Changes in the fiber wall during refining of bleached pine kraft pulp
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C. Laine
Abstract
The effect of refining on the fiber wall was studied for bleached kraft pulp fractions from pine first thinnings and pine sawmill chips. Hydrocyclone fractionation of both pulps produced fractions enriched in earlywood and latewood fibers. Some external fibrillation but no changes in fiber wall thickness were observed for the thin-walled earlywood fibers during refining. Refining the thick-walled latewood fibers led to extensive external fibrillation and a decrease in fiber wall thickness. The pore structure of the fiber wall opened up during refining for all pulp fractions. Earlywood fibers were more porous than latewood fibers, and fibers from first thinnings more porous than those from sawmill chips. The earlywood fibers from first thinnings had more large pores than the other fiber fractions. In the region of the smaller pores, the pore volume did not change significantly with refining, whereas in the region of the larger pores it increased markedly. In all the fractions investigated, specific hydrolytic enzymes hydrolyzed cellulose more easily after refining. This is an indication of an increase in cellulose surface area and/or disordering of cellulose as a result of refining, probably due to local disorder of the cellulose in the fibril aggregates. Bonding developed most strongly for the earlywood fiber fraction from first thinnings. This is concluded to be due to a combination of fiber dimensions and fiber wall porosity.
Copyright © 2004 by Walter de Gruyter GmbH & Co. KG
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Articles in the same Issue
- The Bremen Cog of 1380 – An electron microscopic study of its degraded wood before and after stabilization with PEG
- Ultrastructure of iodine treated wood
- Effects of refining on the fibre structure of kraft pulps as revealed by FE-SEM and TEM: Influence of alkaline degradation
- Changes in the fiber wall during refining of bleached pine kraft pulp
- An unusual formation of tension wood in a natural forest Acacia sp.
- Changes in the surface properties of wood due to sanding
- Use of near infrared spectroscopy to predict the mechanical properties of six softwoods
- The creep of wood destabilized by change in moisture content. Part 1: The creep behaviors of wood during and immediately after drying
- Modeling the process of desorption of water in oak (Quercus robur L.) wood
- Moisture adsorption thermodynamics of wood from fractal-geometry approach
- Application of ionic liquids for electrostatic control in wood
- Ionic liquids in wood preservation
- New bis-quaternary ammonium and bis-imidazolium chloride wood preservatives
- Environmentally-benign wood preservatives based on an organic biocide:antioxidant combination: Ground-contact efficacy ratings and BHT depletion after four years of exposure
- Production of 2,5-dimethoxyhydroquinone by the brown-rot fungus Serpula lacrymans to drive extracellular Fenton reaction
- Fungal decay resistance of wood reacted with phosphorus pentoxide-amine system
- The use of organo alkoxysilane coupling agents for wood preservation
- Phenolic extractives from wood of birch (Betula pendula)
- Stability of arylglycerols during alkaline cooking
