5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications
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Guoxiong Hua
Abstract
Organic selenium- and tellurium-phosphorus compounds have found wide application as reagents in synthetic inorganic and organic chemistry, such as oxygen/chalcogen exchange, oxidation/reduction, nucleophilic/electrophilic substitution, nucleophilic addition, free radical addition, Diels-Alder reaction, cycloadditions, coordination, and so on. This chapter covers the main classes of phosphorus-selenium/tellurium reagents, including binary phosphorus-selenium/ tellurium species, organophosphorus(III)-selenium/tellurium compounds, phosphorus( V)-selenides/tellurides, diselenophosphinates/ditellurophopshinates, diselenaphosphetane diselenides, Woollins’ reagent, phosphorus-selenium/tellurium amides, and imides. Given the huge amount of literature up to mid-2017, this overview is inevitably selective and will focus particularly on their synthesis, reactivity, and applications in synthetic and coordination chemistry.
Abstract
Organic selenium- and tellurium-phosphorus compounds have found wide application as reagents in synthetic inorganic and organic chemistry, such as oxygen/chalcogen exchange, oxidation/reduction, nucleophilic/electrophilic substitution, nucleophilic addition, free radical addition, Diels-Alder reaction, cycloadditions, coordination, and so on. This chapter covers the main classes of phosphorus-selenium/tellurium reagents, including binary phosphorus-selenium/ tellurium species, organophosphorus(III)-selenium/tellurium compounds, phosphorus( V)-selenides/tellurides, diselenophosphinates/ditellurophopshinates, diselenaphosphetane diselenides, Woollins’ reagent, phosphorus-selenium/tellurium amides, and imides. Given the huge amount of literature up to mid-2017, this overview is inevitably selective and will focus particularly on their synthesis, reactivity, and applications in synthetic and coordination chemistry.
Chapters in this book
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
Chapters in this book
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
