Chapter 3 Elastomer blend and compatibility: a flow visualisation study
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Dipak Kumar Setua
Abstract
An experimental study on the influence of several potential compatibilising agents on mixing of binary blends of (i) nitrile rubber (NBR) and ethylene-propylene copolymer (EPM), (ii) polyisoprene (IR) and EPM, and (iii) epoxidised natural rubber (ENR) and EPM have been made. The compatibilising agents used were different types of elastomers, for example, (a) chlorinated polyethylene (CM), (b) chlorosulfonated polyethylene (CSM), (c) chlorinated isobutylene isoprene copolymer (CIIR), (d) transpolyoctenylene (TOR), and (e) polybutadiene (BR). These compatibilisers have varied levels of relative polarity, solubility parameter, and chemical compositions. Addition of a suitable compatibiliser, in a small concentration, in different binary elastomer blends was found to increase the rate of mixing with a corresponding reduction of the blend homogenisation time. Further, the addition of an effective compatibiliser generates finer phase morphology with respect to dispersion and distribution as well as a substantial reduction of size of final dispersed particles in the matrix phase.
Abstract
An experimental study on the influence of several potential compatibilising agents on mixing of binary blends of (i) nitrile rubber (NBR) and ethylene-propylene copolymer (EPM), (ii) polyisoprene (IR) and EPM, and (iii) epoxidised natural rubber (ENR) and EPM have been made. The compatibilising agents used were different types of elastomers, for example, (a) chlorinated polyethylene (CM), (b) chlorosulfonated polyethylene (CSM), (c) chlorinated isobutylene isoprene copolymer (CIIR), (d) transpolyoctenylene (TOR), and (e) polybutadiene (BR). These compatibilisers have varied levels of relative polarity, solubility parameter, and chemical compositions. Addition of a suitable compatibiliser, in a small concentration, in different binary elastomer blends was found to increase the rate of mixing with a corresponding reduction of the blend homogenisation time. Further, the addition of an effective compatibiliser generates finer phase morphology with respect to dispersion and distribution as well as a substantial reduction of size of final dispersed particles in the matrix phase.
Kapitel in diesem Buch
- Frontmatter I
- Contents V
- Contributing authors VII
- Chapter 1 Fundamentals of rubber compounding 1
- Chapter 2 Carbon black morphology and its application in elastomer and polymer matrix 53
- Chapter 3 Elastomer blend and compatibility: a flow visualisation study 121
- Chapter 4 Use of graphene in rubber nanocomposite, its processability, and commercial advantages 151
- Chapter 5 Transmission rubber V-belt technology 197
- Chapter 6 The Science of Rubber Conveyor Belt: A Comprehensive Guide’ 229
- Chapter 7 Reverse engineering: a tool for the chemical composition analysis of finished rubber products 279
- Chapter 8 Thermal and mechanical analysis study of different rubber applications 323
- Chapter 9 Devulcanisation of discarded rubber: a value-added disposal method of waste rubber products 365
- Chapter 10 Cost of quality in rubber processing 445
- Chapter 11 Lean productivity and cost optimisation for rubber processing industries 469
- Index 501
Kapitel in diesem Buch
- Frontmatter I
- Contents V
- Contributing authors VII
- Chapter 1 Fundamentals of rubber compounding 1
- Chapter 2 Carbon black morphology and its application in elastomer and polymer matrix 53
- Chapter 3 Elastomer blend and compatibility: a flow visualisation study 121
- Chapter 4 Use of graphene in rubber nanocomposite, its processability, and commercial advantages 151
- Chapter 5 Transmission rubber V-belt technology 197
- Chapter 6 The Science of Rubber Conveyor Belt: A Comprehensive Guide’ 229
- Chapter 7 Reverse engineering: a tool for the chemical composition analysis of finished rubber products 279
- Chapter 8 Thermal and mechanical analysis study of different rubber applications 323
- Chapter 9 Devulcanisation of discarded rubber: a value-added disposal method of waste rubber products 365
- Chapter 10 Cost of quality in rubber processing 445
- Chapter 11 Lean productivity and cost optimisation for rubber processing industries 469
- Index 501
