8. Reagents that Contain Se-H or Te-H Bonds
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Peter C. Ho
Abstract
Species that contain bonds between hydrogen and selenium or tellurium have a characteristic high reactivity, which can be harnessed in the synthesis of valuable organic compounds. This overview includes the synthesis of dihydrides, alkali metal hydrochalcogenides, chalcogenols, chalcogenocarboxylic and chalcogenocarbamic acids, and their application in reactions of reduction, addition to unsaturated compounds, and nucleophilic substitution.
Abstract
Species that contain bonds between hydrogen and selenium or tellurium have a characteristic high reactivity, which can be harnessed in the synthesis of valuable organic compounds. This overview includes the synthesis of dihydrides, alkali metal hydrochalcogenides, chalcogenols, chalcogenocarboxylic and chalcogenocarbamic acids, and their application in reactions of reduction, addition to unsaturated compounds, and nucleophilic substitution.
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
