Promoting Effects of Al on Ni-Based Catalyst for the Hydrodeoxygenation Performance of Ethyl Acetate
Abstract
The mesoporous Ni20/Al-KIT-6 (denoted as N20AxK) catalysts with different Al content (1–9 wt%) were prepared, metal Ni and KIT-6 modified by Al were used as active component and support, respectively. The physicochemical properties of the prepared N20AxK catalysts were characterized by H2-TPR, XRD, BET, TEM, and H2-TPD. The catalytic hydrodeoxygenation(HDO) performance of N20AxK catalysts was evaluated by ethyl acetate catalytic HDO. The results show that the catalytic HDO performance of the prepared N20AxK catalysts is related to the adsorption and activation performance for H2 molecules, as well as the dispersion of matal Ni active components. N20A5K catalyst shows the best H2 adsorption property and Ni dispersion. N20A5K catalyst presents superior catalytic HDO performance. At 300 °C and atmospheric pressure, the conversion of ethyl acetate and ethane selectivity of N20A5K catalyst are 99.3 % and 97.4 %, respectively. Besides, the N20A5K catalyst exhibits good stability.
Funding statement: This research is funded by Research Foundation of Chongqing Technology and Business University (No. 1752001); Scientific and Technological Key Program of Chongqing Municipal Education Commission (KJZD-K201800801).
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Artikel in diesem Heft
- Review
- Thermally Intensification of Steam Reforming Process by Use of Methane Tri-Reforming: A Review
- Articles
- Promoting Effects of Al on Ni-Based Catalyst for the Hydrodeoxygenation Performance of Ethyl Acetate
- Chalcopyrite Leaching Kinetics in the Presence of Methanol
- 3D CFD Simulation of Gas Hold-up and Mass Transfer in a Modified Airlift Reactor with Net Draft Tube
- Catalytic Combustion of Chlorobenzene with VOx/CeO2 Catalysts: Influence of Catalyst Synthesis Method
- Dual Treatment of Milk Processing Industry Wastewater Using Electro Fenton Process Followed by Anaerobic Treatment
- A Facile Method to Synthesize Ni2P Catalysts and their Catalytic Performances in Hydrotreating Reactions
- Evaluation of Electrocoagulation and Activated Carbon Adsorption Techniques Used Separately or Coupled to Treat Wastewater from Industrial Dairy
- Theoretical Study of CO2 Absorption into Novel Reactive 1DMA2P Solvent in Split-flow Absorber-stripper Unit: Mass Transfer Performance and Kinetic Analysis
- Gas-solid Flow Behaviors in a Pressurized Multi-stage Circulating Fluidized Bed with Geldart Group B Particles
Artikel in diesem Heft
- Review
- Thermally Intensification of Steam Reforming Process by Use of Methane Tri-Reforming: A Review
- Articles
- Promoting Effects of Al on Ni-Based Catalyst for the Hydrodeoxygenation Performance of Ethyl Acetate
- Chalcopyrite Leaching Kinetics in the Presence of Methanol
- 3D CFD Simulation of Gas Hold-up and Mass Transfer in a Modified Airlift Reactor with Net Draft Tube
- Catalytic Combustion of Chlorobenzene with VOx/CeO2 Catalysts: Influence of Catalyst Synthesis Method
- Dual Treatment of Milk Processing Industry Wastewater Using Electro Fenton Process Followed by Anaerobic Treatment
- A Facile Method to Synthesize Ni2P Catalysts and their Catalytic Performances in Hydrotreating Reactions
- Evaluation of Electrocoagulation and Activated Carbon Adsorption Techniques Used Separately or Coupled to Treat Wastewater from Industrial Dairy
- Theoretical Study of CO2 Absorption into Novel Reactive 1DMA2P Solvent in Split-flow Absorber-stripper Unit: Mass Transfer Performance and Kinetic Analysis
- Gas-solid Flow Behaviors in a Pressurized Multi-stage Circulating Fluidized Bed with Geldart Group B Particles