Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
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S. A. Nouh
, S. K. Alghamdi , B. O. Alsobhi , K. Benthami und N. T. El-Shamy
Abstract
Light diffusing polycarbonate samples were exposed to protons fluences at levels between 1011 and 1016 p/cm2. The variation of the refractive index and color intensity with the proton fluence has been studied. The results show that the polycarbonate samples acquire color changes under proton irradiation. Furthermore, thermogravimetric analysis has been performed. It was found that both the onset temperature and activation energy of thermal decomposition are affected by the proton fluencies owing to the degradation and crosslinking processes. Moreover, structural property studies using X-ray diffraction, intrinsic viscosity and Fourier transform infrared spectroscopy were performed.
References
Abdel-SalamM. H., NouhS. A., RadwanY. E. and FouadS. S., “Structure and Mechanical Investigation of the Effect of Proton Irradiation in Makrofol DE 7-2 Polycarbonate”, Mater. Chem. Phys., 127, 305–309 (2011) 10.1016/j.matchemphys.2011.02.017Suche in Google Scholar
Al-JarallahM. I., Abu-JaradF., HallakA. B, CobanA. and IslamM., “Investigation of Proton Response of CR-39”, Nucl. Tracks Radiat. Meas., 22, 191–194 (1993) 10.1016/0969-8078(93)90044-5Suche in Google Scholar
Darraud-TaupiacC., BennamaneB., DecossasJ. L. and VareilleJ. C., “CR-39 (Poly(diethylene glycol bis (allyl carbonate))) under Γ-Rays and Proton Beams”, Nucl. Instrum. Methods Phys. Res. Sect. B., 131, 198–204 (1997) 10.1016/S0168-583X(97)00138-9Suche in Google Scholar
DwivediK. K., GhoshS., FinkD., MishraR., TripathyS. P., KulshreshthaA. and KhathingD. T., “Modifications in Track Registration Response of PADC Detector by Energetic Protons”, Radiat. Meas., 31, 127–132 (1999) 10.1016/S1350-4487(99)00137-7Suche in Google Scholar
GagnadreC., DecossasJ. L. and VareilleJ. C., “IR Spectroscopy Studies of Polycarbonate Irradiated By H+ and Li+ Ions”, Nucl. Instrum. Methods Phys. Res. Sect. B., 73, 48–52 (1993) 10.1016/0168-583X(93)96052-ESuche in Google Scholar
HorowitzH., MetzgerG., “A New Analysis of Thermo Gravimetric Traces”, Anal. Chem., 35, 1464–1468 (1963) 10.1021/ac60203a013Suche in Google Scholar
Jong-SeokP., HyunA., Jong-BaeC., Hui-JeongG., Young-MinS., Youn-MookL., MyungS. and Young-ChangN., “Degradation Behavior of Poly(L-lactide-co-glycolide) Films through Gamma-Ray Irradiation”, Radiat. Phys. Chem., 81, 857–860 (2012)Suche in Google Scholar
KalsiP. C., AgarwalC., “Neutron-Irradiation Effects on Track Etching Characteristics of Polyester Nuclear Track Detector”, Radiat. Eff. Defects Solids, 162, 25–30 (2007) 10.1080/10420150601005113Suche in Google Scholar
LeeE. H., “Ion-Beam Modification of Polymeric Materials–Fundamental Principles and Applications”, Nucl. Instrum. Methods Phys. Res. Sect. B., 151, 29–41 (1999)10.1016/S0168-583X(99)00129-9Suche in Google Scholar
NouhS., AmalM. and MarieH., “Proton-Induced Crosslinking of CR 6-2 Polycarbonate”, J. Appl. Polym. Sci., 112, 2724–2731 (2009) 10.1002/app.29902Suche in Google Scholar
NouhS., SalamAbdel M., RadwanY. and FouadS., “Thermal, Electrical and Optical Properties of Proton-Irradiated Makrofol DE 7-2 Nuclear Track Detector”, Radiat. Eff. Defects Solids, 166, 178–189 (2011) 10.1080/10420150.2010.550006Suche in Google Scholar
