Abstract
The aim of this study was to investigate bubble/drop formation at a single submerged orifice in stagnant Newtonian fluids and to gain qualitative understanding of the formation mechanism. The effects of various governing parameters were studied. Formation behavior of bubbles and drops in Newtonian aqueous solutions were investigated experimentally under different operating conditions with various orifices. The results show that the volume of the detached dispersed phase (bubble or drop) increases with the viscosity of the continuous phase (or dispersion medium), surface tension, orifice diameter, and dispersed phase flow rate. A PIV system was employed to measure the velocity flow field quantitatively during the bubble/drop formation, giving interesting information useful for the elucidation of the fundamental formation process at the orifice. It was revealed that the orifice shape strongly influences the size of the bubble formed. Furthermore, based on a simple mass balance, a general correlation successfully predicting both bubble and drop sizes has been proposed.
[1] Badam, V. K., Buwa, V., & Durst, F. (2007). Experimental investigations of regimes of bubble formation on submerged orifices under constant flow condition. Canadian Journal of Chemical Engineering, 85, 257–267. DOI: 10.1002/cjce.5450850301. http://dx.doi.org/10.1002/cjce.545085030110.1002/cjce.5450850301Search in Google Scholar
[2] Bashforth, F., & Adams, J. C. (1883). An attempt to test the theories of capillary action by comparing the theoretical and measured forms of drops of fluid with an explanation of the method of integration employed in constructing the tables which give the theoretical forms of such drops. Cambridge, UK: Cambridge University Press. Search in Google Scholar
[3] Chang, B., Nave, G., & Jung, S. H. (2012). Drop formation from a wettable nozzle. Communications in Nonlinear Science and Numerical Simulation, 17, 2045–2051. DOI: 10.1016/j.cnsns.2011.08.023. http://dx.doi.org/10.1016/j.cnsns.2011.08.02310.1016/j.cnsns.2011.08.023Search in Google Scholar
[4] Clift, R., Grace, J. R., & Weber, M. E. (1978). Bubbles, drops and particles. New York, NY, USA: Academic Press. Search in Google Scholar
[5] Davidson, J. F., & Schüler, B. O. G. (1960a). Bubble formation at an orifice in a viscous liquid. Transactions of the Institution of Chemical Engineers, 38, 144–154. Search in Google Scholar
[6] Davidson, J. F., & Schüler, B. O. G. (1960b). Bubble formation at an orifice in an inviscid liquid. Transactions of the Institution of Chemical Engineers, 38, 335–342. Search in Google Scholar
[7] de Chazal, L. E. M., & Ryan, J. T. (1971). Formation of organic drops in water. AIChE Journal, 17, 1226–1229. DOI: 10.1002/aic.690170531. http://dx.doi.org/10.1002/aic.69017053110.1002/aic.690170531Search in Google Scholar
[8] Dietrich, N., Poncin, S., Pheulpin, S., & Li, H. Z. (2008). Passage of a bubble through a liquid-liquid interface. AICHE Journal, 54, 594–600. DOI: 10.1002/aic.11399. http://dx.doi.org/10.1002/aic.1139910.1002/aic.11399Search in Google Scholar
[9] Dietrich, N., Poncin, S., & Li, H. Z. (2011). Dynamical deformation of a flat liquid-liquid interface. Experiments in Fluids, 50, 1293–1303. DOI: 10.1007/s00348-010-0989-7. http://dx.doi.org/10.1007/s00348-010-0989-710.1007/s00348-010-0989-7Search in Google Scholar
[10] Frank, X., Funfschilling, D., Midoux, N., & Li, H. Z. (2006). Bubbles in a viscous liquid: lattice Boltzmann simulation and experimental validation. Journal of Fluid Mechanics, 546, 113–122. DOI: 10.1017/s0022112005007135. http://dx.doi.org/10.1017/S002211200500713510.1017/S0022112005007135Search in Google Scholar
[11] Funfschilling, D., & Li, H. Z. (2001). Flow of non-Newtonian fluids around bubbles: PIV measurements and birefringence visualization. Chemical Engineering Science, 56, 1137–1141. DOI: 10.1016/s0009-2509(00)00332-8. http://dx.doi.org/10.1016/S0009-2509(00)00332-810.1016/S0009-2509(00)00332-8Search in Google Scholar
[12] Gaddis, E., & Vogelpohl, A. (1986). Bubble formation in quiescent liquids under constant flow conditions. Chemical Engineering Science, 41, 97–105. DOI: 10.1016/0009-2509(86)85202-2. http://dx.doi.org/10.1016/0009-2509(86)85202-210.1016/0009-2509(86)85202-2Search in Google Scholar
[13] Heertjes, P. M., & de Nie, L. H. (1971). Mass transfer to drops. In C. Hanson (Ed.), Recent advances in liquid-liquid extraction (pp. 367–406). Oxford, UK: Pergamon Press. Search in Google Scholar
[14] Jamialahmadi, M., Zehtaban, M. R., Müller-Steinhagen, H. M., Sarrafi, A., & Smith, J. M. (2001). Study of bubble formation under constant flow conditions. Chemical Engineering Research and Design, 79, 523–532. DOI: 10.1205/02638760152424299. http://dx.doi.org/10.1205/0263876015242429910.1205/02638760152424299Search in Google Scholar
[15] Kulkarni, A. A., & Joshi, J. B. (2005). Bubble formation and bubble rise velocity in gas-liquid systems: A review. Industrial & Engineering Chemistry Research, 44, 5873–5931. DOI: 10.1021/ie049131p http://dx.doi.org/10.1021/ie049131p10.1021/ie049131pSearch in Google Scholar
[16] Kumar, R., & Kuloor, N. R. (1970). The formation of bubbles and drops. Advances in Chemical Engineering, 8, 255–368. DOI: 10.1016/s0065-2377(08)60186-6. http://dx.doi.org/10.1016/S0065-2377(08)60186-610.1016/S0065-2377(08)60186-6Search in Google Scholar
[17] Li, H. Z., Frank, X., Funfschilling, D., & Mouline, Y. (2001). Towards the understanding of bubble interactions and coalescence in non-Newtonian fluids: a cognitive approach. Chemical Engineering Science, 56, 6419–6425. DOI: 10.1016/s0009-2509(01)00269-x. http://dx.doi.org/10.1016/S0009-2509(01)00269-X10.1016/S0009-2509(01)00269-XSearch in Google Scholar
[18] Li, H. Z., Mouline, Y., & Midoux, N. (2002). Modelling the bubble formation dynamics in non-Newtonian fluids. Chemical Engineering Science, 57, 339–346. DOI: 10.1016/s0009-2509(01)00394-3. http://dx.doi.org/10.1016/S0009-2509(01)00394-310.1016/S0009-2509(01)00394-3Search in Google Scholar
[19] Narasinga Rao, E. V. L., Kumar, R., & Kuloor, N. R. (1966). Drop formation studies in liquid-liquid systems. Chemical Engineering Science, 21, 867–880. DOI: 10.1016/0009-2509(66)85081-9. http://dx.doi.org/10.1016/0009-2509(66)85081-910.1016/0009-2509(66)85081-9Search in Google Scholar
[20] Marmur, A. (2004). Adhesion and wetting in an aqueous environment: Theoretical assessment of sensitivity to the solid surface energy. Langmuir, 20, 1317–1320. DOI: 10.1021/la0359124. http://dx.doi.org/10.1021/la035912410.1021/la0359124Search in Google Scholar PubMed
[21] Michael, D. H. (1981). Meniscus stability. Annual Review of Fluid Mechanics, 13, 189–216. DOI: 10.1146/annurev.fl.13.010181.001201. http://dx.doi.org/10.1146/annurev.fl.13.010181.00120110.1146/annurev.fl.13.010181.001201Search in Google Scholar
[22] Null, H. R., & Johnson, H. F. (1958). Drop formation in liquidliquid systems from single nozzles. AIChE Journal, 4, 273–281. DOI: 10.1002/aic.690040308. http://dx.doi.org/10.1002/aic.69004030810.1002/aic.690040308Search in Google Scholar
[23] Oguz, H. N., & Prosperetti, A. (1993). Dynamics of bubble growth and detachment from a needle. Journal of Fluid Mechanics, 257, 111–145. DOI: 10.1017/s0022112093003015. http://dx.doi.org/10.1017/S002211209300301510.1017/S0022112093003015Search in Google Scholar
[24] Scarano, F. (1997). Improvements in PIV image processing application to a backward facing step. Rhode-Saint-Genèse, Belgium: von Karman Institute for Fluid Dynamics. (VKI PR 1997-01) Search in Google Scholar
