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Degradation of polyethylene glycol and hemicellulose in the Vasa
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Gunnar Almkvist
Published/Copyright:
December 5, 2007
Abstract
Mass spectrometric analysis of aqueous wood extracts from the Swedish warship Vasa reveals a serious chemical condition in the depth of the wood. The surface is less affected. Polyethylene glycol, used as conservation agent, is affected and partly degraded, and low-molecular fragments from hemicellulose are found at sites with high iron content and low pH. These findings imply a catalytic oxidative process and acidic hydrolysis in the wood, which contributes to a new picture of the challenge of long-term preservation of the Vasa.
Keywords: catalytic oxidation; hemicelluloses; hydrolysis; matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF); polyethylene glycol; Vasa; wood degradation
Received: 2007-3-21
Accepted: 2007-10-1
Published Online: 2007-12-05
Published in Print: 2008-1-1
©2008 by Walter de Gruyter Berlin New York
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Keywords for this article
catalytic oxidation;
hemicelluloses;
hydrolysis;
matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF);
polyethylene glycol;
Vasa;
wood degradation
Articles in the same Issue
- Meetings
- Evaluation of Eucalyptus grandis Hill ex Maiden biopulping with Ceriporiopsis subvermispora under non-aseptic conditions
- Paper dry strength improvement by xyloglucan addition: Wet-end application, spray coating and synergism with borate
- A new and facile method for isolation of lignin from wood based on complete wood dissolution
- Isolation and characterization of lignins from Eucalyptus grandis Hill ex Maiden and Eucalyptus globulus Labill. by enzymatic mild acidolysis (EMAL)
- Fractionation and characterization of xylan rich extracts from birch
- Polyoxometalate (POM) oxidation of lignin model compounds
- Pyrolytic cleavage mechanisms of lignin-ether linkages: A study on p-substituted dimers and trimers
- Polysaccharide degradation in waterlogged oak wood from the ancient warship Vasa
- Degradation of polyethylene glycol and hemicellulose in the Vasa
- Selection criteria of Eucalyptus globulus Labill. for production of chemithermomechanical pulps (CTMP)
- The effect of (induced) dislocations on the tensile properties of individual Norway spruce fibres
- Mode I and Mode II fracture toughness of densified Sitka spruce fabricated in an airtight atmosphere with high-temperature steam
- Characteristic properties of embedding strength for the nailing of the gonfolo rose (Qualea rosea Aubl.)
- Adhesive penetration of wood cell walls investigated by scanning thermal microscopy (SThM)
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- Decay resistance of wood treated with amino-silicone compounds
- Hydrothermal treatment of mixed preservative-treated wood waste
- Variation of tracheid length within annual rings of Scots pine and Norway spruce
