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Development of partial miscibility in polycarbonate/polypropylene blends via annealing

  • Sani A. Samsudin EMAIL logo , Catherine A. Kelly , Stephen N. Kukureka and Mike J. Jenkins
Published/Copyright: December 9, 2016
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Abstract

The morphology, dynamic mechanical properties and infrared spectra of polycarbonate (PC)/polypropylene (PP) blends were investigated. As expected, PC and PP were immiscible when blended together; however partial miscibility developed following annealing. The miscibility of one polymer in the other was examined using the modified Fox equation and the values of the Flory-Huggins polymer-polymer interaction parameter (χ12) were also calculated following the Kim and Burns approach. Moreover, the possible causes for partial miscibility in the annealed PC/PP blends were explored by infrared spectroscopy. It was concluded that annealing caused degradation of PP, leading to the formation of polar groups which were then able to interact with PC generating regions of partial miscibility.

Acknowledgements

The authors wish to thank Yurong Cao for her assistance with the preparation of the manuscript. The authors would also like to express their appreciation to Mr F. Biddlestone for technical support and assistance.

References

[1] Yin Z, Zhang X, Zhang Y, Yin J. J. Appl. Polym. Sci. 1997, 63, 1857–1863.10.1002/(SICI)1097-4628(19970328)63:13<1857::AID-APP19>3.0.CO;2-VSearch in Google Scholar

[2] Favis BD. J. Appl. Polym. Sci. 1990, 39, 285–300.10.1002/app.1990.070390207Search in Google Scholar

[3] Dobkowski Z, Kohman Z, Krajewski B. In Preliminary Investigation of Polycarbonate-Polypropylene Blends in Polymer Blends, Processing, Morphology and Properties, Martuscelli E, Palumbo R, Kryszewski M, Eds., Plenum Press: New York, 1980, p 363–366.10.1007/978-1-4613-3177-3_19Search in Google Scholar

[4] Favis BD. Polymer 1988, 29, 1761–1767.10.1016/0032-3861(88)90388-6Search in Google Scholar

[5] Favis BD, Chalifoux JP. Polym. Eng. Sci. 1987, 27, 1591–1600.10.1002/pen.760272105Search in Google Scholar

[6] Chun YS, Jung HC, Han MS, Kim WN. Polym. Eng. Sci. 1999, 39, 2304–2312.10.1002/pen.11618Search in Google Scholar

[7] Li C, Tian G, Zhang Y, Zhang Y. Polym. Test. 2002, 21, 919–926.10.1016/S0142-9418(02)00034-XSearch in Google Scholar

[8] Wang K, Zhou C, Yu W. J. Appl. Polym. Sci. 2002, 85, 92–103.10.1002/app.10659Search in Google Scholar

[9] Xu Y, Sun ZD, Chen XL, Chen M, Hu SC, Zhang ZB. J. Macromol. Sci. Phys. 2013, 52, 716–725.10.1080/00222348.2012.721659Search in Google Scholar

[10] Dai SS, Ye L, Hu GH. J. Appl. Polym. Sci. 2012, 126, 1165–1173.10.1002/app.36977Search in Google Scholar

[11] Paukszta D, Garbarczyk J, Sterzynski T. Polymer 1995, 36, 1309–1313.10.1016/0032-3861(95)93935-FSearch in Google Scholar

[12] Jourdan C, Cavaille JY, Perrez J. J. Polym. Sci. Pol. Phys. 1989, 27, 2361–2384.10.1002/polb.1989.090271115Search in Google Scholar

[13] McCrum NG, Read BE, Williams G, In Anelastic and Dielectric Effects in Polymeric Solids, John Wiley and Sons: London, 1967.Search in Google Scholar

[14] Pukanszky B, Fortelny I, Kovar J, Tudos F. Plast. Rub. Compos. Pro. 1991, 15, 31–38.Search in Google Scholar

[15] Mas J, Vidaurre A, Meseguer JM, Romero F, Pradas MM, Ribelles JLG, Maspoch MLL, Santana OO, Pages P, Perez-Folch J. J. Appl. Polym. Sci. 2002, 83, 1507–1516.10.1002/app.10043Search in Google Scholar

[16] Luyt AS, Dramicanin MD, Antic Z, Djokovic V. Polym. Test. 2009, 28, 348–356.10.1016/j.polymertesting.2009.01.010Search in Google Scholar

[17] Vranjes N, Rek V. Macromol. Symp. 2007, 258, 90–100.10.1002/masy.200751210Search in Google Scholar

[18] Menard K. DMA - A Practical Introduction, Taylor & Francis Group: Boca Raton, FL, 2008.Search in Google Scholar

[19] Madbouly SA, Otaigbe JU, Ougizawa T. Macromol. Chem. Phys. 2006, 207, 1233–1243.10.1002/macp.200600177Search in Google Scholar

[20] Zheng SX, Zheng HF, Guo QP. J. Polym. Sci. Pol. Phys. 2003, 41, 1085–1098.10.1002/polb.10435Search in Google Scholar

[21] Miranda MIG, Samios D, Freitas LL, Bica CID. Polimeros. 2013, 23, 1–6.10.1590/S0104-14282013005000005Search in Google Scholar

[22] Kelly CA, Naylor A, Illum L, Shakesheff KM, Howdle SM. Adv. Funct. Mater. 2012, 22, 1684–1691.10.1002/adfm.201101889Search in Google Scholar

[23] Gedde UW. Polymer Physics, Chapman and Hall: London, 1995.Search in Google Scholar

[24] Fox TG. B. Am. Phys. Soc. 1956, 1, 123–125.10.1126/science.123.3187.125Search in Google Scholar

[25] Kim WN, Burns CM. Macromolecules 1987, 20, 1876–1882.10.1021/ma00174a030Search in Google Scholar

[26] Lee HS, Kim WN, Burns CM. J. Appl. Polym. Sci. 1997, 64, 1301–1308.10.1002/(SICI)1097-4628(19970516)64:7<1301::AID-APP9>3.0.CO;2-NSearch in Google Scholar

[27] Kim WN, Burns CM. Makromol. Chem. 1989, 190, 661–676.10.1002/macp.1989.021900322Search in Google Scholar

[28] Scott RJ. J. Chem. Phys. 1949, 17, 279–291.10.1063/1.1747239Search in Google Scholar

[29] Karam HJ. Polymer Compatibility and Incompatibility, Solc K, Ed., MMI Press Symposium Series: New York, 1982, p 2–93.Search in Google Scholar

[30] Rjeb A, Tajounte L, El Idrissi MC, Letarte S, Adnot A, Roy D, Claire Y, Perichaud A, Kaloustian J. J. Appl. Polym. Sci. 2000, 77, 1742–1748.10.1002/1097-4628(20000822)77:8<1742::AID-APP11>3.0.CO;2-TSearch in Google Scholar

[31] Adams JH. J. Polym. Sci. 1970, 8, 1077–1090.10.1002/pol.1970.150080505Search in Google Scholar

[32] McAlea KP, Schultz JM, Gardner KH, Wignall GD. Polymer 1986, 27, 1581–1584.10.1016/0032-3861(86)90108-4Search in Google Scholar

[33] Gugumus F. Polym. Degrad. Stabil. 1996, 52, 145–188.10.1016/0141-3910(95)00227-8Search in Google Scholar

Received: 2016-7-4
Accepted: 2016-10-19
Published Online: 2016-12-9
Published in Print: 2017-8-28

©2017 Walter de Gruyter GmbH, Berlin/Boston

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