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Reaction of Copper(I) Nitrotetrazolate (DBX-1) with Sodium m-Periodate
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Thomas M. Klapötke
,
Davin G. Piercey
Published/Copyright:
June 2, 2014
The reaction of the lead-free primary explosive copper(I) 5-nitrotetrazolate (DBX-1) with sodium m-periodate yields a green precipitate of copper(II) iodate. The energetic properties of the copper(I) nitrotetrazolate starting material are lost since the nitrotetrazolate is removed into the aqueous phase during rinsing, leaving only non-explosive copper(II) iodate and copper(II) periodate. Based on the results of this investigation, the use of oxidizing components in DBX-1 formulations may be limited due to the readiness of copper(I) to be oxidized to copper(II).
Graphical Abstract
Reaction of Copper(I) Nitrotetrazolate (DBX-1) with Sodium m-Periodate
Received: 2013-8-13
Published Online: 2014-6-2
Published in Print: 2014-1-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Keywords for this article
Copper(I) Nitrotetrazolate;
DBX-1;
Lead Azide Replacements;
Sodium Periodate;
Periodate
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