Chemical Actinometry (IUPAC Technical Report)
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Chemical Actinometry (IUPAC Technical Report)
(IUPAC Technical Report)
H.J. Kuhn, S.E. Braslavsky, and R. Schmidt
Pure and Applied Chemistry
Vol. 76, No. 12, pp. 2105-2146 (2004)
This document updates the first version of the IUPAC technical report on “Chemical Actinometers” published in Pure and Applied Chemistry, 61, 187–210 (1989). Since then, some methods have been improved, procedures have been modified, and new substances have been proposed as chemical actinometers. An actinometer is a chemical system or a physical device by which the number of photons in a beam absorbed into the defined space of a chemical reactor can be determined integrally or per time. This compilation includes chemical actinometers for the gas, solid, microheterogeneous, and liquid phases, as well as for use with pulsed lasers for the measurement of transient absorbances, including the quantum yield of phototransformation. The literature for each of the actinometers is included as well. The actinometers listed are for use in the wavelength range from UV to the red region of the spectrum. A set of recommended standard procedures is also given. Advantages and disadvantages are discussed regarding the use of chemical actinometers vs. electronic devices for the measurement of the number of photons absorbed. Procedures for the absolute measurement of incident photon flux by means of photodiodes are also discussed.
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- Masthead
- From the Editor
- Contents
- Welcome to Beijing!
- The Evolution of an Ethic and a Commitment
- Linus Pauling
- Citation Highlights 1998–2003
- How Can IUPAC Facilitate International Collaborative Research?
- COCI Campaigns for the Company Associates Program
- Piet Steyn Wins One of South Africa’s Highest Science Awards
- First ICSU Regional Meeting for Africa
- Standardization of Analytical Approaches and Analytical Capacity-Building in Africa
- Young Ambassadors for Chemistry
- IUPAC Seeks Your Comments
- Definition of Terms Related to Polymer Blends, Composites, and Multiphase Polymeric Materials (IUPAC Recommendations 2004)
- Characterization of Polyamides 6, 11, and 12. Determination of Molecular Weight by Size Exclusion Chromatography (IUPAC Technical Report)
- Rheological Properties and Associated Structural Characteristics of Some Aromatic Polycondensates Including Liquid-Crystalline Polyesters and Cellulose Derivatives (IUPAC Technical Report)
- Name and Symbol of the Element with Atomic Number 111 (IUPAC Recommendations 2004)
- Chemical Actinometry (IUPAC Technical Report)
- Electrochemistry at the Interface between Two Immiscible Electrolyte Solutions (IUPAC Technical Report)
- Special Topic Articles Featuring the 2004 Winners of the IUPAC Prize for Young Chemists
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