Catalysts.” Journal of Catalysis 223 (2): 296–308.10.1016/j.jcat.2004.01.032Suche in Google Scholar
Long, H., Q. Shi, H. Zhang, R. Wei, T. Chun, and J. Li. 2018. “Application Status and Comparison of Dioxin Removal Technologies for Iron Ore Sintering Process.” Journal of Iron and Steel Research International 25 (4): 357–65.10.1007/s42243-018-0046-ySuche in Google Scholar
Mai, H., L. Sun, Y. Zhang, R. Si, W. Feng, H. Zhang, H. Liu, and C. Yan. 2005. “Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes.” The Journal of Physical Chemistry B 109 (51): 24380–85.10.1021/jp055584bSuche in Google Scholar PubMed
Man, C., L. Zhoushiang, Y. Chyiwoei, and S. Yujen. 2012. “Application of SCR Catalyst to Sinter Plant for NO/dioxins Removal.” Engineering Journal of Wuhan University 45 (6): 751–56.Suche in Google Scholar
Maria Veronica, G. P., P. Cristina, S. Joachim, A. Heather, U. Alexander, B. Martin, S. Dario, B. Oleksandr, S. Shamil, and F. Hans-Joachim. 2010. “Role of Ceria in Oxidative Dehydrogenation on Supported Vanadia Catalysts.” Journal of the American Chemical Society 132 (7): 2345–49.10.1021/ja910574hSuche in Google Scholar PubMed
Martínez Arias, A., M. Fernández García, C. Belver, J. C. Conesa, and J. Soria. 2000. “EPR Study on Oxygen Handling Properties of Ceria, Zirconia and Zr–Ce (1: 1) Mixed Oxide Samples.” Catalysis Letters 65 (4): 197–204.10.1023/A:1019089910238Suche in Google Scholar
Martı́Nez-Huerta, M. V., J. M. Coronado, M. Fernández-Garcı́A, A. Iglesias-Juez, G. Deo, J. L. G. Fierro, and M. A. Bañares. 2004. “Nature of the Vanadia–ceria Interface in V5+ /ceo2 Catalysts and Its Relevance for the Solid-state Reaction toward CeVO4 and Catalytic Properties.” Journal of Catalysis 225 (1): 240–48.10.1016/j.jcat.2004.04.005Suche in Google Scholar
Miller, D. D., and S. S. C. Chuang. 2009. “In Situ Infrared Study of NO Reduction over Pd/Al2O3 and Ag-Pd/Al2O3 Catalysts under H2-rich and Lean-burn Conditions.” Journal of the Taiwan Institute of Chemical Engineers 40 (6): 613–21.10.1016/j.jtice.2009.04.006Suche in Google Scholar
Pandelova, M., D. Lenoir, and K. W. Schramm. 2006. “Correlation between PCDD/F, PCB and PCBz in Coal/waste Combustion. Influence of Various Inhibitors.” Chemosphere 62 (7): 1196–205.10.1016/j.chemosphere.2005.07.068Suche in Google Scholar
Pfau, A., and K. D. Schierbaum. 1994. “The Electronic Structure of Stoichiometric and Reduced CeO2 Surfaces: An XPS, UPS and HREELS Study.” Surface Science 321 (1–2): 71–80.10.1016/0039-6028(94)90027-2Suche in Google Scholar
Qian, L., T. Chun, H. Long, J. Li, Z. Di, Q. Meng, and P. Wang. 2018. “Emission Reduction Research and Development of PCDD/Fs in the Iron Ore Sintering.” Process Safety and Environmental Protection 117: 82–91.10.1016/j.psep.2018.04.014Suche in Google Scholar
Savage, P. E., J. B. Dunn, and Y. U. Jianli. 2006. “Recent Advances in Catalytic Oxidation in Supercritical Water.” Combustion Science & Technology 178 (1–3): 443–65.10.1080/00102200500287159Suche in Google Scholar
Scirè, S., and L. F. Liotta. 2012. “Supported Gold Catalysts for the Total Oxidation of Volatile Organic Compounds.” Applied Catalysis B Environmental 125 (2): 222–46.10.1016/j.apcatb.2012.05.047Suche in Google Scholar
Shen, B., Y. Yao, H. Ma, and T. Liu. 2011. “Ceria Modified MnOX/TiO2-Pillared Clays Catalysts for the Selective Catalytic Reduction of NO with NH3 at Low Temperature.” Chinese Journal of Catalysis 32 (11–12): 1803–11.10.1016/S1872-2067(10)60269-0Suche in Google Scholar
Shi, L., X. Wang, Q. Zhao, and Y. Zhang. 2010. “Low Temperature Catalytic Combustion of Chlorobenzene over Mn–Ce–O/γ-Al2O3 Mixed Oxides Catalyst.” Catalysis Today 158 (3): 336–42.10.1016/j.cattod.2010.04.006Suche in Google Scholar
Sokolovskii, V. D. 1990. “Principles of Oxidative Catalysis on Solid Oxides.” Catalysis Reviews 32 (1): 1–49.10.1080/01614949009349939Suche in Google Scholar
