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5 Photocatalytic degradation of organic contaminants in wastewater treatment

  • Getu Kassegn Weldegebrieal and Assefu Kassegn Sibhatu
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Environmental Microbiology
This chapter is in the book Environmental Microbiology

Abstract

The expansion of urbanization and industrialization have primarily given rise to the contamination of the water body via direct or indirect routes. Wastewater treatment is pivotal to avoid its potential deleterious impact on animals and the environment and minimize clean water shortage. Effective removal of pollutants in wastewater using conventional treatment approaches such as adsorption, membrane filtration, flocculation, and flotation is often difficult to achieve due to the complex nature of wastewater matrix. These approaches have drawbacks such as incomplete pollutant removal and sludge formation, and does not involve degradation. Advanced oxidation processes (AOPs) are promising technologies for degrading refractory organic contaminants, removing toxic heavy metal ions and microorganisms from water and wastewater. Heterogeneous photocatalysis is one of the AOPs involving the acceleration of the rate of chemical reactions in the presence of semiconductor catalyst, radiation, and pollutant. It has such merits as high removal efficiency, low cost, no sludge formation, environmental benignity, and easiness to integrate it with other treatment methods. However, its performance is influenced by factors such as nature and concentration of pollutants, catalyst loading, pH, presence of interferents, and presence of oxidants, which are discussed in this chapter one by one based on recent reports in the literature.

Abstract

The expansion of urbanization and industrialization have primarily given rise to the contamination of the water body via direct or indirect routes. Wastewater treatment is pivotal to avoid its potential deleterious impact on animals and the environment and minimize clean water shortage. Effective removal of pollutants in wastewater using conventional treatment approaches such as adsorption, membrane filtration, flocculation, and flotation is often difficult to achieve due to the complex nature of wastewater matrix. These approaches have drawbacks such as incomplete pollutant removal and sludge formation, and does not involve degradation. Advanced oxidation processes (AOPs) are promising technologies for degrading refractory organic contaminants, removing toxic heavy metal ions and microorganisms from water and wastewater. Heterogeneous photocatalysis is one of the AOPs involving the acceleration of the rate of chemical reactions in the presence of semiconductor catalyst, radiation, and pollutant. It has such merits as high removal efficiency, low cost, no sludge formation, environmental benignity, and easiness to integrate it with other treatment methods. However, its performance is influenced by factors such as nature and concentration of pollutants, catalyst loading, pH, presence of interferents, and presence of oxidants, which are discussed in this chapter one by one based on recent reports in the literature.

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