The Chemical Nature of Kiln Brown Stain in Radiata Pine
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Armando G. McDonald
Summary
This paper presents results of a study on the chemical nature of kiln brown stain (KBS) that develops in kiln dried radiata pine (Pinus radiata D. Don) sapwood. KBS is a chocolate brown discolouration which develops approximately 0.5 mm under the timber surface. Stain free radiata pine was achieved during drying trials on “green” radiata pine sapwood which had been treated to extensive cold and hot water extraction. Differences in chemical composition between the sap and hot water extract were observed. Chemical analyses (of the water-soluble extracts) by a combination of chromatographic and spectroscopic techniques, demonstrated that carbohydrates, cyclitols, amino acids, protein, and phenolics were the main compound classes present. The presence of reducing sugars (glucose and fructose) and amino acids (glutamic acid) in the sap and hot water extracts support the theory that Amadori-Maillard type reactions significantly contribute to the formation of colour in KBS. Furthermore, lignin was also detected and is suspected to contribute to KBS formation. The relative contributions of colour formation to KBS intensity from either phenolics or Maillard-Amadori mechanisms is unknown.
Copyright © 2000 by Walter de Gruyter GmbH & Co. KG
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Artikel in diesem Heft
- Identification of Indoor Rot Fungi by Taxon-Specific Priming Polymerase Chain Reaction
- Characteristics of Spruce [Picea abies (L.) Karst] Latewood Formed under Abnormally Low Temperatures
- The Chemical Nature of Kiln Brown Stain in Radiata Pine
- Microdistribution of Some Copper and Zinc Containing Waterborne and Organic Solvent Wood Preservatives in Spruce Wood Cell Walls
- X-Ray Diffraction as an Analytical Method in Wood Preservatives
- Modifications of Hybrid Walnut (Juglans nigra 23 x Juglans regia) Wood Colour and Phenolic Composition Under Various Steaming Conditions
- Incorporation of 13C-Labeled Coniferyl Alcohol into Developing Ginkgo biloba L. Lignin Revealed by Analytical Pyrolysis and CuO Oxidation in Combination with Isotope Ratio Monitoring-Gas Chromatography-Mass Spectrometry
- Atomic Force Microscopy (AFM) Investigation of Langmuir-Blodgett (LB) Films of Sugar Cane Bagasse Lignin
- Comparison of Acetic Acid Lignin with Milled Wood and Alkaline Lignins from Wheat Straw
- Monitoring of Lignin and Hemicelluloses in Spent Cooking Liquor during Kraft Delignification
- Preparation of Wood with Thermoplastic Properties, Part 1. Classical Synthesis
- Preparation of Wood with Thermoplastic Properties, Part 2. Simplified Technologies
- The Effect of Hydrostatic Pressure on Physical Properties and Microstructure of Spruce and Cherry
- Application of Liquefied Wood to a New Resin System—Synthesis and Properties of Liquefied Wood/Epoxy Resins
- Lab-Scale Synthesis of Isotopically Labeled Formaldehyde for the Production of Formaldehyde-Based Wood Adhesives
- Confirmation of the Presence of Formaldehyde and N-(Methylene)morpholinium Cations as Reactive Species in the Cellulose/NMMO/Water System by Trapping Reactions
- Compressive Creep of Wood under High Temperature Steam
- Literature Reports
