Exploring the inhibitive performance of amino-dicarbonitrile derivative for Q235 steel protection in Cl3CCOOH solution: effect of temperature and synergism with iodide ions
-
Kashif Rahmani Ansari
,
Ambrish Singh
,
Ismat H. Ali
Abstract
The inhibitory performance of amino-dicarbonitrile derivative (ANC) for the protection of Q235 steel corrosion in trichloroacetic acid (Cl3CCOOH) solution was investigated using various methods. The surface adsorption of ANC was screened by SEM, AFM, and XPS methods. Based on the data, it can be concluded that ANC effectively inhibits Q235 steel in 0.5 M Cl3CCOOH solution, with 94.3 % inhibition efficiency (η%) at 100 mg/L. The Freundlich model describes how ANC adsorbs on the surface of Q235 steel. Anodic and cathodic reactions are both retarded by ANC, a mixed type inhibitor. The depressed capacitive loop observed is the Nyquist diagram. The double layer capacitance decreases but the charge transfer resistance rises noticeably with the addition of ANC. The AFM and SEM micrographs provide unambiguous confirmation of the effective inhibition of ANC. The XPS result shows that ANC molecules functional groups are attached to the iron atoms.
Funding source: Deanship of Scientific Research, King Khalid University
Award Identifier / Grant number: R.G.P. 2/341/45
-
Research ethics: Not applicable.
-
Informed consent: Not applicable.
-
Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
-
Use of Large Language Models, AI and Machine Learning Tools: Not applicable.
-
Conflict of interests: The authors state no conflict of interest.
-
Research funding: The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through a research group program under grant number R.G.P. 2/341/45.
-
Data availability: The raw data can be obtained on request from the corresponding author.
References
Abdel-Wahaab, S., Abo-El Wafa, O., Kamel, G., and Rashwan, S. (1986). Corrosion of tin in aqueous solutions of mono-, Di-and trichloroacetic acids. J. Chem. Technol. Biotechnol. 36: 305–318, https://doi.org/10.1002/jctb.280360704.Suche in Google Scholar
Akinbulumo, O.A., Odejobi, O.J., and Odekanle, E.L. (2020). Thermodynamics and adsorption study of the corrosion inhibition of mild steel by Euphorbia heterophylla L. extract in 1.5- M HCl. Result. Mat. 5: 100074, https://doi.org/10.1016/j.rinma.2020.100074.Suche in Google Scholar
Al-Amiery, A.A., Betti, N., Isahak, W.N.R.W., Al-Azzawi, W.K., and Wan Nik, W.M.N. (2023). Exploring the effectiveness of isatin–schiff base as an environmentally friendly corrosion inhibitor for mild steel in hydrochloric acid. Lubricants 11: 211, https://doi.org/10.3390/lubricants11050211.Suche in Google Scholar
Al-Baghdadi, S., Gaaz, T., Al-Adili, A., Al-Amiery, A., and Takriff, M. (2021). Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation. Int. J. Low Carbon Technol. 16: 181–188, https://doi.org/10.1093/ijlct/ctaa050.Suche in Google Scholar
Alamiery, A., Isahak, W., Aljibori, H., Al-Asadi, H., and Kadhum, A. (2021). Effect of the structure, immersion time and temperature on the corrosion inhibition of 4-pyrrol-1-yl-n-(2, 5-dimethyl-pyrrol-1-yl) benzoylamine in 1.0 m HCl solution. Int. J. Corr. Scale Inhibit. 10: 700–713.10.17675/2305-6894-2021-10-2-14Suche in Google Scholar
Babić-Samardžija, K., Lupu, C., Hackerman, N., Barron, A.R., and Luttge, A. (2005). Inhibitive properties and surface morphology of a group of heterocyclic diazoles as inhibitors for acidic iron corrosion. Langmuir 21: 12187–12196, https://doi.org/10.1021/la051766l.Suche in Google Scholar PubMed
Bai, C., Liu, T., Shi, L., Song, L., Li, Y., Su, R., Zhao, Y., and Yu, H. (2024). Effect of different Mg2Si concentrations on the wear properties and microstructure of Mg2Si/Al–5 wt.% Cu composites. Int. J. Metalcast.: 1–13, https://doi.org/10.1007/s40962-024-01321-9.Suche in Google Scholar
Bentiss, F., Traisnel, M., and Lagrenee, M. (2000). The substituted 1, 3, 4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media. Corros. Sci. 42: 127–146, https://doi.org/10.1016/s0010-938x(99)00049-9.Suche in Google Scholar
Beyenal, H. and Babauta, J.T. (2015). Biofilms in bioelectrochemical systems: from laboratory practice to data interpretation. John Wiley & Sons, New York, NY.10.1002/9781119097426Suche in Google Scholar
Bouraoui, M.M., Chettouh, S., Chouchane, T., and Khellaf, N. (2019). Inhibition efficiency of cinnamon oil as a green corrosion inhibitor. J. Bio. Tribo Corr. 5: 1–9, https://doi.org/10.1007/s40735-019-0221-0.Suche in Google Scholar
Caihong, Y., Singh, A., Ansari, K., Ali, I.H., and Kumar, R. (2022). Novel nitrogen based heterocyclic compound as Q235 steel corrosion inhibitor in 15% HCl under dynamic condition: a detailed experimental and surface analysis. J. Mol. Liq. 362: 119720, https://doi.org/10.1016/j.molliq.2022.119720.Suche in Google Scholar
Canneva, A., Giordana, I.n. S., Erra, G., and Calvo, A. (2017). Organic matter characterization of shale rock by X-ray photoelectron spectroscopy: adventitious carbon contamination and radiation damage. Energy Fuels 31: 10414–10419, https://doi.org/10.1021/acs.energyfuels.7b01143.Suche in Google Scholar
Chauhan, D.S., Mazumder, M.J., Quraishi, M., Ansari, K., and Suleiman, R. (2020). Microwave-assisted synthesis of a new Piperonal-Chitosan Schiff base as a bio-inspired corrosion inhibitor for oil-well acidizing. Int. J. Biol. Macromol. 158: 231–243, https://doi.org/10.1016/j.ijbiomac.2020.04.195.Suche in Google Scholar PubMed
Desai, P. and Vashi, R. (2011). Inhibitive efficiency of sulphathiazole for aluminum corrosion in trichloroacetic acid. Anti Corr. Method. Mat. 58: 70–75, https://doi.org/10.1108/00035591111110714.Suche in Google Scholar
Ebenso, E., Okafor, P., and Ekpe, U. (2003). Studies on the inhibition of aluminium corrosion by 2-acetylphenothiazine in chloroacetic acids. Anti Corr. Method. Mat. 50: 414–421, https://doi.org/10.1108/00035590310501576.Suche in Google Scholar
Esclapez, M.D., Díez-García, M.I., Sáez, V., Tudela, I., Pérez, J.M., González-García, J., and Bonete, P. (2011). Spectroelectrochemical study of trichloroacetic acid reduction at copper electrodes in an aqueous sodium sulfate medium. Electrochim. Acta 56: 8138–8146, https://doi.org/10.1016/j.electacta.2011.05.133.Suche in Google Scholar
Finšgar, M. and Jackson, J. (2014). Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: a review. Corros. Sci. 86: 17–41, https://doi.org/10.1016/j.corsci.2014.04.044.Suche in Google Scholar
Fragoza-Mar, L., Olivares-Xometl, O., Domínguez-Aguilar, M.A., Flores, E.A., Arellanes-Lozada, P., and Jiménez-Cruz, F. (2012). Corrosion inhibitor activity of 1, 3-diketone malonates for mild steel in aqueous hydrochloric acid solution. Corros. Sci. 61: 171–184, https://doi.org/10.1016/j.corsci.2012.04.031.Suche in Google Scholar
