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Fabrication and characterization of thermally conductive composites based on poly(butylene terephthalate)/glass fiber-silicon carbide

  • Xia Cai , Jinghong Xu and Fenglei Shen EMAIL logo
Published/Copyright: April 14, 2015
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Abstract

A new method is reported for preparing poly(butylene terephthalate) (PBT)/glass fiber (GF)-silicon carbide (SiC) composites. GFs were coated with SiC particles firstly and then the treated GFs (GF-SiC) were mixed with PBT. Scanning electron microscopy (SEM) images showed that some SiC particles dispersed on the surfaces of GFs, and other particles fell off from surfaces of GFs and dispersed around GFs after processing. The thermal conductivities of composites are increased with increase of GF-SiC. At 30 wt% GF-SiC, the thermal conductivity of composites reached 0.6392 W/mK, which improved nearly 160% compared to that of neat polymer. Differential scanning calorimetry (DSC) results indicated that GF-SiC increased crystallinity of PBT compared with that of neat PBT and had no obvious influence on the melting temperature of PBT. The crystallization temperature (Tc) and glass transition temperature of all samples shifted to a higher temperature. The addition of GF-SiC can improve the thermal stability of PBT/GF-SiC composites obviously. Dynamic mechanical properties and dielectric properties were also discussed in this paper.


Corresponding author: Fenglei Shen, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, China, e-mail:

Acknowledgments

This work was supported by the Priority Academic Program Development of Higher Education Institutions.

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Received: 2014-12-22
Accepted: 2015-3-11
Published Online: 2015-4-14
Published in Print: 2015-11-1

©2015 by De Gruyter

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