Steele, B. C. H. 1999. “Fuel-cell Technology: Running on Natural Gas.” Nature 400 (400): 619–21.10.1038/23144Suche in Google Scholar
Stieglitz, L., G. Zwick, J. Beck, H. Bautz, and W. Roth. 1990. “The Role of Particulate Carbon in the De-novo Synthesis of Polychlorinated Dibenzodioxins And-furans in Fly-ash.” Chemosphere 20 (10): 1953–58.10.1016/0045-6535(90)90365-ZSuche in Google Scholar
Stieglitz, L., G. Zwick, J. Beck, H. Bautz, W. Roth, L. Stieglitz, G. Zwick, J. Beck, H. Bautz, and W. Roth. 1989. “Carbonaceous Particles in Fly Ash -a Source for the De-novo-synthesis of Organochlorocompounds.” Chemosphere 19 (1): 283–90.10.1016/0045-6535(89)90325-1Suche in Google Scholar
Sun, Q., Y. Fu, J. Liu, A. Auroux, and J. Shen. 2008. “Structural, Acidic and Redox Properties of V2O5-TiO2SO42− Catalysts.” Applied Catalysis A General 334 (1): 26–34.10.1016/j.apcata.2007.09.023Suche in Google Scholar
Taralunga, M., J. Mijoin, and P. Magnoux. 2005. “Catalytic Destruction of Chlorinated POPs—Catalytic Oxidation of Chlorobenzene over PtHFAU Catalysts.” Applied Catalysis B Environmental 60 (3): 163–71.10.1016/j.apcatb.2005.02.024Suche in Google Scholar
Weber, W. H., K. C. Hass, and J. R. Mcbride. 1993. “Raman Study of CeO2: Second-order Scattering, Lattice Dynamics, and Particle-size Effects.” Physical Review B Condensed Matter 48 (1): 178.10.1103/PhysRevB.48.178Suche in Google Scholar
Wei, D., Q. Dai, Y. Lao, B. Shi, and X. Wang. 2015. “Low Temperature Catalytic Combustion of 1,2-dichlorobenzene over CeO2-TiO2 Mixed Oxide Catalysts.” Applied Catalysis B Environmental 181: 848–61.Suche in Google Scholar
Wu, Z., A. J. Rondinone, and S. H. Overbury. 2011. “Structure of Vanadium Oxide Supported on Ceria by Multiwavelength Raman Spectroscopy.” Journal of Physical Chemistry C 115 (51): 25368–78.10.1021/jp2084605Suche in Google Scholar
Xiang, X., Z. Sheng, Y. Liu, and D. Fan. 2015. “Low-temperature Selective Catalytic Reduction of NOX with NH3 over a Manganese and Cerium Oxide/graphene Composite Prepared by a Hydrothermal Method.” Catalysis Science & Technology 6 (5): 1507–14.Suche in Google Scholar
Xingyi, W., K. Qian, and L. Dao. 2009. “Catalytic Combustion of Chlorobenzene over MnOX–CeO2 Mixed Oxide Catalysts.” Applied Catalysis B: Environmental 86 (3–4): 166–75.10.1016/j.apcatb.2008.08.009Suche in Google Scholar
Yang, S., H. Zhao, F. Dong, F. Zha, and Z. Tang. 2019. “Highly Efficient Catalytic Combustion of O-dichlorobenzene over Three-dimensional Ordered Mesoporous Cerium Manganese Bimetallic Oxides: A New Concept of Chlorine Removal Mechanism.” Molecular Catalysis 463: 119–29.10.1016/j.mcat.2018.12.006Suche in Google Scholar
Zhao, X., J. You, X. Lu, and Z. Chen. 2011. “Hydrothermal Synthesis, Characterization and Property of CeO2 Nanotube.” Journal of Inorganic Materials 26 (02): 159–64.10.3724/SP.J.1077.2011.00159Suche in Google Scholar
Zuo, S., M. Ding, T. Jing, L. Feng, and C. Qi. 2015. “Study on the Preparation and Characterization of a Titanium-pillared Clay-supported CrCe Catalyst and Its Application to the Degradation of a Low Concentration of Chlorobenzene.” Applied Clay Science 105–106: 118–23.10.1016/j.clay.2014.12.033Suche in Google Scholar
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Artikel in diesem Heft
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- Articles
- Promoting Effects of Al on Ni-Based Catalyst for the Hydrodeoxygenation Performance of Ethyl Acetate
- Chalcopyrite Leaching Kinetics in the Presence of Methanol
- 3D CFD Simulation of Gas Hold-up and Mass Transfer in a Modified Airlift Reactor with Net Draft Tube
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- A Facile Method to Synthesize Ni2P Catalysts and their Catalytic Performances in Hydrotreating Reactions
- Evaluation of Electrocoagulation and Activated Carbon Adsorption Techniques Used Separately or Coupled to Treat Wastewater from Industrial Dairy
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