Gandhi, M.R., Viswanathan, N., and Meenakshi, S. (2010). Preparation and application of alumina/chitosan biocomposite. Int. J. Biol. Macromol. 47: 146–154, https://doi.org/10.1016/j.ijbiomac.2010.05.008.Suche in Google Scholar PubMed
Geng, Z., Chen, C., Song, M., Luo, J., Chen, J., Li, R., and Zhou, K. (2024). High strength Al0. 7CoCrFeNi2. 4 hypereutectic high entropy alloy fabricated by laser powder bed fusion via triple-nanoprecipitation. J. Mat. Sci. Technol. 187: 141–155, https://doi.org/10.1016/j.jmst.2023.11.054.Suche in Google Scholar
Hammouti, B., Zarrok, H., Bouachrine, M., Khaled, K., and Al-Deyab, S. (2012). Corrosion inhibition of copper in nitric acid solutions using a new triazole derivative. Int. J. Electrochem. Sci. 7: 89–105, https://doi.org/10.1016/s1452-3981(23)13323-2.Suche in Google Scholar
Haque, J., Ansari, K., Srivastava, V., Quraishi, M., and Obot, I. (2017). Pyrimidine derivatives as novel acidizing corrosion inhibitors for N80 steel useful for petroleum industry: a combined experimental and theoretical approach. J. Ind. Eng. Chem. 49: 176–188, https://doi.org/10.1016/j.jiec.2017.01.025.Suche in Google Scholar
Hong, W.G., Kim, B.H., Lee, S.M., Yu, H.Y., Yun, Y.J., Jun, Y., Lee, J.B., and Kim, H.J. (2012). Agent-free synthesis of graphene oxide/transition metal oxide composites and its application for hydrogen storage. Int. J. Hydrogen Energy 37: 7594–7599, https://doi.org/10.1016/j.ijhydene.2012.02.010.Suche in Google Scholar
Huang, H., Fu, Y., Li, F., Wang, Z., Zhang, S., Wang, X., Wang, Z., Li, H., and Gao, F. (2020). Orderly self-assembly of new ionic copolymers for efficiently protecting copper in aggressive sulfuric acid solution. Chem. Eng. J. 384: 123293, https://doi.org/10.1016/j.cej.2019.123293.Suche in Google Scholar
Ismail, M.A., Shaban, M.M., Abdel-Latif, E., Abdelhamed, F.H., Migahed, M.A., El-Haddad, M.N., and Abousalem, A.S. (2022). Novel cationic aryl bithiophene/terthiophene derivatives as corrosion inhibitors by chemical, electrochemical and surface investigations. Sci. Rep. 12: 3192, https://doi.org/10.1038/s41598-022-06863-8.Suche in Google Scholar PubMed PubMed Central
Kokalj, A. (2021). Molecular modeling of organic corrosion inhibitors: calculations, pitfalls, and conceptualization of molecule–surface bonding. Corros. Sci. 193: 109650, https://doi.org/10.1016/j.corsci.2021.109650.Suche in Google Scholar
Kowsari, E., Arman, S., Shahini, M., Zandi, H., Ehsani, A., Naderi, R., PourghasemiHanza, A., and Mehdipour, M. (2016). In situ synthesis, electrochemical and quantum chemical analysis of an amino acid-derived ionic liquid inhibitor for corrosion protection of mild steel in 1M HCl solution. Corros. Sci. 112: 73–85, https://doi.org/10.1016/j.corsci.2016.07.015.Suche in Google Scholar
Li, X. and Deng, S. (2020). Synergistic inhibition effect of walnut green husk extract and potassium iodide on the corrosion of cold rolled steel in trichloroacetic acid solution. J. Mater. Res. Technol. 9: 15604–15620, https://doi.org/10.1016/j.jmrt.2020.11.018.Suche in Google Scholar
Li, X. and Deng, S. (2021). Ce (SO4) 2 as an efficient corrosion inhibitor for cold rolled steel in citric acid solution. J. Taiwan Inst. Chem. Eng. 122: 273–283, https://doi.org/10.1016/j.jtice.2021.04.057.Suche in Google Scholar
