Evaluation and interlaboratory validation of a GC-MS method for analysis of pesticide residues in teas
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C. Peng
,
H. Kuang
Abstract
A method was described for simultaneous determination of nine organic heterocyclic pesticide residues by gas chromatography-mass spectrometry-selected ion monitoring. Atrazine, vinclozolin, procymidone, triflumizole, imazalil, buprofezin, propiconazole, fenarimol, and pyridaben were clearly separated from each other, extracted with acetone—hexane mixture, purified with graphitized carbon black cartridge and neutral Al2O3 cartridge, eluted with acetone—hexane mixture, simultaneously determined by GC-MS, and then quantified with an external standard method. Recoveries of pesticides ranged from 73 % to 116 % at the spiked level of 0.01–30 mg kg−1, while the relative standard deviation was between 3 % and 27 %. In addition, the limits of determination (0.01 mg kg−1 to 5.0 mg kg−1) and linearity (0.02–40 μg mL−1) revealed that simultaneous determination of multi-residues in Chinese teas (like Oolong tea, green tea, red tea, etc.) was possible. Furthermore, an interlaboratory study among 5 labs was conducted to further validate the method, and the results were satisfactory.
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© 2007 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Evaluation and interlaboratory validation of a GC-MS method for analysis of pesticide residues in teas
- Protective effects of vitamin E against CCl4-induced hepatotoxicity in rabbits
- Influence of composition on corroding process of Na2O-K2O-CaO-ZrO2-SiO2 glasses
- Effects of type and number of impellers and liquid viscosity on the power characteristics of mechanically agitated gas—liquid systems
- Modelling of composting of food waste in a column reactor
- Comparison of chemical properties of food products processed by conventional and ohmic heating
- Electrical resistivity and photoluminescence of lead iodide crystals
- Effect of microwave irradiation on the reactivity of chloroarenes in Suzuki—Miyaura reaction
- Kinetics of extraction of coal-tar pitch components with supercritical carbon dioxide
- Mechanism of photocatalytic oxidation of gaseous ethanol
- Kinetics and mechanism of hydroboration of oct-1-and-4-ene by dimeric dialkylboranes
- Reaction sites of N,N′-substituted p-phenylenediamine antioxidants
- Theoretical study of solvent effect on π-EDA complexation II. Complex between TCNE and two benzene molecules
