4 Homogenous catalysis using ZIF-8
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Muhammad Pervaiz
Abstract
The studies about ZIFs indicate that highly commendable porosity and topology are factors that make them feasible for catalytic reactions. ZIF-8 structure can be studied by different analytical techniques. ZIFs have resemblance with topology of Si-O-Si structure present in zeolites. SEM forms various micrographs that had assisted us in characterization of ZIF-8. Afterwards, it had made possible the use of ZIF-8 commercially as a catalyst. ZIF-8 samples were prepared in different solvents like methanol (MeOH), dimethyl formamide (DMF), and dimethylsulfoxide (DMSO). DMSO gave well dispersed frameworks of ZIF with enhanced porosity that was further used for CO2 adsorption. Knoevenagel condensation is also aided by ZIF-8 catalyst, as supported by various characterization techniques such as XRD, SEM, TEM, TGA, etc.
Abstract
The studies about ZIFs indicate that highly commendable porosity and topology are factors that make them feasible for catalytic reactions. ZIF-8 structure can be studied by different analytical techniques. ZIFs have resemblance with topology of Si-O-Si structure present in zeolites. SEM forms various micrographs that had assisted us in characterization of ZIF-8. Afterwards, it had made possible the use of ZIF-8 commercially as a catalyst. ZIF-8 samples were prepared in different solvents like methanol (MeOH), dimethyl formamide (DMF), and dimethylsulfoxide (DMSO). DMSO gave well dispersed frameworks of ZIF with enhanced porosity that was further used for CO2 adsorption. Knoevenagel condensation is also aided by ZIF-8 catalyst, as supported by various characterization techniques such as XRD, SEM, TEM, TGA, etc.
Chapters in this book
- Frontmatter I
- Acknowledgments V
- Contents VII
- List of contributors IX
- 1 ZIF-8: An overview 1
- 2 ZIF-8 spectacular properties 19
- 3 Heterogeneous catalysis and ZIF-8 33
- 4 Homogenous catalysis using ZIF-8 51
- 5 Wastewater treatment: An overview 59
- 6 Removal of heavy metals using ZIF 8 79
- 7 Light-driven photocatalysis for dyes using ZIF-8 base composite materials 97
- 8 Recent trends in ZIF-8-based composite materials for the removal of ciprofloxacin 111
- 9 Future prospects for ZIF-8-based composite material for decontamination of water 137
- Index 155
Chapters in this book
- Frontmatter I
- Acknowledgments V
- Contents VII
- List of contributors IX
- 1 ZIF-8: An overview 1
- 2 ZIF-8 spectacular properties 19
- 3 Heterogeneous catalysis and ZIF-8 33
- 4 Homogenous catalysis using ZIF-8 51
- 5 Wastewater treatment: An overview 59
- 6 Removal of heavy metals using ZIF 8 79
- 7 Light-driven photocatalysis for dyes using ZIF-8 base composite materials 97
- 8 Recent trends in ZIF-8-based composite materials for the removal of ciprofloxacin 111
- 9 Future prospects for ZIF-8-based composite material for decontamination of water 137
- Index 155