Li, X., Deng, S., Li, N., and Xie, X. (2017). Inhibition effect of bamboo leaves extract on cold rolled steel in Cl3CCOOH solution. J. Mater. Res. Technol. 6: 158–170, https://doi.org/10.1016/j.jmrt.2016.09.002.Suche in Google Scholar
Li, X., Deng, S., Lin, T., Xie, X., and Xu, X. (2019). Inhibition action of triazolyl blue tetrazolium bromide on cold rolled steel corrosion in three chlorinated acetic acids. J. Mol. Liq. 274: 77–89, https://doi.org/10.1016/j.molliq.2018.10.066.Suche in Google Scholar
Li, Y., Chen, X., Zeng, X., Liu, M., Jiang, X., and Leng, Y. (2024). Hard yet tough and self-lubricating (CuNiTiNbCr) Cx high-entropy nanocomposite films: effects of carbon content on structure and properties. J. Mat. Sci. Technol. 173: 20–30, https://doi.org/10.1016/j.jmst.2023.05.082.Suche in Google Scholar
Liu, W., Huang, F., Liao, Y., Zhang, J., Ren, G., Zhuang, Z., Zhen, J., Lin, Z., and Wang, C. (2008). Treatment of CrVI-containing Mg (OH) 2 nanowaste. Angew. Chem. 120: 5701–5704, https://doi.org/10.1002/ange.200800172.Suche in Google Scholar
Liu, W., Zheng, J., Ou, X., Liu, X., Song, Y., Tian, C., Rong, W., Shi, Z., Dang, Z., and Lin, Z. (2018). Effective extraction of Cr (VI) from hazardous gypsum sludge via controlling the phase transformation and chromium species. Environ. Sci. Technol. 52: 13336–13342, https://doi.org/10.1021/acs.est.8b02213.Suche in Google Scholar PubMed
Mazumder, M.A., Al-Muallem, H.A., Faiz, M., and Ali, S.A. (2014). Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media. Corros. Sci. 87: 187–198, https://doi.org/10.1016/j.corsci.2014.06.026.Suche in Google Scholar
Metals, A.-o. (2017). Standard practice for preparing, cleaning, and evaluating corrosion test specimens. ASTM International, West Conshohocken, Pennsylvania.Suche in Google Scholar
Migahed, M., Farag, A.A., Elsaed, S., Kamal, R., Mostfa, M., and Abd El-Bary, H. (2011). Synthesis of a new family of Schiff base nonionic surfactants and evaluation of their corrosion inhibition effect on X-65 type tubing steel in deep oil wells formation water. Mater. Chem. Phys. 125: 125–135, https://doi.org/10.1016/j.matchemphys.2010.08.082.Suche in Google Scholar
Modiano, S., Carreño, J., Fugivara, C.S., Benedetti, A.V., and Mattos, O. (2005). Effect of hydrogen charging on the stability of SAE 10B22 steel surface in alkaline solutions. Electrochim. Acta 51: 641–648, https://doi.org/10.1016/j.electacta.2005.05.022.Suche in Google Scholar
Mohammed Khan, K., Jamil, W., Ambreen, N., Amyn, A., Saied, S., Kanwal, M., Ahmed, A., and Perveen, S. (2012). Synthesis, antibacterial and antifungal activities of 3-amino-5-methyl [1, 1’-biphenyl]-2, 4-dicarbonitrile derivatives. Lett. Drug Des. Discov. 9: 618–624, https://doi.org/10.2174/157018012800672985.Suche in Google Scholar
Murmu, M., Saha, S.K., Murmu, N.C., and Banerjee, P. (2019). Effect of stereochemical conformation into the corrosion inhibitive behaviour of double azomethine based Schiff bases on mild steel surface in 1 mol L− 1 HCl medium: an experimental, density functional theory and molecular dynamics simulation study. Corros. Sci. 146: 134–151, https://doi.org/10.1016/j.corsci.2018.10.002.Suche in Google Scholar
