Volume 5, Issue 1 -

Magnetoelectric coupling in multiferroic materials opens new routes to control the propagation of light. The new effects arise due to dynamic magnetoelectric susceptibility that cross-couples the electric and magnetic fields of light and modifies the solutions of Maxwell equations in media. In this paper, two major effects will be considered in detail: optical activity and asymmetric propagation. In case of optical activity the polarization plane of the input radiation rotates by an angle proportional to the magnetoelectric susceptibility. The asymmetric propagation is a counter-intuitive phenomenon and it represents different transmission coefficients for forward and backward directions. Both effects are especially strong close to resonance frequencies of electromagnons, i. e. excitations in multiferroic materials that reveal simultaneous electric and magnetic character.

Raman spectroscopy and its variants allow for the investigation of a wide range of biological and biomedical samples, i. e. tissue sections, single cells and small molecules. The obtained information is on a molecular level. By making use of databases and chemometrical approaches, the chemical composition of complex samples can also be defined. The measurement procedure is straight forward, however most often sample preparation protocols must be implemented. While pure samples, such as high purity powders or highly concentrated chemicals in aqueous solutions, can be directly measured without any prior sample purification step, samples of biological origin, such as tissue sections, pathogens in suspension or biofluids, food and beverages often require pre-processing steps prior to Raman measurements. In this book chapter, different strategies for handling and processing various sample matrices for a subsequent Raman microspectroscopic analysis were introduced illustrating the high potential of this promising technique for life science and medical applications. The presented methods range from standalone techniques, such as filtration, centrifugation or immunocapture to innovative platform approaches which will be exemplary addressed. Therefore, the reader will be introduced to methods that will simplify the complexity of the matrix in which the targeted molecular species are present allowing direct Raman measurements with bench top or portable setups.

In this article, we focus on (1) type-II multiferroics driven by spiral spin orderings and (2) magnetoelectric couplings in multiferroic skyrmion-hosting materials. We present both phenomenological understanding and microscopic mechanisms for spiral spin state, which is one of the essential starting points for type-II multiferroics and magnetic skyrmions. Two distinct mechanisms of spiral spin states (frustration and Dzyaloshinskii–Moriya [DM] interaction) are discussed in the context of the lattice symmetry. We also discuss the spin-induced ferroelectricity on the basis of the symmetry and microscopic atomic configurations. We compare two well-known microscopic models: the generalized inverse DM mechanism and the metal-ligand d - p hybridization mechanism. As a test for these models, we summarize the multiferroic properties of a family of triangular-lattice antiferromagnets. We also give a brief review of the magnetic skyrmions. Three types of known skyrmion-hosting materials with multiferroicity are discussed from the view point of crystal structure, magnetism, and origins of the magnetoelectric couplings. For exploration of new skyrmion-hosting materials, we also discuss the theoretical models for stabilizing skyrmions by magnetic frustration in centrosymmetric system. Several basic ideas for material design are given, which are successfully demonstrated by the recent experimental evidences for the skyrmion formation in centrosymmetric frustrated magnets.

Each year thousands of wildland fires blaze across the United States causing secondary (“smoke”) damage to numerous businesses and personal property. Currently there are no specific industry standards or guidelines for determining wildfire combustion residues. Remediation decisions often rely on anecdotal evidence from occupants. A variety of particulate methods are used to assess surface contamination but there are few methods for evaluating organic chemical residues that encompass the wide range of chemical classes produced during wildland fires. A new method was developed employing a thermal desorption gas chromatography mass spectrometry (TD-GCMS). TD-GCMS using novel sorbent beds decreases the sample preparation substantially and enables sampling of bulk materials by off-gassing. Furthermore, the method developed is specific to wildland fire events. Results from a simulated wildland fire event are also provided.

Raman spectroscopy has undercome a major development during the last decades, making it more and more popular. One of the reason is that the instrumentation has become more accessible, by making the Raman microscopes much more affordable, reliable and user-friendly. Although the fundamental design has not really changed since the origins, it is important to know what the different components are made of and what is their purpose. Is that sense this chapter about the Optics of the Raman microscope will help to understand how the instrument works and what are the specifications and the useful characteristics.

The “greening” of silicon chemistry is fundamentally important for the future of the field. Traditional methods used to make silicon-based materials rely on carbon rich processes that are highly energy intensive, cause pollution, and are unsustainable. Researchers have taken up the challenge of developing new chemistries to circumvent the difficulties associated with traditional silicon material synthesis. Most of this work has been in the conversion of the “green” carbon neutral biogenic silica source rice hull ash (RHA, ~85 % silica) into useful silicon building blocks such as silica’s, silicon, and alkoxysilanes by using the inherently higher surface area and reactivity of RHA to sidestep the low reactivity of mined silica sources. This is a review of the work that has been done in the area of developing more environmentally benign methods for the synthesis and use of silicon containing materials to eliminate the negative impact on the environment.

Magnetic skyrmions, nanoscopic spin vortices carrying a quantized topological number in chiral-lattice magnets, are recently attracting great research interest. Although magnetic skyrmions had been observed only in metallic chiral-lattice magnets such as B20 alloys in the early stage of the research, their realization was discovered in 2012 also in an insulating chiral-lattice magnet Cu2OSeO3$\textrm{Cu}_2\textrm{OSeO}_3$. A characteristic of the insulating skyrmions is that they can host multiferroicity, that is, the noncollinear magnetization alignment of skyrmion induces electric polarizations in insulators with a help of the relativistic spin-orbit interaction. It was experimentally confirmed that the skyrmion phase in Cu2OSeO3$\textrm{Cu}_2\textrm{OSeO}_3$ is indeed accompanied by the spin-induced ferroelectricity. The resulting strong magnetoelectric coupling between magnetizations and electric polarizations can provide us with a means to manipulate and activate magnetic skyrmions by application of electric fields. This is in sharp contrast to skyrmions in metallic systems, which are driven through injection of electric currents. The magnetoelectric phenomena specific to the skyrmion-based multiferroics are attracting intensive research interest, and, in particular, those in dynamical regime are widely recognized as an issue of vital importance because their understanding is crucial both for fundamental science and for technical applications. In this article, we review recent studies on multiferroic properties and dynamical magnetoelectric phenomena of magnetic skyrmions in insulating chiral-lattice magnet Cu2OSeO3$\textrm{Cu}_2\textrm{OSeO}_3$. It is argued that the multiferroic skyrmions show unique resonant excitation modes of coupled magnetizations and polarizations, so-called electromagnon excitations, which can be activated both magnetically with a microwave magnetic field and electrically with a microwave electric field. The interference between these two activation processes gives rise to peculiar phenomena in the gigahertz regime. As its representative example, we discuss a recent theoretical prediction of unprecedentedly large nonreciprocal directional dichroism of microwaves in the skyrmion phase of Cu2OSeO3$\textrm{Cu}_2\textrm{OSeO}_3$. This phenomenon can be regarded as a one-way window effect on microwaves, that is, the extent of microwave absorption changes significantly when its incident direction is reversed. This dramatic effect was indeed observed by subsequent experiments. These studies demonstrated that the multiferroic skyrmions can be a promising building block for microwave devices.