Startseite Catalytic Combustion of Chlorobenzene with VOx/CeO2 Catalysts: Influence of Catalyst Synthesis Method
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Catalytic Combustion of Chlorobenzene with VOx/CeO2 Catalysts: Influence of Catalyst Synthesis Method

  • Qi Shi , Hong-ming Long EMAIL logo , Tie-jun Chun und Zhi-fang Gao
Veröffentlicht/Copyright: 18. September 2019

Abstract

VOx/CeO2 catalysts with various nanostructure were synthesized by the hydrothermal method and used in catalytic combustion of chlorobenzene (CB) at a low temperature. XRD, BET, TEM, Raman, XPS, and H2-TPR were employed to reveal that catalysts VOx on CeO2 support had considerable activity for CB combustion. VOx/CeO2 catalysts prepared with ammonium to adjust pH value and added P123 as a surfactant, showed the highest CB conversion ratio of 60 % at 250 °C and 100 % at 400 °C. It showed that preparation method could infect the shape evolution and surface species during the synthesis. The new phase CeVO4 formed in VOx/CeO2 catalysts improved the catalysts efficiency by increasing oxygen vacancies.

Acknowledgements

The authors acknowledge financial support from General Program of National Nature Science Foundation of China (51674002) and the Key Project of National Nature Science Foundation of China (U1660206).

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Received: 2019-04-30
Revised: 2019-07-29
Accepted: 2019-08-22
Published Online: 2019-09-18

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Heruntergeladen am 16.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijcre-2019-0084/html
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