Singh, A., Ansari, K., Quraishi, M., Lgaz, H., and Lin, Y. (2018). Synthesis and investigation of pyran derivatives as acidizing corrosion inhibitors for N80 steel in hydrochloric acid: theoretical and experimental approaches. J. Alloys Compd. 762: 347–362, https://doi.org/10.1016/j.jallcom.2018.05.236.Suche in Google Scholar
Singh, A., Ansari, K., Chauhan, D.S., Quraishi, M., Lgaz, H., and Chung, I.-M. (2020a). Comprehensive investigation of steel corrosion inhibition at macro/micro level by ecofriendly green corrosion inhibitor in 15% HCl medium. J. Colloid Interface Sci. 560: 225–236, https://doi.org/10.1016/j.jcis.2019.10.040.Suche in Google Scholar PubMed
Singh, A., Ansari, K., Quraishi, M., Kaya, S., and Guo, L. (2020b). Aminoantipyrine derivatives as a novel eco-friendly corrosion inhibitors for P110 steel in simulating acidizing environment: experimental and computational studies. J. Nat. Gas Sci. Eng. 83: 103547, https://doi.org/10.1016/j.jngse.2020.103547.Suche in Google Scholar
Singh, A., Ansari, K., Lin, Y., Ali, I.H., Kaya, S., and El Ibrahimi, B. (2022). Inhibitive performance of novel/eco-friendly pyrimidine derivative for Q235 steel protection in 15% HCl under hydrodynamic condition: combination of experimental, surface and computational approach. Mater. Today Commun. 32: 104110, https://doi.org/10.1016/j.mtcomm.2022.104110.Suche in Google Scholar
Singh, A., Ansari, K., Ali, I.H., Lin, Y., Murmu, M., and Banerjee, P. (2023a). Evaluation of corrosion mitigation properties of pyridinium-based ionic liquids on carbon steel in 15% HCl under the hydrodynamic condition: experimental, surface, and computational approaches. J. Mol. Liq. 376: 121408, https://doi.org/10.1016/j.molliq.2023.121408.Suche in Google Scholar
Singh, A., Ansari, K., Ali, I.H., Younas, M., Alanazi, A.K., Alamri, A.H., and Lin, Y. (2023b). Experimental, surface and theoretical investigations of a new benzodiazepine derivative designed for corrosion inhibition of carbon steel in 15% hydrochloric acid medium under hydrodynamic environment. Inorg. Chem. Commun. 158: 111684, https://doi.org/10.1016/j.inoche.2023.111684.Suche in Google Scholar
Singh, A., Ansari, K., Sharma, N.R., Singh, S., Singh, R., Bansal, A., Ali, I.H., Younas, M., Alanazi, A.K., and Lin, Y. (2023c). Corrosion and bacterial growth mitigation in the desalination plant by imidazolium based ionic liquid: experimental, surface and molecular docking analysis. J. Environ. Chem. Eng. 11: 109313, https://doi.org/10.1016/j.jece.2023.109313.Suche in Google Scholar
Singh, A., Ansari, K.R., Ali, I.H., Ibrahimi, B.E., Alanazi, A.K., Younas, M., Singh, T., and Lin, Y. (2024a). Synergistic mixture of Capsicum annuum fruit extract/KI as an efficient inhibitor for the corrosion of P110 steel in 15% HCl solution under hydrodynamic condition. Zeitschrift für Physikalische Chemie 238: 339–361, https://doi.org/10.1515/zpch-2023-0367.Suche in Google Scholar
Singh, A., Ansari, K.R., Ali, I.H., Younas, M., Alanazi, A.K., and Lin, Y. (2024b). Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study. Zeitschrift für Physikalische Chemie, 238: 1451–1473. https://doi.org/10.1515/zpch-2023-0377.Suche in Google Scholar
Stern, M. and Geary, A.L. (1957). Electrochemical polarization: I. A theoretical analysis of the shape of polarization curves. J. Electrochem. Soc. 104: 56.10.1149/1.2428496Suche in Google Scholar