NouhS. A., BahmmamS., “Structural and Optical investigation of the Effect of Electron Beam Irradiation in a PM-355 Nuclear Track Detector”, Radiat. Eff. Defects Solids, 167, 352–360 (2012) 10.1080/10420150.2011.607455Suche in Google Scholar
NouhS. A., RadwanY., ElfikyD., AbutalibM., BaharethR., HegazyT. and FouadS., “Structure, Thermal, Optical and Electrical Investigation of the Effect of Heavy Highly Energetic Ions Irradiations in Bayfol DPF 5023 Nuclear Track Detector”, Radiat. Phys. Chem., 97, 68–74 (2014) 10.1016/j.radphyschem.2013.10.017Suche in Google Scholar
PhukanT., KanjilalD., GoswamiT. and DasH., “Dielectric Response of Heavy Ion Irradiated PADC Track Detector”, Nucl. Instrum. Methods Phys. Res. Sect. B., 155, 116–119 (1999) 10.1016/S0168-583X(99)00255-4Suche in Google Scholar
Shams-EldinM., WochnowskiC., KoerdtM., MetevS., HamzaA. and JuptnerW., “Characterization of the Optical-Functional Properties of a Waveguide Written by an UV-Laser into a Planar Polymer Chip”, Opt. Mater., 27, 1138–1148 (2005) 10.1016/j.optmat.2004.09.019Suche in Google Scholar
SinhaD., SarkerG. K., GhoshS., KulshreshthtaA., DwivediK. K. and FinkD., “Gamma Ray Photon-Induced Modifications in Triafol-TN and Triafol-BN Polymeric Track Detectors”, Radiat. Meas., 29, 599–604 (1998) 10.1016/S1350-4487(98)00070-5Suche in Google Scholar
TripathyS. P., MishraR., DwivediK. K., KhathingD. T., GhoshS. and FinkD., “Modifications Induced by Proton Irradiation in Polyallyldiglycol Carbonate”, Int. J. Radiat. Appl. Instrum. Part D., 34, 15–17 (2001) 10.1016/S1350-4487(01)00113-5Suche in Google Scholar
TripathyS. P., MishraR., DwivediK. K., KhathingD. T., GhoshS. and FinkD., “Dose Dependent Modification of Polypropylene by 62 mev Protons”, Int. J. Radiat. Appl. Instrum. Part D, 35, 95–98 (2002)Suche in Google Scholar
TripathyS. P., MishraR., DwivediK. K., KhathingD. T., GhoshS. and FinkD., “Proton Dose Dependent Modification in Track Etching Response in some Polymers”, Int. J. Radiat. Appl. Instrum. Part D, 36, 107–110 (2003) 10.1016/S1350-4487(03)00104-5Suche in Google Scholar
© 2015, Carl Hanser Verlag, Munich
Artikel in diesem Heft
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Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Anti-Aging Performance of Cardanol Grafted onto Polypropylene by Reactive Extrusion
- Co-Extrusion Layer Multiplication of Rheologically Mismatched Polymers: A Novel Processing Route
- Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
- Processing of Soju Industrial Bioresidue to Extract Microcrystalline Cellulose and Characterization
- Competition between α and β Crystallization in Isotactic Polypropylene: Effect of Nucleating Agents Composition
- Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
- The Mechanical Properties of Plasticized PVC Processed in an Extruder with a Modified Feed Zone
- Prediction and Validation of Short Fiber Orientation in a Complex Injection Molded Part with Chunky Geometry
- Microthermoforming Integrated in the Injection Molding Process for Fabrication of Film-Based Microstructured Parts
- Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
- Surface Quenching Induced Microstructure Transformations in Extrusion Foaming of Porous Sheets
- Repercussion of Cenosphere Filler Size on Mechanical and Dry Sliding Wear Peculiarity of Glass Fiber-Reinforced Polyester Composites Using Taguchi Analysis and Neural Network
- Rapid Communications
- PPy Doped with DBSA and Combined with PSS to Improve Processability and Control the Morphology
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts