Non-Metals in Liquid Alkali Metals
New Books and Publications
Non-Metals in Liquid Alkali Metals
Hans Ulrich Borgstedt and Cezary Guminski
IUPAC-NIST Solubility Data Series. 75. Journal of Physical and Chemical Reference Data, Vol. 30, No. 4, pp. 835—1158, 2001.
All available solubility data of nonmetallic elements and some of their compounds in the five liquid alkali metal solvents (Li, Na, K, Rb, and Cs) are collected and compiled. Original publications with reliable data and information on the methods used to generate them are reported in individual compilations. When numerical data are not given in a publication, the data are often read out from figures and converted into numerical data by the compilers. The precision of this procedure is indicated in the compilations under estimated error. Evaluated solubility data are tabulated at the end of the critical evaluations: if there is agreement of at least two independent studies within the experimental error, the solubility values are assigned to the "recommended" category. Values are assigned as "tentative" if only one reliable result was reported, or if the mean value of two or more reliable studies was outside the error limits. In the tabulation, three, two, or one significant figures are assigned for respective precisions that are better than ±1% and ±10% and worse than ±10%. If necessary, the solubilities are recalculated into mol %.
The completeness of this investigation of the literature has been confirmed and extended by studying several reviews dealing with the solution chemistry of substances in the alkali metals. Solubility data are sometimes measured under parameters, which are not standard conditions of such measurements. Frequently measurements are performed under constrained pressure. The solubility of noble gases or other gases, which do not form compounds with the alkali metals, depends on the gas pressures. This dependency is documented in the data sheets.
© 2014 by Walter de Gruyter GmbH & Co.
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Articles in the same Issue
- Contents
- IUPAC and You
- IOCD: 20 Years of Building Capacity in Chemistry in Developing Countries
- Validated Analytical Methods–AOAC’s Experience Over 100 Years
- Small-Scale Chemistry
- The World Chemistry Congress 2001 and the Young Scientist Awards
- Relocating to Cyberspace
- Erick Carreira Receives the Thieme–IUPAC Prize
- Roger Atkinson Receives the ACS Award for Creative Advances in Environmental Science and Technology
- Standard Potentials of Radicals
- Glossary for Toxicokinetics of Chemicals
- Recommendation on the Use of Countercurrent Chromotography in Analytical Chemistry
- Nomenclature for Rotaxanes, Catenanes, and Macromolecular Rotaxanes
- IUPAC Seeks Your Comments
- Thermochemistry of Chemical Reactions: Terminology, Symbols, and Experimental Methods for the Determination of Bond Energies
- Guidelines for the Representation of Pulse Sequences for Solution-State Nuclear Magnetic Resonance Spectrometry (IUPAC Recommendations 2001)
- JCAMP-DX. A Standard Format for the Exchange of Ion Mobility Spectrometry Data (IUPAC Recommendations 2001)
- Molality-Based Primary Standards of Electrolytic Conductivity (IUPAC Technical Report)
- NMR Nomenclature. Nuclear Spin Properties and Conventions for Chemical Shifts (IUPAC Recommendations 2001)
- Electrochemistry and Interfacial Chemistry for the Environment
- Handbook of Pharmaceutical Salts: Properties, Selection, and Use
- Green Chemistry–the Japanese translation of the special topic issue of Pure and Applied Chemistry (Vol. 72, No. 7, 2000)
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- Heat Capacity of Liquids: Critical Review and Recommended Values
- Pesticide Formulation and Application Systems: A New Century For Agricultural Formulations
- Advanced Materials
- Solution Chemistry
- Organometallic Chemistry Directed Towards Organic Synthesis
- 35th International Conference on Coordination Chemistry (35-ICCC) 21–26 July 2002, Heidelberg, Germany
- The Second Pan-European Younger Chemists’ Conference 30 September–2 October 2002, Heidelberg, Germany
- 10th International Symposium on Macromolecule Metal Complexes (MMC-X) 20–24 May 2003, Moscow, Russia
- Plutonium Futures–The Science 2003 6–10 July 2003, Albuquerque, New Mexico, USA
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