Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
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A. Rana
und R. W. Evitts
Abstract
In this study acrylated epoxidized flaxseed oil was synthesized and then characterized by spectroscopic techniques. Triglycerides are the main constituents of flaxseed oil and the carbon-carbon double bond is the reaction site for epoxidation. Flaxseed oil was epoxidized by adding formic acid and hydrogen peroxide. Acrylic acid was then added to produce acrylated epoxidized flaxseed oil (AEFO). The change in the structure of the fatty acids chain after the epoxidation and acrylation reactions was measured and characterized by Hydrogen nuclear magnetic resonance spectroscopy (1H NMR) and Fourier transform infrared spectroscopy (FTIR). The FTIR spectra of epoxidized flaxseed oil and flaxseed oil shows the disappearance of the =C–H (3012 cm−1) and C=C (1654 cm−1) peaks. The FTIR spectra confirmed the formation of AEFO since the presence of hydroxyl group (–OH) was shown by the peak at 3455 cm−1 and the acrylate group (–CH=CH2), which was indicated by the peaks at 1406, 984 and 812 cm−1. The changes in peaks of the 1H NMR spectra also confirmed the formation of AEFO. The number of acrylate groups/molecule of triglyceride was found to be 2.6 from 1H NMR spectra.
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© 2015, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Anti-Aging Performance of Cardanol Grafted onto Polypropylene by Reactive Extrusion
- Co-Extrusion Layer Multiplication of Rheologically Mismatched Polymers: A Novel Processing Route
- Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
- Processing of Soju Industrial Bioresidue to Extract Microcrystalline Cellulose and Characterization
- Competition between α and β Crystallization in Isotactic Polypropylene: Effect of Nucleating Agents Composition
- Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
- The Mechanical Properties of Plasticized PVC Processed in an Extruder with a Modified Feed Zone
- Prediction and Validation of Short Fiber Orientation in a Complex Injection Molded Part with Chunky Geometry
- Microthermoforming Integrated in the Injection Molding Process for Fabrication of Film-Based Microstructured Parts
- Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
- Surface Quenching Induced Microstructure Transformations in Extrusion Foaming of Porous Sheets
- Repercussion of Cenosphere Filler Size on Mechanical and Dry Sliding Wear Peculiarity of Glass Fiber-Reinforced Polyester Composites Using Taguchi Analysis and Neural Network
- Rapid Communications
- PPy Doped with DBSA and Combined with PSS to Improve Processability and Control the Morphology
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Anti-Aging Performance of Cardanol Grafted onto Polypropylene by Reactive Extrusion
- Co-Extrusion Layer Multiplication of Rheologically Mismatched Polymers: A Novel Processing Route
- Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
- Processing of Soju Industrial Bioresidue to Extract Microcrystalline Cellulose and Characterization
- Competition between α and β Crystallization in Isotactic Polypropylene: Effect of Nucleating Agents Composition
- Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
- The Mechanical Properties of Plasticized PVC Processed in an Extruder with a Modified Feed Zone
- Prediction and Validation of Short Fiber Orientation in a Complex Injection Molded Part with Chunky Geometry
- Microthermoforming Integrated in the Injection Molding Process for Fabrication of Film-Based Microstructured Parts
- Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
- Surface Quenching Induced Microstructure Transformations in Extrusion Foaming of Porous Sheets
- Repercussion of Cenosphere Filler Size on Mechanical and Dry Sliding Wear Peculiarity of Glass Fiber-Reinforced Polyester Composites Using Taguchi Analysis and Neural Network
- Rapid Communications
- PPy Doped with DBSA and Combined with PSS to Improve Processability and Control the Morphology
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts