Startseite Surface/Interfacial Tension, Wettability and Foaming Properties of Bi-Component Nonylphenol Alkyl Sulfonates based on Linear Alpha Olefin
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Surface/Interfacial Tension, Wettability and Foaming Properties of Bi-Component Nonylphenol Alkyl Sulfonates based on Linear Alpha Olefin

  • Ruixia Niu , Jingling Wang , Wenyi Wang , Biao Long , Hua Song , Chao Wang , Daqiang Wang und Lingzhi Liao
Veröffentlicht/Copyright: 3. März 2017
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 54 Heft 2

Abstract

Series of bi-component nonylphenol alkyl sulfonate surfactants (C12/Cn-NPAS, n = 8, 10, 14, 16) were synthesized through sulfonation-alkylation-neutralization using a mixture of linear alpha olefin (C12-olefin and Cn-olefin, n = 8, 10, 14, 16), SO3 and nonylphenol as raw materials. The effect of the raw materials composition on the properties, such as surface tension, interfacial tension, wettability, foam properties of the prepared C12/Cn-NPAS (n = 8, 10, 14, 16) surfactants was systematically investigated. The critical micelle concentrations (CMC) of C12/C8-NPAS, C12/C10-NPAS, C12/C14-NPAS and C12/C16-NPAS are 0.42, 0.26, 0.22 and 0.40 mmol · L−1, and surface tensions at CMC (γCMC) are 34.7, 27.9, 31.8 and 33.3 mN · m−1, respectively. Compared with SDBS and HABS, the surface properties of the prepared C12/Cn-NPAS are superior to traditional surfactants. Interfacial tension between Daqing crude oil and weakly alkaline ASP oil flooding system containing 0.1 wt% of C12/C14-NPAS could reach an ultralow level of 9.78 × 10−3 mN · m−1, which is lower than that for C12-NPAS and HABS. C12/C10-NPAS shows better wetting performance and foamability and foam stability than other synthesized surfactants.

Kurzfassung

Eine Reihe von Zweikomponenten-Nonylphenolalkylsulfonat-Tensiden (C12/Cn-NPAS, n = 8, 10, 14, 16) wurde durch eine Sulfonierungsreaktion mit anschließender Alkylierung und Neutralisation unter Verwendung eines Gemischs aus linearem alpha-Olefin (C12-Olefin und Cn-Olefin, n = 8, 10, 14, 16), SO3 und Nonylphenol hergestellt. Der Einfluss der Ausgangsmaterialzusammensetzung auf Eigenschaften wie die Ober- und Grenzflächenspannung, die Benetzbarkeit, das Schäumvermögen der hergestellten C12/Cn-NPAS-Tenside (n = 8, 10, 14, 16) wurde systematisch untersucht. Die kritische Mizellenbildungskonzentrationen (CMC) von C12/C8-NPAS, C12/C10-NPAS, C12/C14-NPAS und C12/C16-NPAS betragen: 0,42, 0,26, 0,22 und 0,40 mmol L−1 und Oberflächenspannungen bei der CMC (γCMC) sind 34,7, 27,9, 31,8 bzw. 33,3 mN · m−1. Die Oberflächeneigenschaften der synthetisierten C12/Cn-NPAS-Tenside sind denen herkömmlicher Tenside (im Vergleich zu SDBS und HABS) überlegen. Die Grenzflächenspannung zwischen dem Daqing-Rohöl und dem Alkali-Tensid-Polymerflutungssystem, das 0,1 Gew.-% C12/C14-NPAS enthielt, betrug 9,78 × 10−3 mN · m−1 und liegt damit unterhalb der Grenzflächenspannung von C12-NPAS und HABS. Das Tensid C12/C10-NPAS zeigt eine bessere Benetzung sowie ein besseres Schäumvermögen und eine höhere Schaumstabilität als die anderen synthetisierten Tenside.

Key words: Nonylphenol alkyl sulfonate; bi-component surfactant; synthesis; surface activity; interfacial activity
Stichwörter: Nonylphenolalkylsulfonate; Zweikomponententensid; Synthese; Oberflächeneigenschaften; Grenzflächenaktivität
* Correspondence address, Dr. Hua Song, Heilongjiang Provincial Key Laboratory Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing, Heilongjiang 163318, China, E-Mail:

Ruixia Niu is currently a teacher at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. She received her M. Sc. and Ph. D. in Chemical Technology of Northeast Petroleum University. Her research interest includes synthesis and application of green surfactants and oilfield chemicals.

Jingling Wang is a Masters student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. Her research interests are the synthesis and characterization of surfactants.

Wenyi Wang is a Masters student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. His research interests are the adsorption desulfurization.

Biao Long is a PH.D. student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. His research interests are the adsorption desulfurization and oilfield chemicals.

Hua Song is currently a teacher at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. She received her M. Sc. and Ph. D. in the Chemical Technology Department of the Northeast Petroleum University. Her research interest includes synthesis and application of oilfield chemicals, preparation and properties of hydrodesulfurizing catalyst.

Chao Wang is a Masters student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. His research interests are the synthesis and characterization of surfactants.

Daqiang Wang is a Masters student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. His research interests are the synthesis and characterization of surfactants.

Lingzhi Liao is a Masters student at the College of Chemistry and Chemical Engineering, Northeast Petroleum University of China. His research interests are the synthesis and characterization of surfactants.

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Received: 2016-03-18
Accepted: 2016-08-30
Published Online: 2017-03-03
Published in Print: 2017-03-15

© 2017, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Review
  4. Origin, Properties, Production and Purification of Microbial Surfactants as Molecules with Immense Commercial Potential
  5. Novel Surfactants
  6. Determination of Surface-Active Characteristics of a Natural Surfactant Extracted from Sapindus Saponaria
  7. Environmental Chemistry
  8. Effect of Contaminated Water with Laundry Detergent on Foxtail Millet Root and Physiological Traits
  9. Washing Technology
  10. Influence of Water Circulation in Household Washing Machines on Cleaning Performance
  11. Physical Chemistry
  12. Approach of Different Properties of Alkylammonium Surfactants using Artificial Intelligence and Response Surface Methodology
  13. Micellar Parameters of Cationic Surfactant Cetylpyridinium Bromide in Aqueous Solutions of Amino Acids at Different Temperatures: Conductometric, Surface Tension, Volumetric and Viscosity Study
  14. Cloud Point of Mixed Ionic-Nonionic Surfactant Solutions in the Presence of Inorganic Salts
  15. Surface/Interfacial Tension, Wettability and Foaming Properties of Bi-Component Nonylphenol Alkyl Sulfonates based on Linear Alpha Olefin
  16. Application
  17. Characterization and Surface Active Properties of Aliphatic Glycerol Acetal Disodium Sulfosuccinates
  18. A Comparative Study on the Cloud Point Extraction Behavior of Copper(II) from Sulphate Medium by N,N′-Bis(Salicylidene)Ethylenediamine using Triton X-100 and Tergitol 15-S-7 as Non-ionic Surfactants
https://doi.org/10.3139/113.110485
Schlagwörter für diesen Artikel
Nonylphenol alkyl sulfonate; bi-component surfactant; synthesis; surface activity; interfacial activity

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Review
  4. Origin, Properties, Production and Purification of Microbial Surfactants as Molecules with Immense Commercial Potential
  5. Novel Surfactants
  6. Determination of Surface-Active Characteristics of a Natural Surfactant Extracted from Sapindus Saponaria
  7. Environmental Chemistry
  8. Effect of Contaminated Water with Laundry Detergent on Foxtail Millet Root and Physiological Traits
  9. Washing Technology
  10. Influence of Water Circulation in Household Washing Machines on Cleaning Performance
  11. Physical Chemistry
  12. Approach of Different Properties of Alkylammonium Surfactants using Artificial Intelligence and Response Surface Methodology
  13. Micellar Parameters of Cationic Surfactant Cetylpyridinium Bromide in Aqueous Solutions of Amino Acids at Different Temperatures: Conductometric, Surface Tension, Volumetric and Viscosity Study
  14. Cloud Point of Mixed Ionic-Nonionic Surfactant Solutions in the Presence of Inorganic Salts
  15. Surface/Interfacial Tension, Wettability and Foaming Properties of Bi-Component Nonylphenol Alkyl Sulfonates based on Linear Alpha Olefin
  16. Application
  17. Characterization and Surface Active Properties of Aliphatic Glycerol Acetal Disodium Sulfosuccinates
  18. A Comparative Study on the Cloud Point Extraction Behavior of Copper(II) from Sulphate Medium by N,N′-Bis(Salicylidene)Ethylenediamine using Triton X-100 and Tergitol 15-S-7 as Non-ionic Surfactants
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