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Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin

  • Won-Suk Kong EMAIL logo , Tae-Jun Ju , Jun-Hyo Park , Jae-Wook Lee and Ho Gyu Yoon EMAIL logo
Published/Copyright: May 5, 2015
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Abstract

The morphologies, crystalline structures, and thermal and rheological behaviors of isotactic polypropylene (iPP) blended with dicyclopentadiene based hydrogenated hydrocarbon resin (HCR) were investigated using scanning electron microscopy (SEM), wide-angle X-ray diffractometry, and differential scanning calorimetry in detail. Furthermore, the transparency, mechanical properties, and water vapor and oxygen permeability of biaxially oriented polypropylene films, fabricated from these iPP/HCR blends using a biaxial drawing machine, were examined. It was found that crystallinity varies with the HCR content of the iPP/HCR blend. In addition, amorphous HCR with its high glass transition temperature (Tg) upon blending with iPP’s amorphous structure affords improvements in various film properties, such as mechanical properties, transparency, and gas permeabilities.


Corresponding authors: Won-Suk Kong, Department of Materials Science and Engineering, Korea University, 5-1 Anam-dong, Seongbuk-gu, Seoul 136-713, Republic of Korea; and HCR Research Institute, Central Research Park, Kolon Industries, Inc., 294, Kajwa-dong, Seo-gu, Incheon 404-815, Republic of Korea, e-mail: ; and Ho Gyu Yoon, Department of Materials Science and Engineering, Korea University, 5-1 Anam-dong, Seongbuk-gu, Seoul 136-713, Republic of Korea, e-mail:

References

[1] Silvestre C, Cimmino S, D’Alma E, Di Lorenzo ML, Di Pace E. Polymer 1999, 40, 5119–5128.10.1016/S0032-3861(98)00696-XSearch in Google Scholar

[2] Cimmino S, Silvestre C, della Vecchia G. J. Appl. Polym. Sci. 2004, 92, 3454–3465.10.1002/app.20307Search in Google Scholar

[3] Cimmino S, D’Alma E, Di Lorenzo ML, Di Pace E, Silvestre C. J. Polym. Sci. Part. B: Polym. Phys. 1999, 37, 867–878.10.1002/(SICI)1099-0488(19990501)37:9<867::AID-POLB1>3.0.CO;2-XSearch in Google Scholar

[4] Silvestre C, Cimmino S, Di Lorenzo ML. J. Appl. Polym. Sci. 1999, 71, 1677–1690.10.1002/(SICI)1097-4628(19990307)71:10<1677::AID-APP15>3.0.CO;2-KSearch in Google Scholar

[5] Di Lorenzo ML, Cimmino S, Silvestre C. J. Appl. Polym. Sci. 2001, 82, 358–367.10.1002/app.1859Search in Google Scholar

[6] Silvestre C, Cimmino S, Di Pace E, Di Lorenzo ML, Monaco M. J. Macromol. Sci. Phys. 1996, 35, 457–476.10.1080/00222349608220389Search in Google Scholar

[7] Cimmino S, Guarrata P, Martuscelli E, Silvestre C, Buzio PP. Polymer 1991, 32, 3299–3304.10.1016/0032-3861(91)90531-MSearch in Google Scholar

[8] Cimmino S, Di Pace E, Karasz FE, Martuscelli E, Silvestre C. Polymer 1993, 34, 972–976.10.1016/0032-3861(93)90216-WSearch in Google Scholar

[9] Cimmino S, Martuscelli E, Silvestre C. Makromol. Chem. Macromol. Symp. 1994, 78, 115–129.10.1002/masy.19940780112Search in Google Scholar

[10] Cimmino S, Di Pace E, Martuscelli E, Mendes LC, Silvestre C. J. Polym. Sci. 1994, 32, 2025–2035.10.1002/polb.1994.090321209Search in Google Scholar

[11] Cimmino S, Di Pace E, Martuscelli E, Silvestre C, Mendes LC, Bonfanti G. J. Polym. Sci. Part B: Polym. Phys. 1995, 33, 1723–1730.10.1002/polb.1995.090331203Search in Google Scholar

[12] Caponetti E, Chillura Martino D, Cimmino S, Floriano MA, Martuscelli E, Silvestre C, Triolo R. J. Mol. Struct. 1996, 383, 75–79.10.1016/S0022-2860(96)09271-XSearch in Google Scholar

[13] Buzio P, Marcandalli B, Martuscelli E, Seves A. Italian Patent 22196A, 1990.Search in Google Scholar

[14] Ewins EEJ, St. Clair DJ, Erickson JR, Korcz WH. The Handbook of Pressure-Sensitive Adhesive Technology, 2nd ed., States D, Ed., Van Nostrand Reinhold: New York, 1989.Search in Google Scholar

[15] DeWitt & Company Incorporated, The Worldwide Hydrocarbon Resin Report, Issue Number 23, 2009, 106–108.Search in Google Scholar

[16] Mildenberg R, Collin G, Zander M. Hydrocarbon Resins, VCH Verlagsgesellschaft mbH-A Wiley Company: Weinheim, 1997, 72–77.10.1002/9783527614653Search in Google Scholar

[17] Silvestre S, Cimmino S, Pirozzi B. Polymer 2003, 44, 4275–4281.10.1016/S0032-3861(03)00393-8Search in Google Scholar

[18] Kim SJ, Yoo CS, Kim GH, Ha CS. J. Adhes. Interface 2008, 9, 4.Search in Google Scholar

[19] Ha CS, Kim SC. J. Appl. Polym. Sci. 1988, 35, 2211–2221.10.1002/app.1988.070350821Search in Google Scholar

Received: 2014-9-15
Accepted: 2015-3-21
Published Online: 2015-5-5
Published in Print: 2015-11-1

©2015 by De Gruyter

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