[25] Scheele G. F., & Meister, B. J. (1968a). Drop formation at low velocities in liquid-liquid systems: Part I. Prediction of drop volume. AIChE Journal, 14, 9–15. DOI: 10.1002/aic.690140105. 10.1002/aic.690140105Search in Google Scholar
[26] Scheele, G. F., & Meister, B. J. (1968b). Drop formation at low velocities in liquid-liquid systems: Part II: Prediction of jetting velocity. AIChE Journal, 14, 16–19. DOI: 10.1002/aic.690140106. http://dx.doi.org/10.1002/aic.69014010510.1002/aic.690140106Search in Google Scholar
[27] Tate, T. (1864). On the magnitude of a drop of liquid formed under different circumstances. London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Series 4, 27, 176–180. 10.1080/14786446408643645Search in Google Scholar
[28] Timgren, A., Trägårdh, G., & Trägårdh, C. (2008). Application of the PIV technique to measurements around and inside a forming drop in a liquid-liquid system. Experiments in Fluids, 44, 565–575. DOI: 10.1007/s00348-007-0416-x. http://dx.doi.org/10.1007/s00348-007-0416-x10.1007/s00348-007-0416-xSearch in Google Scholar
[29] Tsuge, H. (1986). Hydrodynamics of bubble formation from submerged orifices. In N. P. Cheremisinoff (Ed.), Encyclopedia of fluid mechanics (Vol. 3, pp. 191). Houston, TX, USA: Gulf. Search in Google Scholar
[30] Zhang, X. G. (1999). Dynamics of drop formation in viscous flows. Chemical Engineering Science, 54, 1759–1774. DOI: 10.1016/s0009-2509 (99)00027-5. http://dx.doi.org/10.1016/S0009-2509(99)00027-510.1016/S0009-2509(99)00027-5Search in Google Scholar
© 2012 Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Content of selected secondary metabolites in wild hop
- Continuous sorption of synthetic dyes on dried biomass of microalga Chlorella pyrenoidosa
- Sludge of wastewater treatment plants as Co2+ ions sorbent
- Effect of animal age and gender on fatty acid and elemental composition in Austrian beef applicable for authentication purposes
- Nutritional, antioxidant, and glycaemic characteristics of new functional bread
- Effects of enzymes and hydrocolloids on physical, sensory, and shelf-life properties of wheat bread
- Magnetic chains formed from tetra-coordinate Co(II) complexes
- Prediction of anti-tuberculosis activity of 3-phenyl-2H-1,3-benzoxazine-2,4(3H)-dione derivatives
- Experimental investigation of bubble and drop formation at submerged orifices
- Cadmium concentration stabilization in a continuous sulfate reducing bioreactor via sulfide concentration control
- Facile synthesis of gemini surface-active ATRP initiator and its use in soap-free AGET ATRP mini-emulsion polymerisation
- Bulgarian natural diatomites: modification and characterization
- Synthesis, characterisation, and DC conductivity of polyaniline-lead oxide composites
Articles in the same Issue
- Content of selected secondary metabolites in wild hop
- Continuous sorption of synthetic dyes on dried biomass of microalga Chlorella pyrenoidosa
- Sludge of wastewater treatment plants as Co2+ ions sorbent
- Effect of animal age and gender on fatty acid and elemental composition in Austrian beef applicable for authentication purposes
- Nutritional, antioxidant, and glycaemic characteristics of new functional bread
- Effects of enzymes and hydrocolloids on physical, sensory, and shelf-life properties of wheat bread
- Magnetic chains formed from tetra-coordinate Co(II) complexes
- Prediction of anti-tuberculosis activity of 3-phenyl-2H-1,3-benzoxazine-2,4(3H)-dione derivatives
- Experimental investigation of bubble and drop formation at submerged orifices
- Cadmium concentration stabilization in a continuous sulfate reducing bioreactor via sulfide concentration control
- Facile synthesis of gemini surface-active ATRP initiator and its use in soap-free AGET ATRP mini-emulsion polymerisation
- Bulgarian natural diatomites: modification and characterization
- Synthesis, characterisation, and DC conductivity of polyaniline-lead oxide composites