Startseite Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
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Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review

  • Gang Wang , Ming Zhou , Shenying Ding , Zhou Huang , Ze Zhang und Sisi Li
Veröffentlicht/Copyright: 6. Januar 2017
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 54 Heft 1

Abstract

As a new type of high effective surfactant, aliphatic alcohol ether sulfonate has widely application prospects in the process of tertiary oil recovery. So, the theoretical analysis of synthesis of aliphatic alcohol ether sulfonate has played a very important role in the process of its development. After the first patent about the preparation of a fatty alcohol ether sulfonate surfactant was reported in 1938, there were several methods to synthesize alcohol ether sulfonate surfactants with different structure. Sulfonated alkylation, one of the synthesis methods, is introduced in this paper. The synthesis principle of alcohol ether sodium sulfonate was analyzed by three step reactions – synthesis of PTGE, ring opening reaction and sulfonation reaction. Synthesis principle of PTGE includes acid catalysis, phase-transfer catalysis, side reaction of the synthesis of glycerol ether and reaction of PTGE outcome. Ring opening reaction includes two reactions of acid catalysis and alkali catalysis.

Kurzfassung

Aliphatische Alkoholethersulfonate finden als neue Klasse hocheffektiver Tenside viele Anwendungsperspektiven in der tertiären Erdölförderung. Daher spielt die theoretische Analyse der Synthese von aliphatischen Alkoholethersulfonaten eine sehr wichtige Rolle in dem Entwicklungsprozess. Nachdem im Jahr 1938 das erste Patent über die Herstellung von Fettalkoholethersulfonaten gemeldet wurde, gab es verschiedene Methoden für die Synthese von Alkoholethersulfonaten mit unterschiedlichen Strukturen. Eine der Synthesemethoden, die sulfonierte Alkylierung, wird in diesem Beitrag vorgestellt. Der Synthesevorgang wurde analysiert als eine Reaktion mit drei Stufen: Synthese von PTGE, Ringöffnungsreaktion und Sulfonierungsreaktion. Die Synthese von PTGE enthält die saure Katalyse, die Phasentransferkatalyse, die Seitenreaktion der Synthese des Glycerolethers und die Reaktion zum PTGE. Die Ringöffnungsreaktion besteht aus einer säurekatalysierten und einer alkalikatalysierten Reaktion.

Key words: Sulfonated alkylation; dioctyl digomeric glycol; alcohol ether sulfonates; reaction principle
Stichwörter: Sulfonierte Alkylierung; digomeres Dioctylglycol; Alkoholethersulfonate; Prinzip
*Correspondence address, Dr. M. Zhou, State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, 610500, Sichuan, China, E-Mail:

Gang Wang studied at the School of Materials Science and Engineering at Southwest Petroleum University as a postgraduate. He is majoring materials physical chemistry.

Ming Zhou received his B.Sc., M.Sc. and Ph.D. from the Southwest Petroleum University in Chengdu of the PR China and worked at the School of Materials Science and Engineering at Southwest Petroleum University as a research chemist in 2002, he is an associate professor at the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation. His research field is the synthesis and applications of surfactants and polymers.

Shenying Ding studied at the School of Materials Science and Engineering at Southwest Petroleum University as a postgraduate. She is majoring materials physical chemistry.

Zhou Huang studied at the School of Materials Science and Engineering at Southwest Petroleum University as a postgraduate. He is majoring materials physical chemistry.

Ze Zhang studied at the School of Materials Science and Engineering at Southwest Petroleum University as a postgraduate. He is majoring materials physical chemistry.

Sisi Li studied at the School of Materials Science and Engineering at Southwest Petroleum University as a postgraduate. She is majoring materials physical chemistry.

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Received: 2016-04-06
Accepted: 2016-06-14
Published Online: 2017-01-06
Published in Print: 2017-01-20

© 2017, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Editorial
  4. Review of the Year 2016
  5. Review
  6. Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
  7. Biosurfactants/Novel Surfactants
  8. Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
  9. Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
  10. Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
  11. Environmental Chemistry
  12. Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
  13. Physical Chemistry
  14. Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
  15. Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
  16. Micellar Catalysis
  17. Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
  18. Synthesis
  19. Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
  20. Application
  21. Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
  22. Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
https://doi.org/10.3139/113.110472
Schlagwörter für diesen Artikel
Sulfonated alkylation; dioctyl digomeric glycol; alcohol ether sulfonates; reaction principle

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Editorial
  4. Review of the Year 2016
  5. Review
  6. Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
  7. Biosurfactants/Novel Surfactants
  8. Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
  9. Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
  10. Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
  11. Environmental Chemistry
  12. Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
  13. Physical Chemistry
  14. Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
  15. Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
  16. Micellar Catalysis
  17. Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
  18. Synthesis
  19. Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
  20. Application
  21. Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
  22. Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
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