Subbiah, K., Lee, H.-S., Al-Hadeethi, M.R., Park, T., and Lgaz, H. (2024). Unraveling the anti-corrosion mechanisms of a novel hydrazone derivative on steel in contaminated concrete pore solutions: an integrated study. J. Adv. Res. 58: 211–228, https://doi.org/10.1016/j.jare.2023.08.016.Suche in Google Scholar PubMed PubMed Central
Temesghen, W. and Sherwood, P. (2002). Analytical utility of valence band X-ray photoelectron spectroscopy of iron and its oxides, with spectral interpretation by cluster and band structure calculations. Anal. Bioanal. Chem. 373: 601–608, https://doi.org/10.1007/s00216-002-1362-3.Suche in Google Scholar PubMed
Wang, H., Qian, D., Wang, F., Dong, Z., and Chen, J. (2024). Predictive mechanical property and fracture behavior in high-carbon steel containing high-density carbides via artificial RVE modeling. Mater. Des. 247: 113383, https://doi.org/10.1016/j.matdes.2024.113383.Suche in Google Scholar
Wang, X., Yang, H., and Wang, F. (2011). An investigation of benzimidazole derivative as corrosion inhibitor for mild steel in different concentration HCl solutions. Corros. Sci. 53: 113–121, https://doi.org/10.1016/j.corsci.2010.09.029.Suche in Google Scholar
Wu, Y., Wu, H., Zhao, Y., Jiang, G., Shi, J., Guo, C., Liu, P., and Jin, Z. (2023). Metastable structures with composition fluctuation in cuprate superconducting films grown by transient liquid-phase assisted ultra-fast heteroepitaxy. Mat. Today Nano 24: 100429, https://doi.org/10.1016/j.mtnano.2023.100429.Suche in Google Scholar
Xu, X., Singh, A., Sun, Z., Ansari, K., and Lin, Y. (2017). Theoretical, thermodynamic and electrochemical analysis of biotin drug as an impending corrosion inhibitor for mild steel in 15% hydrochloric acid. Royal Soc. Open Sci. 4: 170933, https://doi.org/10.1098/rsos.170933.Suche in Google Scholar PubMed PubMed Central
Zarrouk, A., Hammouti, B., Lakhlifi, T., Traisnel, M., Vezin, H., and Bentiss, F. (2015). New 1H-pyrrole-2, 5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium: electrochemical, XPS and DFT studies. Corros. Sci. 90: 572–584, https://doi.org/10.1016/j.corsci.2014.10.052.Suche in Google Scholar
Zhang, Y., Wang, Z., Huang, S., Liu, H., and Yan, Y. (2024). Electrochemical behavior and passivation film characterization of TiZrHfNb multi-principal element alloys in NaCl-containing solution. Corros. Sci. 235: 112185, https://doi.org/10.1016/j.corsci.2024.112185.Suche in Google Scholar
Zhao, R., Li, C., and Guan, X. (2024). Advances in modeling surface chloride concentrations in concrete serving in the marine environment: a mini review. Buildings 14: 1879, https://doi.org/10.3390/buildings14061879.Suche in Google Scholar
Zheng, Z., Hu, J., Eliaz, N., Zhou, L., Yuan, X., and Zhong, X. (2022). Mercaptopropionic acid-modified oleic imidazoline as a highly efficient corrosion inhibitor for carbon steel in CO2-saturated formation water. Corros. Sci. 194: 109930, https://doi.org/10.1016/j.corsci.2021.109930.Suche in Google Scholar
Zhou, B.-N., Blaskò, G., and Cordell, G.A. (1988). Alternanthin, a C-glycosylated flavonoid from Alternanthera philoxeroides. Phytochemistry 27: 3633–3636, https://doi.org/10.1016/0031-9422(88)80781-7.Suche in Google Scholar
Supplementary Material
This article contains supplementary material (https://doi.org/10.1515/corrrev-2024-0072).
© 2024 Walter de Gruyter GmbH, Berlin/Boston
