Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa
-
Jason B. Burt
,
Nancy L. Ross
Veröffentlicht/Copyright:
31. März 2015
Abstract
The equations of state and structures of andalusite and sillimanite have been determined using high-pressure single-crystal X-ray diffraction. A third-order Birch-Murnaghan equation-of-state fit to 14 P-V data points measured between 1 bar and 9.8 GPa for andalusite yields values of KT0 = 144.2(7) GPa and K’ = 6.8(2). A similar analysis for sillimanite involving a fit to 13 P-V data points between 1 bar and 8.5 GPa results in KT0 = 164(1) GPa and K’ = 5.0(3). The axial compression of both structures is nonlinear and highly anisotropic (~60%) with the c-axis being the least compressible axis in both structures. The axial moduli determined with a parameterized form of the third-order Birch-Murnaghan equation of state are: Ka₀ = 163(1) GPa, Kb₀ = 113.1(7) GPa, and Kc₀ = 297(1) GPa with K’a₀ = 2.1(3), K’b₀ = 5.08(19), and K’c₀ = 11.1(4) for sillimanite, and Ka₀ = 99.6(7) GPa, Kb₀ = 152.2(9) GPa, and Kc₀ = 236(3) GPa with K’a₀ = 5.83(19), K’b₀ = 7.6(3), and K’c₀ = 5.5(9) for andalusite. The major compression mechanism in both structures involves shortening of bond lengths within the AlO6 octahedra with volume reductions of 7.4% and 5.1% in sillimanite and andalusite, respectively, over the pressure ranges studied. In andalusite there is also significant compression of the AlO5 polyhedra and, to a lesser degree, the SiO4 tetrahedra that display reductions of 5.0% and 3.1% in volume, respectively. In sillimanite there is no significant compression of either the AlO4 or SiO4 tetrahedra which behave as rigid, incompressible units.
Keywords: Andalusite; sillimanite; high-pressure studies; equation of state; XRD data; single crystal; crystal structure
Received: 2004-12-8
Accepted: 2005-5-12
Published Online: 2015-3-31
Published in Print: 2006-2-1
© 2015 by Walter de Gruyter Berlin/Boston
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Presidential Address: Elastic properties of minerals and the influence of phase transitions
- Pressure-induced hydration in zeolite tetranatrolite
- Annealing experiments on induced fission tracks in apatite: Measurements of horizontal-confined track lengths and track densities in basal sections and randomly oriented grains
- Alpersite (Mg,Cu)SO4·7H2O, a new mineral of the melanterite group, and cuprian pentahydrite: Their occurrence within mine waste
- Application of a new vanadium valence oxybarometer to basaltic glasses from the Earth, Moon, and Mars
- Quantitative polarized infrared analysis of trace OH in populations of randomly oriented mineral grains
- Hydrogen incorporation in olivine from 2–12 GPa
- A numerical model for steady-state temperature distributions in solid-medium high-pressure cell assemblies
- Thermodynamics and kinetics of cation ordering in natural and synthetic Mg(Al,Fe3+)2O4 spinels from in situ high-temperature X-ray diffraction
- Kinetics of cation ordering in natural Mg(Al,Cr3+)2O4 spinels
- Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa
- Equation of state and phase transition in KAlSi3O8 hollandite at high pressure
- A novel arrangement of silicate tetrahedra in the uranyl silicate sheet of oursinite, (Co0.8Mg0.2)[(UO2)(SiO3OH)]2(H2O)6
- Aluminum substitution in stishovite and MgSiO3 perovskite: High-resolution 27Al NMR
- The effect of chlorine on the viscosity of Na2O-Fe2O3-Al2O3-SiO2 melts
- TEM imaging and analysis of microinclusions in diamonds: A close look at diamond-growing fluids
- A partial molar volume for ZnO in silicate melts
- Garnet-spinel intergrowths in ultrahigh-temperature granulite, Eastern Ghats, India: Possible evidence of an early Tschermak-rich orthopyroxene during prograde metamorphism
- The partial molar volume of Fe2O3 in alkali silicate melts: Evidence for an average Fe3+ coordination number near five
- The crystal structure of a second antigorite polysome (m = 16), by single-crystal synchrotron diffraction
- Oxide melt solution calorimetry of sulfides: Enthalpy of formation of sphalerite, galena, greenockite, and hawleyite
- An experimental determination of the effect of pressure on the Fe3+/ΣFe ratio of an anhydrous silicate melt to 3.0 GPa
- Evolution of product phase assemblages during thermal decomposition of muscovite under strong disequilibrium conditions
- Synthetic P21/m amphiboles in the system Li2O-Na2O-MgO-SiO2-H2O (LNMSH)
- Incongruent dissolution of wollastonite measured with vertical scanning interferometry
- Experiments on CaCO3-MgCO3 solid solutions at high pressure and temperature
- Calorimetric data for naturally occurring magnesiocarpholite and ferrocarpholite
- Clinopyroxene exsolution in wollastonite from Namaqualand granulite, South Africa
- Icosahedral coordination of phosphorus in the crystal structure of melliniite, a new phosphide mineral from the Northwest Africa 1054 acapulcoite
- Mechanism for the dissolution of olivine series minerals in acidic solutions
- High-pressure behavior of synthetic antigorite in the MgO-SiO2-H2O system from Raman spectroscopy
- Sinoite (Si2N2O) shocked at pressures of 28 to 64 GPa
- Laser Raman spectroscopic measurements of water in unexposed glass inclusions
- The Mars/Earth dichotomy in Mg/Si and Al/Si ratios: Is it real?
- Equation of state of CaIrO3-type MgSiO3 up to 144 GPa
- Synchrotron infrared spectroscopy of synthetic Na(NaMg)Mg5Si8O22(OH)2 up to 30 GPa: Insight on a new high-pressure amphibole polymorph
Schlagwörter für diesen Artikel
Andalusite;
sillimanite;
high-pressure studies;
equation of state;
XRD data;
single crystal;
crystal structure
Artikel in diesem Heft
- Presidential Address: Elastic properties of minerals and the influence of phase transitions
- Pressure-induced hydration in zeolite tetranatrolite
- Annealing experiments on induced fission tracks in apatite: Measurements of horizontal-confined track lengths and track densities in basal sections and randomly oriented grains
- Alpersite (Mg,Cu)SO4·7H2O, a new mineral of the melanterite group, and cuprian pentahydrite: Their occurrence within mine waste
- Application of a new vanadium valence oxybarometer to basaltic glasses from the Earth, Moon, and Mars
- Quantitative polarized infrared analysis of trace OH in populations of randomly oriented mineral grains
- Hydrogen incorporation in olivine from 2–12 GPa
- A numerical model for steady-state temperature distributions in solid-medium high-pressure cell assemblies
- Thermodynamics and kinetics of cation ordering in natural and synthetic Mg(Al,Fe3+)2O4 spinels from in situ high-temperature X-ray diffraction
- Kinetics of cation ordering in natural Mg(Al,Cr3+)2O4 spinels
- Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa
- Equation of state and phase transition in KAlSi3O8 hollandite at high pressure
- A novel arrangement of silicate tetrahedra in the uranyl silicate sheet of oursinite, (Co0.8Mg0.2)[(UO2)(SiO3OH)]2(H2O)6
- Aluminum substitution in stishovite and MgSiO3 perovskite: High-resolution 27Al NMR
- The effect of chlorine on the viscosity of Na2O-Fe2O3-Al2O3-SiO2 melts
- TEM imaging and analysis of microinclusions in diamonds: A close look at diamond-growing fluids
- A partial molar volume for ZnO in silicate melts
- Garnet-spinel intergrowths in ultrahigh-temperature granulite, Eastern Ghats, India: Possible evidence of an early Tschermak-rich orthopyroxene during prograde metamorphism
- The partial molar volume of Fe2O3 in alkali silicate melts: Evidence for an average Fe3+ coordination number near five
- The crystal structure of a second antigorite polysome (m = 16), by single-crystal synchrotron diffraction
- Oxide melt solution calorimetry of sulfides: Enthalpy of formation of sphalerite, galena, greenockite, and hawleyite
- An experimental determination of the effect of pressure on the Fe3+/ΣFe ratio of an anhydrous silicate melt to 3.0 GPa
- Evolution of product phase assemblages during thermal decomposition of muscovite under strong disequilibrium conditions
- Synthetic P21/m amphiboles in the system Li2O-Na2O-MgO-SiO2-H2O (LNMSH)
- Incongruent dissolution of wollastonite measured with vertical scanning interferometry
- Experiments on CaCO3-MgCO3 solid solutions at high pressure and temperature
- Calorimetric data for naturally occurring magnesiocarpholite and ferrocarpholite
- Clinopyroxene exsolution in wollastonite from Namaqualand granulite, South Africa
- Icosahedral coordination of phosphorus in the crystal structure of melliniite, a new phosphide mineral from the Northwest Africa 1054 acapulcoite
- Mechanism for the dissolution of olivine series minerals in acidic solutions
- High-pressure behavior of synthetic antigorite in the MgO-SiO2-H2O system from Raman spectroscopy
- Sinoite (Si2N2O) shocked at pressures of 28 to 64 GPa
- Laser Raman spectroscopic measurements of water in unexposed glass inclusions
- The Mars/Earth dichotomy in Mg/Si and Al/Si ratios: Is it real?
- Equation of state of CaIrO3-type MgSiO3 up to 144 GPa
- Synchrotron infrared spectroscopy of synthetic Na(NaMg)Mg5Si8O22(OH)2 up to 30 GPa: Insight on a new high-pressure amphibole polymorph
